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31.
Arctic landscapes are believed to be highly sensitive to climate change and accelerated disturbance of permafrost is expected to significantly impact the rate of carbon cycling. While half the global soil organic matter (SOM) is estimated to reside in Arctic soils, projected warmer temperatures and permafrost disturbance will release much of this SOM into waterways in the form of dissolved organic matter (DOM). The spring thaw and subsequent flushing of soils releases the highest contributions of DOM annually but has historically been undersampled due to the difficulties of sampling during this period. In this study, passive samplers were placed throughout paired High Arctic watersheds during the duration of the 2008 spring flush in Nunavut, Canada. The watersheds are very similar with the exception of widespread active layer detachments (ALDs) that occurred within one of the catchments during a period of elevated temperatures in the summer of 2007. DOM samples were analyzed for structural and spectral characteristics via nuclear magnetic resonance (NMR) and fluorescence spectroscopy as well as vulnerability to degradation with simulated solar exposure. Lignin-derived phenols were further assessed utilizing copper(II) oxide (CuO) oxidation and gas chromatography/mass spectrometry (GC/MS). The samples were found to have very low dissolved lignin phenol content (∼0.07% of DOC) and appear to originate from primarily non-woody angiosperm vegetation. The acid/aldehyde ratios for dissolved vanillyl phenols were found to be high (up to 3.6), indicating the presence of highly oxidized lignin. Differences between DOM released from the ALD vs. the undisturbed watershed suggest that these shallow detachment slides have significantly impacted the quality of Arctic DOM. Although material released from the disturbed catchment was found to be highly oxidized, DOM in the lake into which this catchment drained had chemical characteristics indicating high contributions from microbial and/or primary productivity. The resulting pool of dissolved carbon within the lake appears to be more biologically- and photochemically-labile than material from the undisturbed system. These disturbances may have implications for projected climate warming; sustained elevated temperatures would likely perpetuate widespread ALDs and further affect carbon cycling in this environment.  相似文献   
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The study of climate impacts on Living Marine Resources (LMRs) has increased rapidly in recent years with the availability of climate model simulations contributed to the assessment reports of the Intergovernmental Panel on Climate Change (IPCC). Collaboration between climate and LMR scientists and shared understanding of critical challenges for such applications are essential for developing robust projections of climate impacts on LMRs. This paper assesses present approaches for generating projections of climate impacts on LMRs using IPCC-class climate models, recommends practices that should be followed for these applications, and identifies priority developments that could improve current projections. Understanding of the climate system and its representation within climate models has progressed to a point where many climate model outputs can now be used effectively to make LMR projections. However, uncertainty in climate model projections (particularly biases and inter-model spread at regional to local scales), coarse climate model resolution, and the uncertainty and potential complexity of the mechanisms underlying the response of LMRs to climate limit the robustness and precision of LMR projections. A variety of techniques including the analysis of multi-model ensembles, bias corrections, and statistical and dynamical downscaling can ameliorate some limitations, though the assumptions underlying these approaches and the sensitivity of results to their application must be assessed for each application. Developments in LMR science that could improve current projections of climate impacts on LMRs include improved understanding of the multi-scale mechanisms that link climate and LMRs and better representations of these mechanisms within more holistic LMR models. These developments require a strong baseline of field and laboratory observations including long time series and measurements over the broad range of spatial and temporal scales over which LMRs and climate interact. Priority developments for IPCC-class climate models include improved model accuracy (particularly at regional and local scales), inter-annual to decadal-scale predictions, and the continued development of earth system models capable of simulating the evolution of both the physical climate system and biosphere. Efforts to address these issues should occur in parallel and be informed by the continued application of existing climate and LMR models.  相似文献   
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Abstract— The origin of hematite detected in Martian surface materials is commonly attributed to weathering processes or aqueous precipitation. Here, we present a new hematite formation mechanism that requires neither water nor weathering. Glass‐rich basalts with Martian meteorite‐like chemistry (high FeO, low Al2O3) oxidized at high (700 and 900 °C) temperatures in air and CO2, respectively, form thin (<1 μm) hematite coatings on their outermost surfaces. Hematite is manifested macroscopically by development of magnetism and a gray, metallic sheen on the glass surface and microscopically by Fe enrichment at the glass surface observed in element maps. Visible and near‐infrared, thermal infrared, and Raman spectroscopy confirm that the Fe enrichment at the oxidized glass surfaces corresponds to hematite mineralization. Hematite formation on basaltic glass is enabled by a mechanism that induces migration of Fe2+ to the surface of an oxidizing glass and subsequent oxidation to form hematite. A natural example of the hematite formation mechanism is provided by a Hawaiian basalt hosting a gray, metallic sheen that corresponds to a thin hematite coating. Hematite coating development on the Hawaiian basalt demonstrates that Martian meteorite‐like FeO contents are not required for hematite coating formation on basalt glass and that such coatings form during initial extrusion of the glassy basalt flows. If gray hematite originating as coatings on glassy basalt flows is an important source of Martian hematite, which is feasible given the predominance of igneous features on Mars, then the requirement of water as an agent of hematite formation is eliminated.  相似文献   
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High Arctic river responses to changing hydroclimatic and landscape processes are poorly understood. In non‐glacierized basins, snowmelt and rainfall generate river discharge, which provides first order control over fluxes. Further factors include the seasonality of precipitation, seasonal active layer development, and permafrost disturbance. These controls were evaluated in terms of sedimentary and biogeochemical fluxes from paired catchments at Cape Bounty, Melville Island, Nunavut during 2006–2009. Results indicate that the source of runoff can be more important than the amount of runoff for sediment, solutes, and organic yields. Although the snowmelt period is typically the most important time for these yields, heavy late summer precipitation events can create disproportionately large yields. Rainfall increases yields because it hydrologically connects areas otherwise isolated. Inorganic solute yields from late summer rainfall are higher because the thick active layer maximizes hydrologic interactions with mineral soils and generates high solute concentrations. Results also indicate that while the catchments are broadly similar, subtle topographic differences result in important inter‐catchment differences in runoff and suspended and dissolved loads. The East watershed, which had less extensive permafrost disturbance, consistently had higher concentrations of dissolved solids. These higher dissolved fluxes cannot therefore be explained by thermokarst features, but rather by deeper active layer development, due to a greater proportion of south‐facing slopes. Although warm temperatures in 2007 led to extensive active layer disturbance in the West watershed, because the disturbances were largely hydrologically disconnected, the total disturbed area was small, and inter‐annual variability in discharge was high, there was no detectable response in dissolved loads to disturbances. Sediment availability increased after 2007, but yields have largely returned to pre‐disturbance levels. Results indicate that seasonality and frequency‐magnitude characteristics of projected increases in precipitation must be considered along with active layer changes to predict the fluvial sedimentary and biogeochemical response to regional climate change. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
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In a context of neo-liberal environmental governance, imperatives for global climate change mitigation are motivating a new round of policy initiatives and projects aimed at carbon forestry: conserving and enhancing forest carbon stocks, and trading these values in emerging carbon markets. In this context modelling and measurement, always significant in framing and justifying forest policy initiatives, are of renewed importance, with a growing array of protocols focused on counting and accounting for forest carbon as a commodity. This article draws on perspectives from science and technology studies and environmental discourse analysis to explore how these modelling and measurement processes are being co-constructed with forest carbon policies and political economies, and applied in project design in local settings. Document analysis and key informant interviews are used to track and illustrate these processes in a pair of case studies of forest carbon projects in Sierra Leone and Ghana. These are chosen to highlight different project types – focused respectively on forest reserve and farm-forestry – in settings with multi-layered histories of people-forest relations, landscape change and prior project intervention. The analysis shows how longer established framings and assessments of deforestation are being re-invoked and re-worked amidst current carbon concerns. We demonstrate that measurement processes are not just technical but social and political, carrying and thus cementing particular views of landscape and social relations that in turn make likely particular kinds of intervention pathway, with fortress style conservation or plantations becoming the dominant approach. In the process, other possibilities – including alternative pathways that might treat and value carbon as part of complex, lived-in landscapes, or respond more adaptively to less equilibrial people–forest relations, are occluded.  相似文献   
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High-resolution observations of atmospheric phenomena by the Mars Odyssey Thermal Emission Imaging System (THEMIS) during its first mapping year are presented. An atmospheric campaign was implemented on the basis of previous spacecraft imaging. This campaign, however, proved of limited success. This appears to be due to the late local time of the Odyssey orbit (the locations of activity at 4–6 p.m. appear to be different from those at 2 p.m.). Ironically, images targeting the surface were more useful for study of the atmosphere than those images specifically targeting atmospheric features. While many previously recognized features were found, novel THEMIS observations included persistent clouds in the southern polar layered deposits, dust or condensate plumes on the northern polar layered deposits, dust plumes as constituent parts of local dust storms, and mesospheric clouds. The former two features tend to be aligned parallel and normal to polar troughs, respectively, suggesting a wind system directed normal to troughs and radially outward from the center of the polar deposits. This is consistent with katabatic drainage of air off the polar deposits, analogous to flow off Antarctica. The observation of dust lifting plumes at unprecedented resolution associated with local dust storms not only demonstrates the importance of mean wind stresses (as opposed to dust devils) in initiation of dust storms, but is also seen to be morphologically identical to dust lifting in terrestrial dust storms. As Odyssey moves to earlier local times, we suggest that the atmospheric campaign from the first mapping year be repeated.  相似文献   
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ABSTRACT

Work Integration Social Enterprises (WISE) offer supported work environments for people experiencing disadvantage, including people with disability. This paper reflects on a research project that is mapping the ways in which social enterprises in regional Australian cities produce wellbeing for their employees. Through supported employment programs, these organisations are transforming individual lives, helping to build a sense of self-worth and purpose, and increase individuals’ social skills and capacities. Many of the perceived benefits are associated with a belief in the innate good of paid work. Based upon interviews with employees in the social enterprises, it is apparent that the hopes attached to providing ‘meaningful work’ are considerable. At the same time social enterprises are taking on social responsibilities that were once provided by the state, while also selling their services as employers of disabled and disadvantaged members of society and maintaining commercial viability of the enterprise. Using feminist political economy alongside discussion of the distributive economy, this paper explores how contemporary policy conditions, productivist biases and normative discourses about the value of wage work inflect the forms of wellbeing that can be experienced by WISE workers.  相似文献   
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