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41.
Quantum-thermodynamic treatment of intrinsic anharmonicity; Wallace’s theorem revisited 总被引:1,自引:0,他引:1
Wallace (in Thermodynamics of crystals, 1972) developed a theorem, rooted in rigid lattice dynamics, which incorporates intrinsic anharmonic effects in solids. The practical
application of this theorem in mineral physics is computationally involved and this is the main reason for the theorem not
getting the attention it deserves. Because intrinsic anharmonicity is an important issue at the extreme conditions in planetary
mantles, we derived a method which removes the computational obstacles in applying this theorem. We extended the theorem to
incorporate details of the phonon spectrum and tested our algorithm on forsterite (Mg2SiO4). Using a least squares inversion technique applied to all available experimental data, we show that it results in an accurate
representation of thermodynamic properties and sound wave velocities of Mg2SiO4 in its complete pressure–temperature stability range. We also show that the accuracy of our results is not significantly
affected by the use of a different equation of state. 相似文献
42.
This paper briefly reviews the sociological literature on the “New” Chinatown phenomenon stressing its structural location
vis-à-vis the “Old” Chinatown and the homeland. It defines the New Chinatown as a panethnopolis, that is a global neighborhood
with a majority population of Chinese immigrants and of other ethnic groups of mostly Asian descent. It analyzes more particularly
the formation, development, and integration of San Francisco’s Richmond District’s New Chinatown into both the city where
it is located and the network of transglobal sites to which it belongs. It provides an interpretation of the New Chinatown
as a cultural enclave within the context of globalization theory. 相似文献
43.
Michel Magny Matthieu Honegger et Laurent Chalumeau 《Eclogae Geologicae Helvetiae》2005,98(2):249-259
Resume. Les fouilles archéologiques réalisées de 1998 à 2002 sur le site néolithique de Marin-Les Piécettes sur la rive nord-ouest
du lac de Neuchatel ont offert l’opportunité d’observer deux séquences sédimentaires intéressantes pour la reconstitution
des variations holocènes du niveau du lac, en particulier au cours de la période correspondant au changement de cours de l’Aar
en direction du nord-est, vers 5650–5500 cal BP. La géométrie des corps sédimentaires et les changements lithologiques permettent
de reconna?tre plusieurs phases majeures de bas niveaux relatifs du plan d’eau vers 6870, 5660, 5060–3990, 3580, 2280, 1640
et 1170 cal BP. Le site néolithique de Marin-Les Piécettes s’est développé vers 5454–5433 cal BP à la faveur d’un court épisode
de bas niveau du lac qui a interrompu une importante phase de haut niveau au début du Subboréal. Les événements paléohydrologiques
identifiés à Marin-Les Piécettes apparaissent cohérents avec ceux reconstitués sur le site de Montilier au bord du lac de
Morat, ainsi qu’avec les variations paléohydrologiques reconstituées à partir des lacs du Jura, du Plateau suisse et des Préalpes
du Nord fran?aises. Ceci suggère qu’ils témoignent d’un signal climatique. La séquence sédimentaire de Marin-Les Piécettes
met enfin en évidence la formation d’un cordon littoral sur la rive nord-ouest du lac juste après 5660 cal BP.
Manuscrit re?u le 22 septembre 2004 Révision acceptée le 11 mars 2005 相似文献
44.
45.
Derek G. Turner Brent C. Ward Duane G. Froese Michel Lamothe Jeffrey D. Bond Nancy H. Bigelow 《Boreas: An International Journal of Quaternary Research》2016,45(3):521-536
At least five Middle to Late Pleistocene advances of the northern Cordilleran Ice Sheet are preserved at Silver Creek, on the northeastern edge of the St Elias Mountains in southwest Yukon, Canada. Silver Creek is located 100 km up‐ice of the Marine Isotope Stage (MIS) 2 McConnell glacial limit of the St Elias lobe. This site contains ~3 km of nearly continuous lateral exposure of glacial and non‐glacial sediments, including multiple tills separated by thick gravel, loess and tilted lake beds. Infrared‐stimulated luminescence (IRSL) and AMS radiocarbon dating constrain the glacial deposits to MIS 2, 4, either MIS 6 or mid‐MIS 7, and two older Middle Pleistocene advances. This chronology and the tilt of the lake beds suggest Pleistocene uplift rates of up to 1.9 mm a?1 along the Denali Fault since MIS 7. The non‐glacial sediment consists of sand, gravel, loess and organic beds from MIS 7, MIS 3 and the early Holocene. The MIS 3 deposits date to between 30–36 14C ka BP, making Silver Creek one of the few well‐constrained MIS 3‐aged sites in Yukon. This confirms that ice receded close to modern limits in MIS 3. Pollen and macrofossil analyses show that a meadow‐tundra to steppe‐tundra mosaic with abundant herbs and forbs and few shrubs or trees, dominated the environment at this time. The stratigraphy at Silver Creek provides a palaeoclimatic record since at least MIS 8 and comprises the oldest direct record of Pleistocene glaciation in southwest Yukon. 相似文献
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49.
Charles L. Curry Bárbara Tencer Kirien Whan Andrew J. Weaver Michel Giguère Edward Wiebe 《大气与海洋》2016,54(4):364-384
We evaluate the capacity of a regional climate model to represent observed extreme temperature and precipitation events and also examine the impact of increased resolution, in an effort to identify added value in this respect. Two climate simulations of western Canada (WCan) were conducted with the Canadian Regional Climate Model (version 4) at 15 (CRCM15) and 45?km (CRCM45) horizontal resolution driven at the lateral boundaries by data from the European Centre for Medium-range Weather Forecasts (ECMWF) 40-year Reanalysis (ERA-40) for the period 1973–1995. The simulations were evaluated using the spline-interpolated dataset ANUSPLIN, a daily observational gridded surface temperature and precipitation product with a nominal resolution of approximately 10?km. We examine a range of climate extremes, comprising the 10th and 90th percentiles of daily maximum (TX) and minimum (TN) temperatures, the 90th percentile of daily precipitation (PR90), and the 27 core Climate Daily Extremes (CLIMDEX) indices.Both simulations exhibit cold biases compared with observations over WCan, with the bias exacerbated at higher resolution, suggesting little added value for temperature overall. There are instances, however, of regional improvement in the spatial pattern of temperature extremes at the higher resolution of CRCM15 (e.g., the CLIMDEX index for the annual number of days when TX?>?25°C). The high-resolution simulations also reveal similarly localized features in precipitation (e.g., rain shadows) that are not resolved at the 45?km resolution. With regard to precipitation extremes, although both simulations generally display wet biases, CRCM15 features a reduced bias in PR90 in all seasons except winter. This improvement occurs despite the fact that spatial and interannual variability of PR90 in CRCM15 is significantly overestimated relative to both CRCM45 and ANUSPLIN. We posit that these characteristics are the result of demonstrable differences between corresponding topographical datasets used in the gridded observations and CRCM, the resulting errors propagated to physical variables tied to elevation and the beneficial effect of subsequent spatial averaging. Because topographical input is often discordant between simulations and gridded observations, it is argued that a limited form of spatial averaging may contribute added value beyond that which has already been noted in previous studies with respect to small-scale climate variability. 相似文献
50.
Chris Bataille Henri Waisman Michel Colombier Laura Segafredo Jim Williams Frank Jotzo 《Climate Policy》2016,16(4):S7-S26
Constraining global average temperatures to 2 °C above pre-industrial levels will probably require global energy system emissions to be halved by 2050 and complete decarbonization by 2100. In the nationally orientated climate policy framework codified under the Paris Agreement, each nation must decide the scale and method of their emissions reduction contribution while remaining consistent with the global carbon budget. This policy process will require engagement amongst a wide range of stakeholders who have very different visions for the physical implementation of deep decarbonization. The Deep Decarbonization Pathways Project (DDPP) has developed a methodology, building on the energy, climate and economics literature, to structure these debates based on the following principles: country-scale analysis to capture specific physical, economic and political circumstances to maximize policy relevance, a long-term perspective to harmonize short-term decisions with the long-term objective and detailed sectoral analysis with transparent representation of emissions drivers through a common accounting framework or ‘dashboard’. These principles are operationalized in the creation of deep decarbonization pathways (DDPs), which involve technically detailed, sector-by-sector maps of each country’s decarbonization transition, backcasting feasible pathways from 2050 end points. This article shows how the sixteen DDPP country teams, covering 74% of global energy system emissions, used this method to collectively restrain emissions to a level consistent with the 2 °C target while maintaining development aspirations and reflecting national circumstances, mainly through efficiency, decarbonization of energy carriers (e.g. electricity, hydrogen, biofuels and synthetic gas) and switching to these carriers. The cross-cutting analysis of country scenarios reveals important enabling conditions for the transformation, pertaining to technology research and development, investment, trade and global and national policies.Policy relevanceIn the nation-focused global climate policy framework codified in the Paris Agreement, the purpose of the DDPP and DDPs is to provide a common method by which global and national governments, business, civil society and researchers in each country can communicate, compare and debate differing concrete visions for deep decarbonization in order to underpin the necessary societal and political consensus to design and implement short-term policy packages that are consistent with long-term global decarbonization. 相似文献