Phyllocladane in brown coal from Handlová, Slovakia: Isolation and structural characterization     

Anton Zubrik  David Šaman  Soňa Vašíčková  Bernd R.T. Simoneit  L’udmila Turčániová  Michal Lovás  Josef Cvačka 《Organic Geochemistry》2009,40(1):126-134

Aliphatic diterpenes were isolated from brown coal from Handlová, Slovakia, using microwave assisted extraction of mechanically activated coal powder. The parameters of the extraction procedure were optimized to get the target compounds in high yield. The total extract was separated using adsorption chromatography. GC–MS revealed tetracyclic and tricyclic diterpanes in the aliphatic fraction; they were identified as 16α(H)-phyllocladane (83%), isopimarane (11%), 18-norisopimarane (4%), abietane (2%) and fichtelite (<0.1%). It was found that more than 2 g of the most abundant diterpane, 16α(H)-phyllocladane could be extracted from 1 kg of Handlová coal. Because of the scarcity of relevant analytical data, 16α(H)-phyllocladane was thoroughly characterized by spectroscopic and chromatographic methods. A complete set of ¹H and ¹³C NMR data is given including their comparison with published values and ab initio calculations. EI mass and IR spectra of 16α(H)-phyllocladane are shown and discussed. Kováts retention indices measured on two common GC stationary phases are also given.  相似文献   

Czech hydrometeorological institute limited-area operational forecast model     

Michal Baťka 《Studia Geophysica et Geodaetica》1991,35(2):109-124

Summary The CHMI LAOFM is used in the daily routine of the Central Forecasting Office of the Czech Hydrometeorological Institute and some special results are transmitted to the regional offices. The model works in the region of Europe and the North Atlantic, uses conservative finite difference schemes and two types of semi-implicit schemes that allow effective model structurization in terms of programming language. The basic philosophy of the model is described.

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Seasonal and interannual variability of the planktic foraminiferal flux in the vicinity of the Azores Current     

David Storz  Hartmut Schulz  Joanna J. Waniek  Detlef E. Schulz-Bull  Michal Kučera 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(1):107-124

Planktic foraminiferal (PF) flux and faunal composition from three sediment trap time series of 2002–2004 in the northeastern Atlantic show pronounced year-to-year variations despite similar sea surface temperature (SST). The averaged fauna of the in 2002/2003 is dominated by the species Globigerinita glutinata, whereas in 2003/2004 the averaged fauna is dominated by Globigerinoides ruber. We show that PF species respond primarily to productivity, triggered by the seasonal dynamics of vertical stratification of the upper water column. Multivariate statistical analysis reveals three distinct species groups, linked to bulk particle flux, to chlorophyll concentrations and to summer/fall oligotrophy with high SST and stratification. We speculate that the distinct nutrition strategies of strictly asymbiontic, facultatively symbiontic, and symbiontic species may play a key role in explaining their abundances and temporal succession. Advection of water masses within the Azores Current and species expatriation result in a highly diverse PF assemblage. The Azores Frontal Zone may have influenced the trap site in 2002, indicated by subsurface water cooling, by highest PF flux and high flux of the deep-dwelling species Globorotalia scitula. Similarity analyses with core top samples from the global ocean including 746 sites from the Atlantic suggest that the trap faunas have only poor analogs in the surface sediments. These differences have to be taken into account when estimating past oceanic properties from sediment PF data in the eastern subtropical North Atlantic.  相似文献   

Early Badenian ostracod assemblage of the ?idlochovice stratotype(Carpathian Foredeep, Czech Republic)     

Michal Seko  Radovan Pipík  Nela Doláková 《Central European Journal of Geosciences》2012,4(1):111-125

Fifty-two ostracod taxa were identified from two sediment cores collected from the early Badenian ?idlochovice stratotype. Ostracod assemblages were analyzed with a focus on taxonomy, paleoecology, distribution of taxa along the sediment cores, quantification of valve/carapace ratios, and species richness by Simpson??s Reciprocal Index. The changes in ostracod assemblages identified in these cores reflect a shallowing of the marine water-depth from circalittoral/epibathyal to shallow infralittoral, and an increase in the sedimentation rate upwards through time. A comparison of all Badenian ostracod assemblages in the Carpathian Foredeep indicates a high proportion of deep-water ostracod species in ?idlochovice and its surroundings, suggesting that the deepest part of the Carpathian Foredeep was probably situated in this part of the Czech Republic.  相似文献   

Stardust-NExT,Deep Impact,and the accelerating spin of 9P/Tempel 1     

Michael J.S. Belton  Karen J. Meech  Steven Chesley  Jana Pittichová  Brian Carcich  Michal Drahus  Alan Harris  Stephen Gillam  Joseph Veverka  Nicholas Mastrodemos  William Owen  Michael F. A’Hearn  S. Bagnulo  J. Bai  L. Barrera  Fabienne Bastien  James M. Bauer  J. Bedient  B.C. Bhatt  Hermann Boehnhardt  H. Zhao 《Icarus》2011,213(1):345-368

The evolution of the spin rate of Comet 9P/Tempel 1 through two perihelion passages (in 2000 and 2005) is determined from 1922 Earth-based observations taken over a period of 13 year as part of a World-Wide observing campaign and from 2888 observations taken over a period of 50 days from the Deep Impact spacecraft. We determine the following sidereal spin rates (periods): 209.023 ± 0.025°/dy (41.335 ± 0.005 h) prior to the 2000 perihelion passage, 210.448 ± 0.016°/dy (41.055 ± 0.003 h) for the interval between the 2000 and 2005 perihelion passages, 211.856 ± 0.030°/dy (40.783 ± 0.006 h) from Deep Impact photometry just prior to the 2005 perihelion passage, and 211.625 ± 0.012°/dy (40.827 ± 0.002 h) in the interval 2006–2010 following the 2005 perihelion passage. The period decreased by 16.8 ± 0.3 min during the 2000 passage and by 13.7 ± 0.2 min during the 2005 passage suggesting a secular decrease in the net torque. The change in spin rate is asymmetric with respect to perihelion with the maximum net torque being applied on approach to perihelion. The Deep Impact data alone show that the spin rate was increasing at a rate of 0.024 ± 0.003°/dy/dy at JD2453530.60510 (i.e., 25.134 dy before impact), which provides independent confirmation of the change seen in the Earth-based observations.The rotational phase of the nucleus at times before and after each perihelion and at the Deep Impact encounter is estimated based on the Thomas et al. (Thomas et al. [2007]. Icarus 187, 4–15) pole and longitude system. The possibility of a 180° error in the rotational phase is assessed and found to be significant. Analytical and physical modeling of the behavior of the spin rate through of each perihelion is presented and used as a basis to predict the rotational state of the nucleus at the time of the nominal (i.e., prior to February 2010) Stardust-NExT encounter on 2011 February 14 at 20:42.We find that a net torque in the range of 0.3–2.5 × 10⁷ kg m² s^?2 acts on the nucleus during perihelion passage. The spin rate initially slows down on approach to perihelion and then passes through a minimum. It then accelerates rapidly as it passes through perihelion eventually reaching a maximum post-perihelion. It then decreases to a stable value as the nucleus moves away from the Sun. We find that the pole direction is unlikely to precess by more than ～1° per perihelion passage. The trend of the period with time and the fact that the modeled peak torque occurs before perihelion are in agreement with published accounts of trends in water production rate and suggests that widespread H₂O out-gassing from the surface is largely responsible for the observed spin-up.  相似文献   

An epidemiological approach to determining the risk of road damage due to landslides     

Michal Bíl  Jan Kubeček  Richard Andrášik 《Natural Hazards》2014,73(3):1323-1335

Disruption of segments of roads can have a significant impact on the vulnerability of the entire network. Natural disasters are frequent causes of disruptions of this kind. This article focuses on determining the risk of road disruptions due to landslides. Our approach is based on methodology widely used in the field of epidemiology. We had available data on the location of the landslides, the road network and a list of the disrupted road segments. With the use of a 2 × 2 table, we determined the relationship between landslide data and road segment disruptions and derived the risk coefficient based on the number of landslides in the vicinity of the road and its length. The result is a disruption risk map with risk coefficients ranging from 0 to 47.94. In order to distinguish the most risky segments, we calculated a threshold of 12.40 with the use of a risk breakdown in a group of segments without damage. Nineteen percentage (402 km) of the road network in the Zlín region (Czech Republic), where the methodology was applied, is located beyond this threshold. The benefits of this approach stem from its speed and potential to define the most risky areas on which a detailed geomorphologic analysis can be focused.  相似文献   

Confirmation of Cometary Features of Newly Discovered Bodies     

Miloš Tichý  Jana Tichá  Michal Kočer 《Earth, Moon, and Planets》2002,90(1-4):507-513

The majority of new ground-based discoveries of comets comes from large surveys devoted, predominantly, to Near Earth Asteroids. The first step in distinguishing these newly discovered members of the population of cometary bodies consists inconfirmatory astrometric observations along with detection of their cometaryfeatures. Although both amateur and professional stations take part in suchconfirmatory observations, only some of them do a preliminary analysis of thecometary activity of a particular newly discovered body. A timely recognitionof cometary features of a particular body having an unusual orbit can help inplanning further observing campaigns.A main goals of the Klet Observatory NEO astrometric follow-upprogramme consists of an analysis of possible cometary activity of newlydiscovered unusual bodies. Here, we describe several examples (comets C/1999 S4 (LINEAR) and so on). We also mention an extension of our programme to fainterobjects after the completion ofa new 1-m telescope at the Klet Observatory.  相似文献   

A search for shocked quartz grains in the Allerød‐Younger Dryas boundary layer          下载免费PDF全文

Annelies Van Hoesel  Wim Z. Hoek  Gillian M. Pennock  Knut Kaiser  Oliver Plümper  Michal Jankowski  Maartje F. Hamers  Norbert Schlaak  Mathias Küster  Alexander V. Andronikov  Martyn R. Drury 《Meteoritics & planetary science》2015,50(3):483-498

The Younger Dryas impact hypothesis suggests that multiple airbursts or extraterrestrial impacts occurring at the end of the Allerød interstadial resulted in the Younger Dryas cold period. So far, no reproducible, diagnostic evidence has, however, been reported. Quartz grains containing planar deformation features (known as shocked quartz grains), are considered a reliable indicator for the occurrence of an extraterrestrial impact when found in a geological setting. Although alleged shocked quartz grains have been reported at a possible Allerød‐Younger Dryas boundary layer in Venezuela, the identification of shocked quartz in this layer is ambiguous. To test whether shocked quartz is indeed present in the proposed impact layer, we investigated the quartz fraction of multiple Allerød‐Younger Dryas boundary layers from Europe and North America, where proposed impact markers have been reported. Grains were analyzed using a combination of light and electron microscopy techniques. All samples contained a variable amount of quartz grains with (sub)planar microstructures, often tectonic deformation lamellae. A total of one quartz grain containing planar deformation features was found in our samples. This shocked quartz grain comes from the Usselo palaeosol at Geldrop Aalsterhut, the Netherlands. Scanning electron microscopy cathodoluminescence imaging and transmission electron microscopy imaging, however, show that the planar deformation features in this grain are healed and thus likely to be older than the Allerød‐Younger Dryas boundary. We suggest that this grain was possibly eroded from an older crater or distal ejecta layer and later redeposited in the European sandbelt. The single shocked quartz grain at this moment thus cannot be used to support the Younger Dryas impact hypothesis.  相似文献   

How can stream bank erosion be predicted on small water courses? Verification of BANCS model on the Kubrica watershed     

Zuzana Allmanova  Maria Vlckov  Martin Jankovský  Michal Allman  Jan Merganic 《国际泥沙研究》2021,36(3):419-429

The current paper deals with the evaluation of the BANCS erosion prediction model and its two componentsethe Bank Erosion Hazard Index(BEHI)and Near-Bank Stress(NBS)indices.To construct the erosion prediction curves,18 experimental sections were established on the Kubrica Stream,district of Trencín,Slovakia.Each section was assessed through the NBS index and BEHI index and real annual bank erosion was measured using erosion toe pins.Subsequently,the relations between the BEHI and real annual bank erosion was assessed through regression and correlation analyses.The relation proved to be moderately strong,with the correlation coefficient(R)reaching 0.47.Further,the relation between the NBS index and real annual bank erosion was evaluated,which was also moderately strong,with R=0.65.Based on the measured data,two erosion prediction curves were constructed,the first for moderate BEHI,with R=0.69 and coefficient of determination(R2)of 0.47 and the second for high BEHI with R=0.74 and R2=0.55.The prediction curves were based on data from one year of measurements and can,therefore,be used only for discharges that occurred within that year and in the region where the model was developed.In the current case,according to runoff Curve Numbers(CN),the real culmination discharge was Q=1.88 m3/s,which is roughly equivalent to 1.5-year recurrence interval flow(Q1.5).  相似文献   

Solving the nonstationary Richards equation with adaptive hp-FEM     

Pavel Solin  Michal Kuraz 《Advances in water resources》2011,34(9):1062-1081

This paper examines the potential of the adaptive hp-FEM method for the numerical solution of time-dependent variably saturated Darcian flow problems described by the Richards equation. The method is illustrated on three model problems: a benchmark with known exact solution, groundwater seepage into a dry lysimeter box with time-dependent boundary conditions, and capillary barrier behavior under an intense infiltration. In the second part of the paper we present the weak formulation of the Richards equation for the Newton’s and Picard’s methods, give a brief overview of adaptive hp-FEM with emphasis on aspects that are usually not discussed in the literature, and we briefly introduce the open source adaptive hp-FEM library HERMES that was used to generate numerical results for this paper. All computations that we present are easily reproducible.  相似文献