Synthesis of Calix[4]arene‐grafted Magnetite Nanoparticles and Evaluation of Their Arsenate as Well as Dichromate Removal Efficiency     

Serkan Sayin  Fatih Ozcan  Mustafa Yilmaz  Ali Tor  Shahabuddin Memon  Yunus Cengeloglu 《洁净——土壤、空气、水》2010,38(7):639-648

In this study, 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy‐calix[4]arene ( 3 ) has been prepared by the treatment of calix[4]arene with a secondary amine (4‐benzylpiperidine) and formaldehyde by means of Mannich reaction. The prepared Mannich base ( 3 ) has been grafted onto [3‐(2,3‐epoxypropoxy)‐propyl]‐trimethoxysilane‐modified Fe₃O₄ magnetite nanoparticles (EPPTMS‐MN) in order to obtain 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy calix[4]arene‐grafted EPPTMS‐MN (BP‐calix[4]arene‐grafted Fe₃O₄). All new compounds were characterized by a combination of FTIR and ¹H‐NMR analyses. The morphology of the magnetic nanoparticles was examined by transmission electron microscopy. Moreover, the studies regarding the removal of arsenate and dichromate ions from the aqueous solutions were also carried out by using 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy‐calix[4]arene in liquid–liquid extraction and BP‐calix[4]arene‐grafted Fe₃O₄ ( 4 ) in solid–liquid extraction experiments. The extraction results indicated that 3 is protonated at proton‐switchable binding sites in acidic conditions. Hence, facilitating binding of arsenate and dichromate is resulted from both electrostatic interactions and hydrogen bonding. To understand the selectivity of 3 , the retention of dichromate anions in the presence of Cl⁻, NO, and SO anions at pH 1.5 was also examined.  相似文献   

Enhancing the Performance of Anaerobic Digestion of Dairy Manure through Phase‐Separation     

Vedat Yilmaz  Göksel N. Demirer 《洁净——土壤、空气、水》2008,36(9):760-766

Anaerobic digestion (AD) is an effective way to convert animal manures into profitable by‐products while simultaneously reducing the pollution of water, air, and soil caused by these wastes. Conventional high‐rate anaerobic reactors cannot effectively process animal manures with high solids‐containing wastes. The two‐phase configuration for AD has several advantages over conventional one‐phase processes, e. g., increased stability of the process, smaller size and cost efficient process configurations. In the present study, the experiments were carried out in a two‐phase system composed of an acidogenic reactor and a methanogenic reactor, and in a one‐phase system composed of only a methanogenic reactor. The reactors were operated as unmixed (without an external mixing aid), unsophisticated, and daily‐fed mode. It was found that the two‐phase configuration was more efficient than the one‐phase system. The biogas production in the two‐phase system at a hydraulic retention time (HRT) of 8.6 days (only methanogenic phase) was calculated to be 42% higher at an organic loading rate (OLR) of 3.5 g VS/L·day than that of the one‐phase with a HRT of 20 days. This translates into significant performance improvement and reduced volume requirement. This finding represents a further step in the achievement of wider use of simple anaerobic reactor configurations for waste treatment in rural areas.  相似文献   

Seismic behaviour of shallow foundations: Shaking table experiments vs numerical modelling   总被引：1，自引：0，他引：1  

Roberto Paolucci  Masahiro Shirato  M. Tolga Yilmaz 《地震工程与结构动力学》2008,37(4):577-595

The capability of a simplified approach to model the behaviour of shallow foundations during earthquakes is explored by numerical simulation of a series of shaking table tests performed at the Public Works Research Institute, Tsukuba, Japan. After a summary of the experimental work, the numerical model is introduced, where the whole soil–foundation system is represented by a multi‐degrees‐of‐freedom elasto‐plastic macro‐element, supporting a single degree‐of‐freedom superstructure. In spite of its simplicity and of the large intensity of the excitation involving a high degree of nonlinearity in the foundation response, the proposed approach is found to provide very satisfactory results in predicting the rocking behaviour of the system and the seismic actions transmitted to the superstructure. The agreement is further improved by introducing a simple degradation rule of the foundation stiffness parameters, suitable to capture even some minor details of the observed rocking response. On the other hand, the performance of the model is not fully satisfactory in predicting vertical settlements. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Spectroscopic study of the eclipsing binary V 367 Cygni     

Aydin  Cemal  Hack  Margherita  Yilmaz  Nihal 《Astrophysics and Space Science》1978,53(2):345-370

Seventeen coudé spectrograms (dispersion 20 A mm^–1) of the Lyrae-type eclipsing binary V 367 Cygni (P=18.6 d) have been studied. The observations were made at the Haute Provence Observatory during a period of almost two years (May 1973–March 1975). An anomalous behavior for the radial velocities of the spectrograms taken during one cycle (406) was observed; it is suggested that gas eruption under form of prominences may explain it. The spectrum is dominated by shell lines very similar to those present in the spectrum of the supergiant A9 Ia Aurigae. The underlying stellar spectrum is classified as A5 I on the basis of the intensity of the sole clearly visible stellar line, 4481 MgII, of the wings of the stellar Balmer lines, and an estimate of the intensity of the stellarK line. The radial velocity curves for the shell lines of CaII, HI, metallic ions and neutral iron, as well as the phase dependence of the microturbulence, indicate stratification in the shell.  相似文献   

The high-galactic-latitude O-type star HD 93521     

Margherita Hack  Nihal Yilmaz 《Astrophysics and Space Science》1977,48(2):483-489

The spectrum of the peculiar O9 star HD 93521 is studied and compared with those of the standard stars 10 Lac and AE Aur. Several possibilities are examined which might explain the high galactic latitude of this star, corresponding toz>750 pc and its slight helium excess. It is suggested that HD 93521 is a runaway binary system composed of the O9 star plus a neutron star left over from a supernova explosion.  相似文献   

Simplified theoretical approaches to earthquake fault rupture–shallow foundation interaction     

R. Paolucci  M. T. Yilmaz 《Bulletin of Earthquake Engineering》2008,6(4):629-644

Construction of buildings in the proximity to seismically active faults is restricted by clause 4.1.2 of Eurocode 8 Part 5. However, there is no clear definition of the safe distance to fault, and the uncertainty related to the location of main and secondary traces of rupture for a future event can prevent the reduction of fault-breakage related risks to acceptable levels. The diversion of the surface trace of rupture by massive structures seated on thick soil deposits can be beneficial for the risk reduction. The scope of this study is first to revise previous theoretical approaches for providing simple engineering criteria for the diversion of the surface breakage of fault rupture for shallow foundations and, secondly, to extend them to treat the case of drained soils subjected to normal or reverse fault. The applicability of these criteria, which essentially provide minimum values for the weight of structure depending on the thickness of the surface soil deposit, is discussed through comparisons with the experimental results.  相似文献   

Climatic Influences on Autochthonous and Allochthonous Phytoplankton Blooms in a Subtropical Estuary, St. Lucie Estuary, Florida, USA     

Edward J. Phlips  Susan Badylak  Jane Hart  Daniel Haunert  Jean Lockwood  Kathyrn O’Donnell  Detong Sun  Paula Viveros  Mete Yilmaz 《Estuaries and Coasts》2012,35(1):335-352

The St. Lucie Estuary, located on the southeast coast of Florida, provides an example of a subtropical ecosystem where seasonal changes in temperature are modest, but summer storms alter rainfall regimes and external inputs to the estuary from the watershed and Atlantic Ocean. The focus of this study was the response of the phytoplankton community to spatial and temporal shifts in salinity, nutrient concentration, watershed discharges, and water residence times, within the context of temporal patterns in rainfall. From a temporal perspective, both drought and flood conditions negatively impacted phytoplankton biomass potential. Prolonged drought periods were associated with reduced nutrient loads and phytoplankton inputs from the watershed and increased influence of water exchange with the Atlantic Ocean, all of which restrict biomass potential. Conversely, under flood conditions, nutrient loads were elevated, but high freshwater flushing rates in the estuary diminished water residence times and increase salinity variation, thereby restricting the buildup of phytoplankton biomass. An exception to the latter pattern was a large incursion of a cyanobacteria bloom from Lake Okeechobee via the St. Lucie Canal observed in the summer of 2005. From a spatial perspective, regional differences in water residence times, sources of watershed inputs, and the proximity to the Atlantic Ocean influenced the composition and biomass of the phytoplankton community. Long water residence times in the North Fork region of the St. Lucie Estuary provided an environment conducive to the development of blooms of autochthonous origin. Conversely, shorter residence times in the mid-estuary limit autochthonous increases in biomass, but allochthonous sources of biomass can result in bloom concentrations of phytoplankton.  相似文献   

Intermediate sulfidation epithermal gold-base metal deposits in Tertiary subaerial volcanic rocks,Sahinli/Tespih Dere (Lapseki/Western Turkey)     

Huseyin Yilmaz  Tolga Oyman  F. Nuran Sonmez  Greg B. Arehart  Zeki Billor 《Ore Geology Reviews》2010,37(3-4):236-258

Gold in the Sahinli and Tespih Dere intermediate sulfidation gold-base metal deposits in Western Turkey occurs in relatively deep epithermal quartz veins along with base metal minerals which have epithermal textures, including plumose quartz, vug infills, comb and cockade textures and matrix-supported milled breccias. The total sulfide content of the veins in the area is variable ranging from < 1% to 60% and is dominated by pyrite, galena, sphalerite and chalcopyrite. Sphalerite is Fe-poor (0.6 to 1.4 mol% FeS). Minor amounts of Ag-rich tetrahedrite are present. Primary hydrothermal alteration minerals include illite/muscovite, mixed-layer illite/smectite (11.6 Å) and clinochlore towards the east and, alunite, dickite/nacrite and pyrophyllite towards the west at Sahinli; major illite/muscovite and dickite occur at Tespih Dere and Sarioluk, respectively.Fluid inclusions in main-stage quartz at Sahinli are only liquid-rich, with homogenization temperatures ranging from 220 to 322 °C and the majority of T_h values between 250 and 300 °C. Salinity ranges from 4.3 to 6.9 wt.% NaCl equiv. First ice-melting temperatures (T_mf) between ?24.5 and ?19.0 °C indicate that the fluids were dominated by NaCl – H₂O during mineralization. The relatively higher average T_h at the Tespih Dere deposit (295 °C) is attributed to a relatively deeper level of exposure.Calculated δ¹⁸O values indicate that ore-forming hydrothermal fluids in the study area had δ¹⁸O_H2O ranging from + 1.1 to + 9.7‰ (average = 3.8‰), strongly ¹⁸O-enriched compared with present-day hydrothermal meteoric water in the area (δ¹⁸O = ?8.5‰). δD values of fluid inclusions in quartz range from ?58 to ?93‰ and δD values of clay minerals and alunite from ?40 to ?119‰. δD values from intermediate argillic alteration (average = ?68‰) in the study area are very similar to δD values of the present-day local geothermal system (average δD = ?54‰) whereas δD values from advanced-argillic alteration (average δD = ?33‰) are very different from the present-day local geothermal system.The δ³⁴S values in samples from the Sahinli and Tespih Dere deposits average ?2.9‰ for pyrite; ?3.3‰ for chalcopyrite; ?5.4‰ for sphalerite and ?7.6‰ for galena. These data are consistent with derivation of the sulfur from either igneous rocks or possibly from local wallrock.  相似文献   

Water quality and hydrogeochemical characteristics of the River Buyukmelen,Duzce, Turkey     

Rustem Pehlivan  Osman Yilmaz 《水文研究》2005,19(20):3947-3971

The River Buyukmelen is located in the province of Duzce in northwest Turkey and its water basin is approximately 470 km². The Aksu, Kucukmelen and Ugursuyu streams flow into the River Buyukmelen. It flows into the Black Sea with an output of 44 m³ s⁻¹. The geological succession in the basin comprises limestone and dolomitic limestone of the Yılanlı formation, sandstone, clayey limestone and marls of the Akveren formation, clastics and volcano‐clastics of the Caycuma formation, and cover units comprised of river alluvium, lacutrine sediments and beach sands. The River Buyukmelen is expected to be a water source that can supply the drinking water needs of Istanbul until 2040; therefore, it is imperative that its water quality be preserved. The samples of rock, soil, stream water, suspended, bed and stream sediments and beach sand were collected from the Buyukmelen river basin. They were examined using mineralogical and geochemical methods. The chemical constituents most commonly found in the stream waters are Na⁺, Mg²⁺, SO²⁻₄, Cl⁻ and HCO₃⁻ in the Guz stream water, Ca²⁺ in the Abaza stream water, and K⁺ in the Kuplu stream water. The concentrations of Na⁺, K⁺, Ca²⁺, Mg²⁺, SO²⁻₄, HCO⁻₃, Cl⁻, As, Pb, Ni, Mn, Cr, Zn, Fe and U in the Kuplu and Guz stream waters were much higher than the world average values. The Dilaver, Gubi, Tepekoy, Maden, Celik and Abaza streams interact with sedimentary rocks, and the Kuplu and Guz streams interact with volcanic rocks. The amount of suspended sediment in the River Buyukmelen in December 2002 was 120 mg l⁻¹. The suspended and bed sediments in the muddy stream waters are formed of quartz, calcite, plagioclase, clay (kaolinite, illite and smectite), muscovite and amphibole minerals. As, Co, Cd, Cr, Pb, Ni, Zn and U have all accumulated in the Buyukmelen river‐bed sediments. The muddy feature of the waters is related to the petrographic features of the rocks in the basin and their mineralogical compositions, as most of the sandstones and volcanic rocks (basalt, tuffite and agglomerate) are decomposed to a clay‐rich composition at the surface. Thus, the suspended sediment in stream waters increases by physical weathering of the rocks and water–rock interaction. Owing to the growing population and industrialization, water demand is increasing. The plan is to bring water from the River Buyukmelen to Istanbul's drinking‐water reservoirs. According to the Water Pollution Regulations, the River Buyukmelen belongs to quality class 1 based on Hg, Cd, Pb, As, Cu, Cr, Zn, Mn, Se, Ba, Na⁺, Cl⁻, and SO²⁻₄; and to quality class 3 based on Fe concentration. The concentration of Fe in the River Buyukmelen exceeds the limit values permitted by the World Health Organization and the Turkish Standard. Because water from the River Buyukmelen will be used as drinking water, it will have an adverse effect on water quality and humans if not treated in advance. In addition, the inclusion of Mn and Zn in the Elmali drinking‐water reservoir of Istanbul and Fe in the River Buyukmelen water indicates natural inorganic contamination. Mn, Zn and Fe contents in the waters are related to geological origin. Moreover, the River Buyukmelen flow is very muddy in the rainy seasons and it is inevitable that this will pose problems during the purification process. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Failure and flow development of a collapse induced complex landslide: the 2005 Kuzulu (Koyulhisar, Turkey) landslide hazard   总被引：1，自引：0，他引：1  

Işık Yilmaz  Tülay Ekemen  Mustafa Yildirim  İnan Keskin  Gül Özdemir 《Environmental Geology》2006,49(3):467-476

Koyulhisar located in a slope of hilly region and constructed in the side of a mountain along the North Anatolian Fault Zone is frequently subject to landslides. A catastrophic landslide occurred on the morning of 17 March 2005 in the North of the Kuzulu district of Koyulhisar (Sivas, Turkey). This landslide caused widespread loss of life, and damage to buildings, and lifelines. Fifteen people were dead and five were injured, 21 houses and a minaret were covered and damaged severely. The case study presented in this paper describes and analyses the results of the detailed surveys of an interesting landslide in Kuzulu district of Koyulhisar (Sivas, Turkey), based on field and laboratory measurements and monitoring of the slide area. Landslide initiated as a collapse, and developed into debris avalanches in the valley. This phenomenon caused a disaster in the Kuzulu district. The importance of this landslide in particular has been recognized both in terms of its consequence for the people and structures and in terms of its role in allowing an understanding of process and properties of landslide triggered by a collapse in limestone karst. In view of the potential for such events to occur again in this area and environs, understanding of the failure mechanism is very crucial.  相似文献