Laboratory simulations of prebiotic molecule stability in the jarosite mineral group; end member evaluation of detection and decomposition behavior related to Mars sample return     

J. Michelle Kotler  C. Doc Richardson  Jill R. Scott 《Planetary and Space Science》2009,57(12):1381-1388

Recently, the prebiotic amino acid glycine has been found associated with natural jarosite samples from locations around the world. Since the discovery of jarosite on Mars, extensive research focuses on linking this mineral group with possible detection of biosignatures in the geologic record on Earth and Mars. Multiple analytical methods, including extraction and mass spectrometry techniques, have identified glycine and other biomolecules in jarosite samples. The jarosite end members jarosite (sensu stricto-potassium jarosite), natrojarosite (sodium jarosite), and ammoniojarosite (ammonium jarosite) have different thermodynamic stabilities, decompose at different rates, and have potentially different susceptibilities to substitution. The relationship between the thermodynamic stability of the jarosite end members and the effect that glycine has on the thermal decomposition behavior of each end member was investigated using thermal gravimetric analysis. Introducing glycine into the synthesis procedure (75 ppm) of the potassium, sodium, and ammonium jarosite end member has elucidated the effects that glycine has on the thermal stability of the mineral group. Potassium jarosite appears to be the least susceptible to the effects of glycine, with the sodium and ammonium end members showing marked changes in thermal decomposition behavior and decomposition rates. These results suggest that the sodium and ammonium jarosites are more suitable targets for identifying signs of prebiotic or biotic activity on Mars and Earth than the potassium jarosites. These results have implications for current in situ investigations of the martian surface and future sample return missions.  相似文献   

Modern Sphagnumδ13C signatures follow a surface moisture gradient in two boreal peat bogs,James Bay lowlands,Québec     

Julie Loisel  Michelle Garneau  Jean‐François Hélie 《第四纪科学杂志》2009,24(3):209-214

Carbon isotopic composition of Sphagnum macrofossils can potentially be used as a palaeohydrological tool for peat‐based climatic studies since a relationship between Sphagnum δ¹³C values and peatland surface moisture has been presented in previous studies. In order to verify this hypothesis, modern Sphagnum δ¹³C values were measured along a moisture (microtopographic) gradient in two boreal peat bogs. Isotopic measurements were performed on bulk material of S. fuscum, S. magellanicum, S. capillifolium and S. pulchrum. Isotopic variations found within and between Sphagnum species along the microtopographic gradient were compared using analysis of variance. A significant positive correlation (P < 0.0001) was found between Sphagnum δ¹³C values and their position along the surface moisture gradient. Results show that ¹³C‐depleted values are related to low water table depths (WTD), while ¹³C‐enriched values correspond to a water table that is close to the peat surface. Although the mechanisms underlying carbon fractionation processes in mosses are not well understood, we demonstrate that water resistance to CO₂ diffusion is an important fractionation process that is observed in bulk Sphagnum δ¹³C measurements, since drier and wetter samples exhibit consistent and very different isotopic signatures. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Advance,deglacial and sea‐level chronology for Foxe Peninsula,Baffin Island,Nunavut          下载免费PDF全文

Daniel J. Utting  John C. Gosse  Samuel E. Kelley  Kayla J. Vickers  Brent C. Ward  Michelle S. Trommelen 《Boreas: An International Journal of Quaternary Research》2016,45(3):439-454

The impact of the Laurentide Ice Sheet (LIS) deglaciation on Northern Hemisphere early Holocene climate can be evaluated only once a detailed chronology of ice history and sea‐level change is established. Foxe Peninsula is ideally situated on the northern boundary of Hudson Strait, and preserves a chronostratigraphy that provides important glaciological insights regarding changes in ice‐sheet position and relative sea level before and after the 8.2 ka cooling event. We utilized a combination of radiocarbon ages, adjusted with a new locally derived ΔR, and terrestrial in‐situ cosmogenic nuclide (TCN) exposure ages to develop a chronology for early‐Holocene events in the northern Hudson Strait. A marine limit at 192 m a.s.l., dated at 8.1–7.9 cal. ka BP, provides the timing of deglaciation following the 8.2 ka event, confirming that ice persisted at least north of Hudson Bay until then. A moraine complex and esker morphosequence, the Foxe Moraine, relates to glaciomarine outwash deltas and beaches at 160 m a.s.l., and is tightly dated at 7.6 cal. ka BP with a combination of shell dates and exposure ages on boulders. The final rapid collapse of Foxe Peninsula ice occurred by 7.1–6.9 cal. ka BP (radiocarbon dates and TCN depth profile age on an outwash delta), which supports the hypothesis that LIS melting contributed to the contemporaneous global sea‐level rise known as the Catastrophic Rise Event 3 (CRE‐3).  相似文献   

The effect of habitat and environmental history on otolith chemistry of barramundi Lates calcarifer in estuarine populations of a regulated tropical river     

David Milton  Ian Halliday  Michelle Sellin  Richard Marsh  Jonathan Staunton-Smith  Jon Woodhead 《Estuarine, Coastal and Shelf Science》2008

We examine the microchemistry of otoliths of cohorts of a fished population of the large catadromous fish, barramundi Lates calcarifer from the estuary of a large tropical river. Barramundi from the estuary of the large, heavily regulated Fitzroy River, north-eastern Australia were analysed by making transects of ⁸⁷Sr/⁸⁶Sr isotope and trace metal/Ca ratios from the core to the outer edge. Firstly, we examined the Sr/Ca, Ba/Ca, Mg/Ca and Mn/Ca and ⁸⁷Sr/⁸⁶Sr isotope ratios in otoliths of barramundi tagged in either freshwater or estuarine habitats that were caught by the commercial fishery in the estuary. We used ⁸⁷Sr/⁸⁶Sr isotope ratios to identify periods of freshwater residency and assess whether trace metal/Ca ratios varied between habitats. Only Sr/Ca consistently varied between known periods of estuarine or freshwater residency. The relationships between trace metal/Ca and river flow, salinity, temperature were examined in fish tagged and recaptured in the estuary. We found weak and inconsistent patterns in relationships between these variables in the majority of fish. These results suggest that both individual movement history within the estuary and the scale of environmental monitoring were reducing our ability to detect any patterns. Finally, we examined fish in the estuary from two dominant age cohorts (4 and 7 year old) before and after a large flood in 2003 to ascertain if the flood had enabled fish from freshwater habitats to migrate to the estuary. There was no difference in the proportion of fish in the estuary that had accessed freshwater after the flood. Instead, we found that larger individuals with of each age cohort were more likely to have spent a period in freshwater. This highlights the need to maintain freshwater flows in rivers. About half the fish examined had accessed freshwater habitats before capture. Of these, all had spent at least their first two months in marine salinity waters before entering freshwater and some did not enter freshwater until four years of age. This contrasts with the results of several previous studies in other parts of the range that found that access to freshwater swamps by larval barramundi was important for enhanced population productivity and recruitment.  相似文献   

Young-of-the-year oyster,Crassostrea virginica,reproduction in coastal Georgia     

Francis X. O’Beirn  Peter B. Heffernan  Randal L. Walker  Michelle L. Jansen 《Estuaries and Coasts》1996,19(3):651-658

Young-of-the-year (YOY) oysters (Crassostrea virginica) in the Gulf of Mexico mature sexually and spawn in their first year. This study determined whether YOY oysters in the southeastern United States also mature and spawn in their first year. In 1991 and 1993, 300 YOY oysters were marked in May and 20–30 were sampled in subsequent months along with 20 adult controls. Two sites were chosen in 1991 (House Creek and Skidaway River) and one in 1993 (Skidaway River). At House Creek, YOY oysters were mature and spawned in September. YOY oysters at Skidaway spawned in October. Adult oysters did not appear to spawn in 1991. In 1993, the adult oysters spawned in August and September whereas, the YOY oysters spawned heavily in October. Oyster recruitment in coastal Georgia extends through October. The potential contribution of YOY oysters to this late season set is substantial, given that the YOY oysters are relatively large (≈4 cm) and are found in greater numbers than the adults. Oysters are capable of having two, if not more, generations within one year, prior to exposure of disease-causing organisms. Also, this particular reproductive strategy would increase the oysters suitability as a test subject in population genetic studies.  相似文献   

From data gathering to resources assessment: A holistic view of petroleum geology     

Hernani A. F. Chaves  M. Effie Lewis 《Natural Resources Research》1994,3(1):72-82

To integrate geological data to obtain an interpretation of the geology and natural resources of an area, we need a methodology that provides a holistic approach, addressing all basic issues in geological relations as well as uncertainties that arise with the evolution of basic geological knowledge of an area.In spite of the major role played by geoinformatics—the application of mathematics, statistics, and computer science to solve geological problems—we do not yet have a properly designed method for organizing geological data, including raw data, conceptual models, modeling results, and geological integration. Such a rapid method should provide for updating of existing interpretations based on new data or new theories.A systematic view of data integration and interpretation is important in petroleum exploration and petroleum engineering. We point out the more striking tools already available but of restricted use and some of the possible solutions for known problems that still require research and development.  相似文献   

Statistical analysis of the microlithotype sequences in the Bulli Seam, Australia, and relevance to permeability for coal gas     

Michelle Smyth  Michael J. Buckley 《International Journal of Coal Geology》1993,22(3-4)

Sequential microlithotype analyses through the Permian Bulli Coal, Sydney Basin, Australia, enable determination of the abundance, locations and thicknesses of various microlithotypes in the seam. Statistical analyses allow prediction of these parameters. Microlithotype analyses may be used as a means of predicting seam permeability in relation to coal gas drainage, if used in conjunction with reported correlation between coal type and seam reservoir properties.A combination of sequential microlithotype analyses and statistical modelling provide data on the number, location and thicknesses of individual bands of vitrite, vitrinertite, inertite and mineral-rich coal. A Markov chain describes both the order and thickness of the bands in the seam. Local ordering of microlithotypes is similar, irrespective of vertical orientation, which suggests that analyses and predictions may be possible using representative, randomly oriented samples. Statistical modelling can be used to characterise the seam using a small number of parameters. These include the elements of the transition probability matrix of the Markov chain, from which many seam properties such as maximum band thickness, thickness distribution of bands and spacing of thick bands can be predicted.The permeability of vitrite-rich coal in the seam is 30 mD and it is 2.3 mD for inertite-rich coal. In general, for the Bulli seam, vitrite-rich plies are expected to provide better flow paths for coal gas than inertite-rich plies, because of the abundance of cleat systems in vitrite. Using this information, it thus may be possible to predict gas and water flow paths in a seam from microlithotype analyses, thereby leading to the development of a rapid method for assessing the comparative permeabilities of coal plies.  相似文献   

Geochemical effects on metals following permanganate oxidation of DNAPLs   总被引：2，自引：0，他引：2  

Crimi ML  Siegrist RL 《Ground water》2003,41(4):458-469

The application of in situ chemical oxidation for dense, nonaqueous phase liquid (DNAPL) remediation requires delivery of substantial levels of oxidant chemicals into the subsurface to degrade target DNAPLs and to satisfy natural oxidant demand. This practice can raise questions regarding changes in subsurface conditions, yet information regarding potential effects, especially at the field scale, has been lacking. This paper describes an evaluation of the effects on metals associated with in situ chemical oxidation using potassium permanganate at Launch Complex 34 (LC34), Cape Canaveral Air Station, Florida. At LC34, high concentrations of permanganate (1 to 2 wt%) were injected into the subsurface as part of a demonstration of DNAPL remediation technologies. In a companion experimental effort at the Colorado School of Mines, field samples were characterized and laboratory batch and mini-column studies were completed to assess effects of permanganate oxidation on metals in the subsurface one year after completion of the field demonstration. Results indicated there was potential for long-term immobilization of a portion of introduced manganese and no treatment-induced loss in subsurface permeability due to deposition of manganese oxides particles, which are a product of the oxidation reactions. Permanganate treatment did cause elevated manganese, chromium, and nickel concentrations in site ground water within the treated region. Some of these metals effects can be attenuated during downgradient flow through uncontaminated and untreated aquifer sediments.  相似文献   

Seasonal variation of the diurnal cycle of rainfall in the eastern equatorial Indian Ocean     

M. R. Ramesh Kumar  S. M. Pednekar  M. Katsumata  M. K. Antony  Y. Kuroda  A. S. Unnikrishnan 《Theoretical and Applied Climatology》2006,85(1-2):117-122

Summary The diurnal cycle of rainfall over the eastern equatorial Indian Ocean was studied for the period 23^rd October 2001 to 31^st October 2003 using hourly data from the Triton buoy positioned at 1.5° S and 90° E. An analysis of the active and weak spells of rainfall for different seasons revealed peaks in the late evening hours in Winter, Summer and Fall and in early morning hours (in Spring) in 2002. The active spell of rainfall peaked in the afternoon hours, during Winter, Spring and Summer in 2003, which agrees with the previous results of Janowiak et al. (1994). An analysis of rainfall events showed that Fall 2002 had a maximum number of rainfall events (90) and minimum (60) were observed in Spring 2003. Further it was found that the majority of rain events (>60%) were less than 3 hours in duration throughout the study period. The longer duration rainfall events (i.e. rain events greater than 6 hour duration) contributed significantly to Spring 2002 (20% of the total rainfall) and Winter 2003 (21% of the total rainfall). Harmonic analysis of the hourly rainfall data for different seasons revealed that diurnal harmonic explains more than 80% of the variance for all seasons. Furthermore, the diurnal harmonic has a maximum amplitude for all seasons except summer, where the semidiurnal and six hourly harmonics are significant.  相似文献   

Quantifying PCE and TCE in DNAPL Source Zones: Effects of Sampling Methods Used for Intact Cores at Varied Contaminant Levels and Media Temperatures   总被引：1，自引：0，他引：1  

Robert L. Siegrist  Kathryn S. Lowe  Michelle L. Crimi  Michael A. Urynowicz 《Ground Water Monitoring & Remediation》2006,26(2):114-124

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