Iron distribution in the octahedral sheet of dioctahedral smectites. An Fe K-edge X-ray absorption spectroscopy study   总被引：1，自引：1，他引：1  

D. Vantelon  E. Montarges-Pelletier  L. J. Michot  M. Pelletier  F. Thomas  V. Briois 《Physics and Chemistry of Minerals》2003,30(1):44-53

The distribution of iron atoms in the octahedral sheet of a series of dioctahedral smectites with varying unit-cell composition and iron content was investigated by Fe K-edge XAS spectroscopy. First-step analysis reveals that the patterns corresponding to backscattering by atoms located between 3 and 4 Å from the absorbing atom are very sensitive to the relative amount of light (Si, Al, Mg) and heavy (Fe) atoms. Detailed modelling of this domain then provides valuable information on the number of iron atoms surrounding octahedral iron. By comparing the number of iron neighbours deduced from EXAFS with that determined from unit-cell composition assuming a statistical distribution, three groups of montmorillonites can be distinguished: (1) clay samples from Wyoming display an ordered distribution of iron atoms; (2) clay samples from Georgia, Milos, China and Washington exhibit a close to random distribution of iron atoms; (3) clay samples from North Africa, Germany, Texas and Arizona display extensive iron clustering. These results complement previously obtained IR results and show that the combination of these two spectroscopic techniques could provide an additional crystal-chemistry-based framework for typological analysis of montmorillonite deposits.  相似文献   

Sea-to-air flux of contaminants via bubbles bursting. An experimental approach for tributyltin     

Richard Saint-Louis  Emilien Pelletier   《Marine Chemistry》2004,84(3-4):211-224

Although seawater concentration of tributyltin (TBT) should decrease when the direct inputs from ship hulls will cease after the incoming world ban of organotin-based antifouling paints in 2003 or later, the TBT environmental issue will still be present for decades as contaminated sediments in shallow waters will be acting as a long-lasting reservoir for TBT and its degradation products. The lost of TBT to the atmosphere by volatilization has already been proposed as a part of its molecular motion through the aquatic environment but most recent calculated values of water-to-air rate of exchange of TBT (from 20 to 510 nmol m⁻² year⁻¹) do not take into account the potential contribution of aerosols ejection to the atmosphere upon bubbles bursting, an important process for pollutants transport in the marine environment. In this work, an experimental approach to measure the seawater-to-air flux of TBT mediated by bubbles bursting is described, and the influence of phytoplankton cells and dissolved organic matter from exudates and culture weathering on flux rates was assessed. The results demonstrate that TBT can be transferred from water to air via the ejection of droplets from bubbles bursting and that cell density strongly affected the transfer. Under a bubbling regime, the water-to-air flux (pmol TBT cm⁻² min⁻¹ level) is estimated up to 1000-fold the flux measured for the molecular diffusion and volatilization under static quiescent conditions. The surface microlayer acted as a transient boundary between the water column and the atmosphere where the dynamic of TBT accumulation has the same trend as the dynamic of TBT ejection. This physical transfer mechanism might be of high significance in nearshore environments, harbors, and shallow channels where clouds of bubbles generated in the wake of large ships play an important role for the atmosphere/seawater chemical exchanges.  相似文献   

Crack propagation by differential insolation on desert surface clasts     

John E. Moores  Jon D. Pelletier  Peter H. Smith   《Geomorphology》2008,102(3-4):472-481

In the southwest U.S., cracks in alluvial fan surface clasts have a preferred orientation independent of rock fabric and shape. In this paper, we show that differential insolation of incipient cracks of random orientations predicts a distribution of crack orientations consistent with field observations. In this model, crack growth by hydration and/or thermal weathering is primarily a function of local water content at the crack tip. Crack tips that experience minimal solar insolation maintain a greater average moisture and, hence, weather more rapidly than cracks that experience greater solar insolation. To show this, we used a numerical radiative transfer code to quantify the solar insolation of rectangular cracks at 35° N. latitude with a range of depths and orientations. The amount of solar energy reaching the bottom of each crack was calculated at 5-min intervals over the day for several days of the year to determine hourly, daily, seasonal, and annual energy deposition as a function of crack depth and orientation. By assuming that only crack orientations that effectively shield their interiors and minimize their water loss are able to grow, the pattern of cracks produced by the model is consistent with field observations. The annual average insolation, which controls water retention, is associated with the two primary modes of crack orientation. The effect of daily recharge by summer rains of the North American monsoon system is consistent with the observed deviations from these primary modes. Model results suggest that both the annual average insolation and the daily pattern of rainfall is recorded in the preferred crack orientations of surface clasts in the southwest U.S.  相似文献   

Detrital clay grain coats in estuarine clastic deposits: origin and spatial distribution within a modern sedimentary system,the Gironde Estuary (south‐west France)     

Maxime Virolle  Benjamin Brigaud  Raphaël Bourillot  Hugues Fnis  Eric Portier  Thibault Duteil  Julius Nouet  Patricia Patrier  Daniel Beaufort 《Sedimentology》2019,66(3):859-894

Porosity and permeability may be preserved in deep sandstone reservoirs by clay coating (mainly chlorite) which limits quartz overgrowths. Chloritization around quartz grains results mainly from mineralogical transformations of pre‐existing clays. It is fundamental to study those clay precursors to better understand and predict the location and distribution of clay coatings in subsurface sandstones for petroleum or geothermal prospecting. This paper reports a high‐resolution analysis of the composition, distribution and fabric of clays along a modern estuary, the Gironde (south‐west France). The scale of the study ranges from thin sections, through sand bar bodies, up to the entire estuary. Results show that clays are detrital and deposited at the same time as sand grains despite strong hydrodynamic conditions. Clays bind to medium‐grained sands forming detrital clay grain coats. On average, 26% of detrital sand grains are coated along the entire length of the estuary. Coat thickness varies from 1 μm to more than 200 μm, and coat coverage exceeds 30% in some samples. The turbidity maximum zone position (surface water turbidity from 1 to 10 g l^?1) in the estuary, which is controlled by seasonal variations in hydrodynamic processes, significantly impacts the location of the maximum clay content and the abundance of coated grains in sandy facies along the estuary. Flocculation in the water column results in the accumulation of suspended matter and contributes to the high turbidity in the estuary. Exopolymeric substances produced by diatoms are observed both in the field and by cryo‐scanning electron microscopy, suggesting that they may play a major role in binding detrital clay around sand grains. Finally, tidal bars and heterolithic point bars in the estuary funnel and estuarine channels are prime sedimentological targets for finding clay coatings and potentially good reservoir quality in deeply buried sandstones.  相似文献   

ERORUN-STAFOR: A collaborative observatory for the multidisciplinary study of the critical zone processes in a tropical volcanic watershed including a Tropical Montane Cloud Forest     

Alix Toulier  Jean-Lambert Join  Pierre Staménoff  Yoan Benoit  Geneviève Lebeau  Maxime Gautier  Caroline Gorge  Eric Gayer  Emmanuel Cordier  Victor Kbidi  Guillaume Payen  Magali David  Sophie Ferreira  François Bonnardot  Julien Bonnier  Stéphane Martel  Jimmy Gonthier  Emilie Roulleau  Jean-Pierre Cammas  Dominique Strasberg  Olivier Flores  Fabrice R. Fontaine  Thomas Giambelluca  Claudine Ah-Peng 《水文研究》2024,38(2):e15061

Tropical volcanic islands are biodiversity hotspots where the Critical Zone (CZ) still remains poorly studied. In such steep topographic environments associated with extreme climatic events (cyclones), deployment and maintenance of monitoring equipment is highly challenging. While a few Critical Zone Observatories (CZOS) are located in tropical volcanic regions, none of them includes a Tropical Montane Cloud Forest (TMCF) at the watershed scale. We present here the dataset of the first observatory from the French network of critical zone observatories (OZCAR) located in an insular tropical and volcanic context, integrating a ‘Tropical Montane Cloud Forest’: The ERORUN-STAFOR observatory. This collaborative observatory is located in the northern part of La Réunion island (Indian Ocean) within the 45.0 km² watershed of Rivière des Pluies (i.e., Rainfall river) which hosts the TMCF of Plaines des Fougères, one of the best preserved natural habitats in La Réunion Island. Since 2014, the ERORUN-STAFOR monitoring in collaboration with local partners collected a multidisciplinary dataset with a constant improvement of the instrumentation over time. At the watershed scale and in its vicinity, the ERORUN-STAFOR observatory includes 10 measurement stations covering the upstream, midstream and downstream part of the watershed. The stations record a total of 48 different variables through continuous (sensors) or periodic (sampling) monitoring. The dataset consists of continuous time series variables related to (i) meteorology, including precipitation, air temperature, relative humidity, wind speed and direction, net radiation, atmospheric pressure, cloud water flux, irradiance, leaf wetness and soil temperature, (ii) hydrology, including water level and temperature, discharge and electrical conductivity (EC) of stream, (iii) hydrogeology, including (ground)water level, water temperature and EC in two piezometers and one horizontally drilled groundwater gallery completed by soil moisture measurements under the canopy. The dataset is completed by periodic time series variables related to (iv) hydrogeochemistry, including field parameters and water analysis results. The periodic sampling survey provides chemical and isotopic compositions of rainfall, groundwater, and stream water at different locations of this watershed. The ERORUN-STAFOR monitoring dataset extends from 2014 to 2022 with an acquisition frequency from 10 min to hourly for the sensor variables and from weekly to monthly frequency for the sampling. Despite the frequent maintenance of the monitoring sites, several data gaps exist due to the remote location of some sites and instrument destruction by cyclones. Preliminary results show that the Rivière des Pluies watershed is characterized by high annual precipitation (>3000 mm y⁻¹) and a fast hydrologic response to precipitation (≈2 h basin lag time). The long-term evolution of the deep groundwater recharge is mainly driven by the occurrence of cyclone events with a seasonal groundwater response. The water chemical results support existing hydrogeological conceptual models suggesting a deep infiltration of the upstream infiltrated rainfall. The TMCF of Plaine des Fougères shows a high water storage capacity (>2000% for the Bryophytes) that makes this one a significant input of water to groundwater recharge which still needs to be quantified. This observatory is a unique research site in an insular volcanic tropical environment offering three windows of observation for the study of critical zone processes through upstream-midstream-downstream measurements sites. This high-resolution dataset is valuable to assess the response of volcanic tropical watersheds and aquifers at both event and long-term scales (i.e., global change). It will also provide insights in the hydrogeological conceptual model of volcanic islands, including the significant role of the TMCFs in the recharge processes as well as the watershed hydrosedimentary responses to extreme climatic events and their respective evolution under changing climatic conditions. All data sets are available at https://doi.org/10.5281/zenodo.7983138 .  相似文献   

Topographic correlations with soil and regolith thickness from shallow‐seismic refraction constraints across upland hillslopes in the Valles Caldera,New Mexico          下载免费PDF全文

Jared Olyphant  Jon D. Pelletier  Roy Johnson 《地球表面变化过程与地形》2016,41(12):1684-1696

How rock is weathered physically and chemically into transportable material is a fundamental question in critical‐zone science. In addition, the distribution of weathered material (soil and intact regolith) across upland landscapes exerts a first‐order control on the hydrology of watersheds. In this paper we present the results of six shallow seismic‐refraction surveys in the Redondo Mountain region of the Valles Caldera, New Mexico. The P‐wave velocities corresponding to soil (≤ 0.6 km s^?1) were inferred from a seventh seismic survey where soil‐thickness data were determined by pit excavation. Using multivariable regression, we quantified the relationships among slope gradient, aspect, and topographic wetness index (TWI) on soil and regolith (soil plus intact regolith) thicknesses. Our results show that both soil and regolith thicknesses vary inversely with TWI in all six survey areas while varying directly with slope aspect (i.e. thicker beneath north‐facing slopes) and inversely with slope gradient (i.e. thinner beneath steep slopes) in the majority of the survey areas. An empirical model based on power‐law relationships between regolith thickness and its correlative variables can fit our inferred thicknesses with R² ‐values up to 0.880 for soil and 0.831 for regolith in areas with significant topographic variations. These results further demonstrate the efficacy of shallow seismic refraction for mapping and determining how soil and regolith variations correlate with topography across upland landscapes. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Magnetite‐out and pyrrhotite‐in temperatures in shales and slates     

Charles Aubourg  Mike Jackson  Maxime Ducoux  Mohannad Mansour 《地学学报》2019,31(6):534-539

Clay‐rich basins have undergone varying degrees of magnetic transformation during burial, affecting their ability to retain accurate records of Earth's dynamic magnetic field. We propose to bracket the magnetite‐out and pyrrhotite‐in temperatures in shales and slates from Taiwan and the Pyrenees by using a combination of low‐temperature magnetic transitions and geothermometers. For T_burial < 340°C, the magnetic assemblage is dominated by magnetite. Gradually with increasing burial temperature, the concentration of magnetite decreases to a few ppmv. We observe the magnetite‐out isograd at T_burial ~350°C. At T_burial >60°C and T_burial >340°C respectively, fine‐grained and coarse‐grained pyrrhotite develop. In the course of burial, a clay‐rich basin gradually loses its capability to retain a record of Earth's magnetic field. It is only during basin uplift, that coarse pyrrhotite might acquire a thermo remanent magnetization. Our results point out therefore highly contrasted magnetic properties and palaeomagnetic records between deeply buried basins and exhumed ones.  相似文献   

Influence of glass polymerisation and oxidation on micro-Raman water analysis in alumino-silicate glasses   总被引：1，自引：0，他引：1  

Maxime Mercier  Andrea Di Muro  Daniele Giordano  Priscille Lesne  Bruno Scaillet  Gilles Montagnac 《Geochimica et cosmochimica acta》2009,73(1):197-217

The development of an accurate analytical procedure for determination of dissolved water in complex alumino-silicate glasses via micro-Raman analysis requires the assessment of the spectra topology dependence on glass composition. We report here a detailed study of the respective influence of bulk composition, iron oxidation state and total water content on the absolute and relative intensities of the main Raman bands related to glass network vibrations (LF: ∼490 cm⁻¹; HF: ∼960 cm⁻¹) and total water stretching (H₂O_T: ∼3550 cm⁻¹) in natural glasses. The evolution of spectra topology was examined in (i) 33 anhydrous glasses produced by the re-melting of natural rock samples, which span a very large range of polymerisation degree (NBO/T from 0.00 to 1.16), (ii) 2 sets of synthetic anhydrous basaltic glasses with variable iron oxidation state (Fe³⁺/Fe_T from 0.05 to 0.87), and (iii) 6 sets of natural hydrous glasses (C_H2OT from 0.4 to 7.0 wt%) with NBO/T varying from 0.01 to 0.76.In the explored domain of water concentration, external calibration procedure based on the H₂O_T band height is matrix-independent but its accuracy relies on precise control of the focusing depth and beam energy on the sample. Matrix-dependence strongly affects the internal calibrations based on H₂O_T height scaled to that of LF or HF bands but its effect decreases from acid (low NBO/T, SM) to basic (high NBO/T, SM) glasses. Structural parameters such as NBO/T (non-bridging oxygen per tetrahedron) and SM (sum of structural modifiers) describe the matrix-dependence better than simple compositional parameters (e.g. SiO₂, Na₂O + K₂O). Iron oxidation state has only a minor influence on band topology in basalts and is thus not expected to significantly affect the Raman determinations of water in mafic (e.g. low SiO₂, iron-rich) glasses. Modelling the evolution of the relative band height with polymerisation degree allows us to propose a general equation to predict the dissolved water content in natural glasses: