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61.
Playa lake systems tend to be overlooked archives of paleoenvironmental change due to the likelihood of a short and intermittent record of deposition. Groundwater-fed wetlands associated with these climate-sensitive playas, however, preserve changes in hydrologic budget and are thus valuable archives for semiarid regions. This study examines the paleoecological record of a groundwater-fed wetland from Lake Solai, Kenya. Biological proxies are used to reconstruct paleoenvironmental change and climate impacts over the past millennium. Dry conditions persisted between CE 1115 and 1490, followed by wetter conditions during the Little Ice Age. Near surface sediments indicate increasing anthropogenic impact through pastoralism.  相似文献   
62.
An ion exchange technique has been used to determine the copper complexing capacity (CuCC) of strong organic complexing agents at 21 stations across the continental shelf of the southeastern United States and in the western Sargasso Sea. The concentration of dissolved organic carbon (DOC) and total particulate materal (TPM), two pools of potential complexing agents, was also measured at each station. The CuCC ranged from 0.014 to 1.681 μM Cu dm−3 on the inner shelf, from 0.043 to 0.095 μM Cu dm−3 in mid and outer shelf waters, and from < 0.010 to 0.036 μM Cu dm−3 at the Sargasso Sea stations. The correlation between CuCC and both DOC and TPM is highly significant (α < 0.01). Two synoptic surveys of the distribution of DOC and TPM across the shelf showed that DOC ranges from > 3 mg C dm−3 nearshore to <1 mg C dm−3 offshore and that TPM ranges from > 50 mg dm−3 nearshore to <1 mg dm−3 offshore. Both TPM and DOC are most variable on the inner shelf. These data are consistent with CuCC data which indicate that the CuCC of inner shelf waters was relatively high and very heterogeneous. In contrast, DOC, TPM and copper complexing capacity are low and nearly invariant at the Sargasso Sea stations. We present a model of the distribution of complexing agents in different marine environments and hypothesize that the mechanisms underlying differences between environments relate to differences in the source(s) and nature of complexing agents in each system.  相似文献   
63.
Marine protected areas in Puerto Rico: Historical and current perspectives   总被引:1,自引:0,他引:1  
In Puerto Rico, the environmental legislation for establishing marine protected areas (MPAs) is complex due to its current political position with the United States (US) as not only local but also federal US laws affect designations. Historically, during the Spanish rule, mangrove forests were protected for extractive reasons (i.e., charcoal) and the first protected area was established by 1918 as an Insular Forest. Currently, of the 37 MPAs recognized and investigated in this work, the vast majority (73%) are Natural Reserves, followed by Commonwealth Forests (13.5%). Most MPAs in Puerto Rico were implemented using a top-down approach (i.e., government) which follows US federal guidelines for protecting endangered species, critical habitats, and natural and cultural resources. The development of management plans for MPAs on the island is increasingly adopting a public participatory process. However, this latter process is new for the government of Puerto Rico that has not incorporated a policy based on an Integrated Coastal Management.  相似文献   
64.
We studied the effects of low-frequency climate change on the reproductive performance of 11 species of marine bird in the southern California Current system, 1969–1997. Reproductive performance of Brown Pelican (Pelecanus occidentalis) and Double-crested Cormorant (Phalacrocrax auritus) in southern California demonstrated an increase in the 1970s and early 1980s, attributable to recovery from organochlorine contamination (primarily DDE). Brandt's Cormorant (Phalacrocorax penicillatus) in central California was the only species to demonstrate a secular increase in performance through time, a pattern that remains unexplained. Ashy Storm-petrel (Oceanodroma homochroa) and Pelagic Cormorant (Phalacrocorax pelagicus) demonstrated curvilinear patterns of change, with decreasing reproductive performance in the past decade. All other species including Western Gull (Larus occidentalis), Pigeon Guillemot (Cepphus columba), Xantus's Murrelet (Synthiloboramphus hypoleucus), Common Murre (Uria aalge), Cassin's Auklet (Ptychoramphus aleuticus) and Rhinoceros Auklet (Cerorhinca monocerata) showed diminishing reproductive performance through time. Patterns of change for the murre and auklets were not significant, presumably because of a lack of reproductive variation for these species, which display a conservative breeding effort (i.e. single-egg clutches). Changes in the birds' abilities to provision young and maintain chick survival during May–July each year appeared most closely related to overall changes in reproductive performance. Dietary change indicated a decline in use of juvenile rockfish (Sebastes spp.) by marine birds in central California. There was also significant interannual variability in consumption of juvenile rockfish and the euphausiid Thysanoessa spinifera. Patterns of change in marine bird reproductive performance were generally concordant between southern and central California after considering the period of recovery for Brown Pelican and Double-crested Cormorant. The decline in reproductive performance and changes in diet composition do not appear directly related to the polarity reversal of the Pacific Decadal Oscillation in 1976/1977. Instead, reproductive performance and dietary characteristics indicate substantial change in the late 1980s, suggesting another regime-shift at that time.  相似文献   
65.
Proxy reconstructions of climatic parameters developed using transfer functions are central to the testing of many palaeoclimatic hypotheses on Holocene timescales. However, recent work shows that the mathematical models underpinning many existing transfer functions are susceptible to spatial autocorrelation, clustered training set design and the uneven sampling of environmental gradients. This may result in over‐optimistic performance statistics or, in extreme cases, a lack of predictive power. A new testate amoeba‐based transfer function is presented that fully incorporates the new recommended statistical tests to address these issues. Leave‐one‐out cross‐validation, the most commonly applied method in recent studies to assess model performance, produced over‐optimistic performance statistics for all models tested. However, the preferred model, developed using weighted averaging with tolerance downweighting, retained a predictive capacity equivalent to other published models even when less optimistic performance statistics were chosen. Application of the new statistical tests in the development of transfer functions provides a more thorough assessment of performance and greater confidence in reconstructions based on them. Only when the wider research community have sufficient confidence in transfer function‐based proxy reconstructions will they be commonly used in data comparison and palaeoclimate modelling studies of broader scientific relevance. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
66.
Modeling effects of multinode wells on solute transport   总被引:1,自引:0,他引:1  
Long-screen wells or long open boreholes with intraborehole flow potentially provide pathways for contaminants to move from one location to another in a ground water flow system. Such wells also can perturb a flow field so that the well will not provide water samples that are representative of ground water quality a short distance away from the well. A methodology is presented to accurately and efficiently simulate solute transport in ground water systems that include wells longer than the grid spacing used in a simulation model of the system and hence are connected to multiple nodes of the grid. The methods are implemented in a MODFLOW-compatible solute-transport model and use MODFLOW's Multi-Node Well Package but are generic and can be readily implemented in other solute-transport models. For nonpumping multinode wells (used to simulate open boreholes or observation wells, for example) and for low-rate pumping wells (in which the flow between the well and the ground water system is not unidirectional), a simple routing and local mixing model was developed to calculate nodal concentrations within the borehole. For high-rate pumping multinode wells (either withdrawal or injection, in which flow between the well and the ground water system is in the same direction at all well nodes), complete and instantaneous mixing in the wellbore of all inflows is assumed.  相似文献   
67.
Formation of mountains on Io: Variable volcanism and thermal stresses   总被引:1,自引:0,他引:1  
Thermal stresses are potentially important drivers of Io's tectonics and mountain building. It has been hypothesized that sustained local or regional shut down of heat-pipe volcanism on Io could lead to deep crustal heating and large compressive stresses [McKinnon, W.B., Schenk, P.M., Dombard, A.J., 2001. Geology 29, 103-106]. Such large stresses would then be relieved by thrust faulting and uplifting of crustal blocks, producing mountains like those observed on Io. Here we analyze the tectonic consequences of the heat-pipe model in detail, considering both the initial thermal stress state of a basalt or peridotite crust created by heat-pipe volcanism, and relative roles of subsidence stresses (due to burial of preexisting layers) and thermal stresses arising from variable volcanism and changes in crustal (∼lithosphere) thickness. We limit the magnitude of the potential subsidence stresses in our study, because the magnitude of subsidence stresses can be quite large, if not dominant. Results indicate that for a fixed crustal thickness, the region of failure and faulting moves closer to the surface as eruption rate decreases and time increases. When the crust melts at its base as volcanism decreases (as might occur under steady state tidal heating), resulting in crustal thinning, the region of failure is brought even closer to the surface. Naturally, when compressive, subsidence stresses are included, the vertical extent of crust in brittle failure thickens to include most of the lithosphere. In contrast, increases in eruption rate cause the extent of the region in compressional failure to decrease and be driven very deep in the crust (in the absence of sufficient subsidence stress). Therefore, regions of declining volcanism are more likely to produce mountains, whereas regions of extensive or increasing volcanism are less likely to do so. This is consistent with the observation of a global anticorrelation between mountains and volcanic centers on Io. Finally, we find that the choice of crustal composition/rheology (dry basalt vs. dry peridotite) has little effect on our results implying that basalt, peridotite and komatiite are all similarly “stiff” in the Io environment.  相似文献   
68.
Recently, the prebiotic amino acid glycine has been found associated with natural jarosite samples from locations around the world. Since the discovery of jarosite on Mars, extensive research focuses on linking this mineral group with possible detection of biosignatures in the geologic record on Earth and Mars. Multiple analytical methods, including extraction and mass spectrometry techniques, have identified glycine and other biomolecules in jarosite samples. The jarosite end members jarosite (sensu stricto-potassium jarosite), natrojarosite (sodium jarosite), and ammoniojarosite (ammonium jarosite) have different thermodynamic stabilities, decompose at different rates, and have potentially different susceptibilities to substitution. The relationship between the thermodynamic stability of the jarosite end members and the effect that glycine has on the thermal decomposition behavior of each end member was investigated using thermal gravimetric analysis. Introducing glycine into the synthesis procedure (75 ppm) of the potassium, sodium, and ammonium jarosite end member has elucidated the effects that glycine has on the thermal stability of the mineral group. Potassium jarosite appears to be the least susceptible to the effects of glycine, with the sodium and ammonium end members showing marked changes in thermal decomposition behavior and decomposition rates. These results suggest that the sodium and ammonium jarosites are more suitable targets for identifying signs of prebiotic or biotic activity on Mars and Earth than the potassium jarosites. These results have implications for current in situ investigations of the martian surface and future sample return missions.  相似文献   
69.
Carbon isotopic composition of Sphagnum macrofossils can potentially be used as a palaeohydrological tool for peat‐based climatic studies since a relationship between Sphagnum δ13C values and peatland surface moisture has been presented in previous studies. In order to verify this hypothesis, modern Sphagnum δ13C values were measured along a moisture (microtopographic) gradient in two boreal peat bogs. Isotopic measurements were performed on bulk material of S. fuscum, S. magellanicum, S. capillifolium and S. pulchrum. Isotopic variations found within and between Sphagnum species along the microtopographic gradient were compared using analysis of variance. A significant positive correlation (P < 0.0001) was found between Sphagnum δ13C values and their position along the surface moisture gradient. Results show that 13C‐depleted values are related to low water table depths (WTD), while 13C‐enriched values correspond to a water table that is close to the peat surface. Although the mechanisms underlying carbon fractionation processes in mosses are not well understood, we demonstrate that water resistance to CO2 diffusion is an important fractionation process that is observed in bulk Sphagnum δ13C measurements, since drier and wetter samples exhibit consistent and very different isotopic signatures. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
70.
The impact of the Laurentide Ice Sheet (LIS) deglaciation on Northern Hemisphere early Holocene climate can be evaluated only once a detailed chronology of ice history and sea‐level change is established. Foxe Peninsula is ideally situated on the northern boundary of Hudson Strait, and preserves a chronostratigraphy that provides important glaciological insights regarding changes in ice‐sheet position and relative sea level before and after the 8.2 ka cooling event. We utilized a combination of radiocarbon ages, adjusted with a new locally derived ΔR, and terrestrial in‐situ cosmogenic nuclide (TCN) exposure ages to develop a chronology for early‐Holocene events in the northern Hudson Strait. A marine limit at 192 m a.s.l., dated at 8.1–7.9 cal. ka BP, provides the timing of deglaciation following the 8.2 ka event, confirming that ice persisted at least north of Hudson Bay until then. A moraine complex and esker morphosequence, the Foxe Moraine, relates to glaciomarine outwash deltas and beaches at 160 m a.s.l., and is tightly dated at 7.6 cal. ka BP with a combination of shell dates and exposure ages on boulders. The final rapid collapse of Foxe Peninsula ice occurred by 7.1–6.9 cal. ka BP (radiocarbon dates and TCN depth profile age on an outwash delta), which supports the hypothesis that LIS melting contributed to the contemporaneous global sea‐level rise known as the Catastrophic Rise Event 3 (CRE‐3).  相似文献   
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