Phosphorus retention in constructed wetlands enhanced by zeolite- and clinopyroxene-dominated lava sand     

Christine Alewell  Jen-How Huang  Timothy I. McLaren  Lea Huber  Else K. Bünemann 《水文研究》2021,35(2):e14040

Constructed wetlands (CWs) are engineered systems for treating wastewater by sequestering nutrients and contaminants. Our aim was to assess the main phosphorus (P) binding states in operating CWs to assess P saturation and indications on P recycling potential of filter materials, which might be necessary under future peak P scenarios. The investigated vertical flow CWs (operation time up to 16 years) are based on either fluviatile (Fluv) sand or zeolite- (Ze-LS) and clinopyroxene (Cl-LS)-dominated lava sand. Organic and inorganic P accumulated in all CWs independent of filter materials and showed a considerable increase with operation time. Concentrations of P decreased sharply with depth in the Fluv-CWs compared to only a slight decrease in the lava sand CWs, with P concentrations of deeper horizons approximating the relatively P enriched original lava sand substrates. Orthophosphate was the dominant pool in all CWs, while the sum of organic fractions ranged between 11% and 33%. Sequential extraction indicated that P was mainly associated with Fe and Al (hydr)oxides for Fluv-CWs and Ze-LS-CWs, while Ca and Mg bound mineral phosphates dominated in Cl-LS-CWs. Oxalate extractions pointed to a clear dominance of P fractions associated with poorly crystalline Fe- and Al-(oxy)hydroxides. Solution ³¹P NMR analyses revealed that inositol hexakisphosphates were a major pool of organic P in surface layers of CWs, which increased with operation time. With a maximum of 0.5% P content, filter sands do not appear to be a suitable fertilizer for direct application to agricultural fields. The dominance of inorganic, poorly crystalline P species point to potentially high desorption capacity which might be investigated further, to assess recycling potential of P or usage of filter materials as soil amendments with relatively high plant available P. The latter might become feasible and economically attractive under future P scarcity. Simultaneously, P saturation indexes (DPS) did not indicate an imminent P saturation of filters, since P accumulation was not restricted by binding to Al and Fe minerals.  相似文献   

Tectonic Evolution of the Itremo Region (Central Madagascar) and Implications for Gondwana Assembly   总被引：1，自引：0，他引：1  

Alain Fernandez  Sarah Huber  Guido Schreurs  Igor Villa  Michel Rakotondrazafy 《Gondwana Research》2001,4(2)

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Observation of snowfall with a low-power FM-CW K-band radar (Micro Rain Radar)     

Stefan Kneifel  Maximilian Maahn  Gerhard Peters  Clemens Simmer 《Meteorology and Atmospheric Physics》2011,113(1-2):75-87

Quantifying snowfall intensity especially under arctic conditions is a challenge because wind and snow drift deteriorate estimates obtained from both ground-based gauges and disdrometers. Ground-based remote sensing with active instruments might be a solution because they can measure well above drifting snow and do not suffer from flow distortions by the instrument. Clear disadvantages are, however, the dependency of e.g. radar returns on snow habit which might lead to similar large uncertainties. Moreover, high sensitivity radars are still far too costly to operate in a network and under harsh conditions. In this paper we compare returns from a low-cost, low-power vertically pointing FM-CW radar (Micro Rain Radar, MRR) operating at 24.1?GHz with returns from a 35.5?GHz cloud radar (MIRA36) for dry snowfall during a 6-month observation period at an Alpine station (Environmental Research Station Schneefernerhaus, UFS) at 2,650?m height above sea level. The goal was to quantify the potential and limitations of the MRR in relation to what is achievable by a cloud radar. The operational MRR procedures to derive standard radar variables like effective reflectivity factor (Z _e) or the mean Doppler velocity (W) had to be modified for snowfall since the MRR was originally designed for rain observations. Since the radar returns from snowfall are weaker than from comparable rainfall, the behavior of the MRR close to its detection threshold has been analyzed and a method is proposed to quantify the noise level of the MRR based on clear sky observations. By converting the resulting MRR-Z _e into 35.5?GHz equivalent Z _e values, a remaining difference below 1?dBz with slightly higher values close to the noise threshold could be obtained. Due to the much higher sensitivity of MIRA36, the transition of the MRR from the true signal to noise can be observed, which agrees well with the independent clear sky noise estimate. The mean Doppler velocity differences between both radars are below 0.3?ms^?1. The distribution of Z _e values from MIRA36 are finally used to estimate the uncertainty of retrieved snowfall and snow accumulation with the MRR. At UFS low snowfall rates missed by the MRR are negligible when comparing snow accumulation, which were mainly caused by intensities between 0.1 and 0.8 mm?h^?1. The MRR overestimates the total snow accumulation by about 7%. This error is much smaller than the error caused by uncertain Z _e?Csnowfall rate relations, which would affect the MIRA36 estimated to a similar degree.  相似文献   

Sorption reversibility kinetics in the ternary system radionuclide–bentonite colloids/nanoparticles–granite fracture filling material     

F. Huber  P. Kunze  H. Geckeis  T. Schäfer 《Applied Geochemistry》2011,26(12):2226-2237

The kinetics of radionuclide desorption from bentonite colloids and subsequent sorption onto fracture filling material can influence colloid-facilitated radionuclide migration in ground water. To shed light on the significance of these issues batch-type experiments using a cocktail of strong and weak sorbing radionuclides as well as FEBEX bentonite colloids in the presence of fracture filling material from Grimsel (Switzerland) under Grimsel ground water conditions have been conducted. Results show that tri- and tetravalent radionuclides, ²³²Th(IV), ²⁴²Pu(IV) and ²⁴³Am(III) are clearly colloid associated in contrast to ²³³U(VI), ²³⁷Np(V) and ⁹⁹Tc(VII). Concentrations of colloid-borne ²³²Th(IV), ²⁴²Pu(IV) and ²⁴³Am(III) decrease after ∼100 h showing desorption from bentonite colloids while ²³³U(VI) and ⁹⁹Tc(VII) concentrations remain constant over the entire experimental time of 7500 h thus showing no interaction either to colloids or to the fracture filling material. ²³²Th(IV) and ²⁴²Pu(IV) data yield a slower dissociation from colloids compared to ²⁴³Am(III) indicating stronger RN–colloid interaction. In the case of ²³⁷Np(V), a decrease in concentration after ∼300 h is observed which can be explained either by slow reduction to Np(IV) and subsequent sorption to mineral surfaces in accordance with the evolution of pe/pH and/or by a slow sorption onto the fracture filling material. No influence of the different fracture filling material size fractions (0.25–0.5 mm, 0.5–1 mm and 1–2 mm) can be observed implying reaction independence of the mineral surface area and mineralogical composition. The driving force of the observed metal ion desorption from colloids is binding to fracture filling material surfaces being in excess of the available colloid surface area (76:1, 55:1 and 44:1 for the 0.25–0.5 mm, 0.5–1 mm and 1–2 mm size fraction of the FFM, respectively).  相似文献   

Significance of slope sediments layering on physical characteristics and interflow within the Critical Zone – Examples from the Colorado Front Range,USA     

Jörg Völkel  Juliane Huber  Matthias Leopold 《Applied Geochemistry》2011

The subalpine to montane zones within the Critical Zone (CZ) of the Colorado Front Range, USA outside Pleistocene glaciation limits are characterized by the abundance of stratified and multilayered slope deposits exhibiting depths >1 m. Initial luminescence dating for the upper sediment layers in different profiles give last glacial ages ranging between 40 and 12 ka. A periglacial origin by solifluction is hypothesized for these slope deposits, which is corroborated by geomorphic and sedimentologic parameters. The stratified slope sediments have a strong influence on the physical and chemical properties as well as on soil forming processes in the CZ. Examples are provided for the sediment derived contribution of some elements and common clay minerals together and the great importance of slope sediments as barriers and pathways for the interflow that runs in sediment layers are shown.  相似文献   

Noble gases in 18 Martian meteorites and angrite Northwest Africa 7812—Exposure ages,trapped gases,and a re‐evaluation of the evidence for solar cosmic ray‐produced neon in shergottites and other achondrites          下载免费PDF全文

R. Wieler  L. Huber  H. Busemann  S. Seiler  I. Leya  C. Maden  J. Masarik  M. M. M. Meier  K. Nagao  R. Trappitsch  A. J. Irving 《Meteoritics & planetary science》2016,51(2):407-428

We present noble gas data for 16 shergottites, 2 nakhlites (NWA 5790, NWA 10153), and 1 angrite (NWA 7812). Noble gas exposure ages of the shergottites fall in the 1–6 Ma range found in previous studies. Three depleted olivine‐phyric shergottites (Tissint, NWA 6162, NWA 7635) have exposure ages of ~1 Ma, in agreement with published data for similar specimens. The exposure age of NWA 10153 (~12.2 Ma) falls in the range of 9–13 Ma reported for other nakhlites. Our preferred age of ~7.3 Ma for NWA 5790 is lower than this range, and it is possible that NWA 5790 represents a distinct ejection event. A Tissint glass sample contains Xe from the Martian atmosphere. Several samples show a remarkably low (²¹Ne/²²Ne)_cos ratio < 0.80, as previously observed in a many shergottites and in various other rare achondrites. This was explained by solar cosmic ray‐produced Ne (SCR Ne) in addition to the commonly found galactic cosmic ray‐produced Ne, implying very low preatmospheric shielding and ablation loss. We revisit this by comparing measured (²¹Ne/²²Ne)_cos ratios with predictions by cosmogenic nuclide production models. Indeed, several shergottites, acalpulcoites/lodranites, angrites (including NWA 7812), and the Brachina‐like meteorite LEW 88763 likely contain SCR Ne, as previously postulated for many of them. The SCR contribution may influence the calculation of exposure ages. One likely reason that SCR nuclides are predominantly detected in meteorites from rare classes is because they usually are analyzed for cosmogenic nuclides even if they had a very small (preatmospheric) mass and hence low ablation loss.  相似文献   

First Results of the Regional Earthquake Likelihood Models Experiment   总被引：1，自引：0，他引：1  

Danijel Schorlemmer  J. Douglas Zechar  Maximilian J. Werner  Edward H. Field  David D. Jackson  Thomas H. Jordan 《Pure and Applied Geophysics》2010,167(8-9):859-876

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Inter‐ and intra‐colonial genotypic diversity in hermatypic hydrozoans of the family Milleporidae          下载免费PDF全文

Maximilian Schweinsberg  Ralph Tollrian  Kathrin P. Lampert 《Marine Ecology》2017,38(1)

Genetic diversity is the basis for adaptation and therefore of primary scientific interest, especially in species that are threatened by anthropogenic challenges, e.g. climate change and/or pollution. Coral reefs are among the most threatened but also the most diverse ecosystems and have therefore been studied quite extensively. So far, most investigations have focused on scleractinian corals while the equally important reef builders, the hydrozoans, have been less considered. Here we provide the first study of genotypic variability as well as intra‐colonial genetic variability, the co‐occurrence of more than one genotype within a single colony, in Milleporidae based on microsatellites. We analysed two geographically distinct populations from the Millepora dichotoma complex, one from the Red Sea and one from the Great Barrier Reef. Additionally, a population of Millepora platyphylla was analysed from French Polynesia. We compared microsatellite multilocus genotypes and cytochrome c oxidase subunit I haplotypes for each of the three field sites to detect levels of genotypic diversity at the intra‐ and inter‐specific levels. Furthermore, we examined all species for the occurrence of intra‐colonial genetic variability, a recently described mechanism in scleractinian corals that might enhance the adaptive potential of sessile organisms. We found both species and all field sites to be genotypically variable. Twelve mitochondrial haplotypes and 27 multilocus microsatellite genotypes were identified. In addition, intra‐colonial genetic variability was detected in the M. dichotoma complex from the Great Barrier Reef as well as in M. platyphylla from French Polynesia. All of the intra‐colonial genetically variable colonies consisted of one main genotype and a second divergent genotype caused by somatic mutations (mosaicism). Our study proves that Milleporidae are genetically variable and that the phenomenon of intra‐colonial genetic variability also occurs in this important reef‐building family.  相似文献   

Potential of space-borne GNSS reflectometry to constrain simulations of the ocean circulation     

Jan Saynisch  Maximilian Semmling  Jens Wickert  Maik Thomas 《Ocean Dynamics》2015,65(11):1441-1460

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Diffusion-controlled spherulite growth in obsidian inferred from H<Subscript>2</Subscript>O concentration profiles     

Jim Watkins  Michael Manga  Christian Huber  Michael Martin 《Contributions to Mineralogy and Petrology》2009,157(2):163-172

Spherulites are spherical clusters of radiating crystals that occur naturally in rhyolitic obsidian. The growth of spherulites requires diffusion and uptake of crystal forming components from the host rhyolite melt or glass, and rejection of non-crystal forming components from the crystallizing region. Water concentration profiles measured by synchrotron-source Fourier transform spectroscopy reveal that water is expelled into the surrounding matrix during spherulite growth, and that it diffuses outward ahead of the advancing crystalline front. We compare these profiles to models of water diffusion in rhyolite to estimate timescales for spherulite growth. Using a diffusion-controlled growth law, we find that spherulites can grow on the order of days to months at temperatures above the glass transition. The diffusion-controlled growth law also accounts for spherulite size distribution, spherulite growth below the glass transition, and why spherulitic glasses are not completely devitrified. An erratum to this article can be found at  相似文献