Evidence for fullerenes in solid bitumen from pillow lavas of Proterozoic age from Mítov (Bohemian Massif, Czech Republic)     

Jan Jehli?ka  Aleš Svatoš  Filip Uhlík 《Geochimica et cosmochimica acta》2003,67(8):1495-1506

Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C₆₀, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C₇₀ was detected, nor was C₆₀ found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C₆₀ in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation.  相似文献   

Thermodynamic modelling of sodic pyroxene solid-solution and its application in a garnet-omphacite-kyanite-coesite geothermobarometer for UHP metamorphic rocks   总被引：3，自引：0，他引：3  

Daisuke Nakamura  Shohei Banno 《Contributions to Mineralogy and Petrology》1997,130(1):93-102

A garnet-omphacite-kyanite-coesite geothermobarometer is constructed to estimate the peak metamorphic pressure of ultrahigh-pressure (UHP) eclogites. For this we use a quaternary regular solution model for garnet, and propose a new model for sodic pyroxene that assumes double site solid-solution (Na,Ca)^M2(Al,Fe³⁺,Fe²⁺,Mg)^M1Si₂O₆, where cations in the M2- and the M1-sites mix randomly but with inter-site interactions, not only between nearest neighboring cations but also between next nearest neighboring cations. In the new model, overall excess interaction parameters are quantitatively deduced from the previous experimental data and critical temperature, and the activity of the jadeite component agrees reasonably with that based on the Landau theory. Furthermore, the relations of the calculated order parameter to temperature and composition are consistent with other experimental works. These facts support the usefulness of the new model. Application of our geothermobarometer to kyanite eclogite gave metamorphic conditions around 3.4 GPa and 800 ^∘C for both samples from the Dora Maira Massif, Western Alps, and from Rongcheng County, in the Su-Lu region of eastern China. Received: 30 December 1996 / Accepted: 25 August 1997  相似文献   

Aquatic chemistry: 3rd ed. by W. Stumm and J. J. Morgan. A Wiley-Interscience Publication, John Wiley & Sons, Inc., 1996, xvi + 1022p., US $29.95 (ISBN 0-471-51184-6)     

Tomas Pa?es 《Geochimica et cosmochimica acta》1996,60(24):5158-5159

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Quantitative methods in the earth sciences     

A. F?rster  D. F. Merriam 《Mathematical Geology》1997,29(2):315

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Corrections to Vesicle layering in solidified intrusive magma bodies: a newly recognized type of igneous structure     

Atsushi Toramaru  Akira Ishiwatari  Maki Matsuzawa  Masaru Nakamura  Shoji Arai 《Bulletin of Volcanology》1997,58(8):655-656

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Simulation of normal distributed smooth fields by Karhunen-Loéve expansion in combination with kriging     

Nils-Otto Kitterr?d  Lars Gottschalk 《Stochastic Hydrology and Hydraulics》1997,11(6):459-482

Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function. This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the 2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the predefined covariance functions are evaluated.  相似文献   

Structure and tectonics of convergent plate margins     

Aleš Špi?ák  Ond?ej ?adek  E.Robert Engdahl 《Physics of the Earth and Planetary Interiors》2004,141(4):241

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Influence of the zone of weakness on dip angle and shear heating of subducted slabs     

Martin Kuka?ka  Ctirad Matyska 《Physics of the Earth and Planetary Interiors》2004,141(4):243-252

We study the importance of the zones of weakness and the pattern of downgoing flow in steady-state models of subducting lithosphere, which interacts mechanically and thermally with the ambient mantle. The non-linear system of governing equations consists of (i) the momentum equation in stream function formulation and (ii) the steady-state heat transfer equation including conduction and advection of heat and dissipation. A finite element method has been applied to this system. We consider the viscosity to be a non-linear function of both the temperature and the stream function. In steady-state two-dimensional (2D) flow, the stream function isolines follow material trajectories. They are used to follow the top of the subducting slab, which because of its possible increase in water content, is assumed to have a lower viscosity. The zone of weakness has been thus obtained in the self-consistent fashion since the stream function as well as the temperature are the output from our modeling and no a priori assumptions about the shape of the bending lithosphere are taken into account. It was shown that several orders decrease of viscosity in the zone of weakness is required to obtain the dip angle of about 45°. If the decrease of viscosity is not sufficient enough, the subducted slab either sinks almost vertically or does not exhibit a plate-like behavior. We have also demonstrated that shear heating can unrealistically increase at the zone of weakness for fast subductions if decrease of viscosity is underestimated.  相似文献   

A Modeling Study of the Effects of Anomalous Snow Cover over the Tibetan Plateau upon the South Asian Summer Monsoon   总被引：1，自引：0，他引：1  

刘华强  孙照渤王举 闵锦忠 《大气科学进展》2004,21(6):964-975

The effect of anomalous snow cover over the Tibetan Plateau upon the South Asian summer monsoon is investigated by numerical simulations using the NCAR regional climate model (RegCM2) into which gravity wave drag has been introduced. The simulations adopt relatively realistic snow mass forcings based on Scanning Multi-channel Microwave Radiometer (SNINIR) pentad snow depth data. The physical mechanism and spatial structure of the sensitivity of the South Asian early summer monsoon to snow cover anomaly over the Tibetan Plateau are revealed. The main results are summarized as follows. The heavier than normal snow cover over the Plateau can obviously reduce the shortwave radiation absorbed by surface through the albedo effect, which is compensated by weaker upward sensible heat flux associated with colder surface temperature, whereas the effects of snow melting and evaporation are relatively smaller.The anomalies of surface heat fluxes can last until June and become unobvious in July. The decrease of the Plateau surface temperature caused by heavier snow cover reaches its maximum value from late April to early May. The atmospheric cooling in the mid-upper troposphere over the Plateau and its surrounding areas is most obvious in May and can keep a fairly strong intensity in June. In contrast, there is warming to the south of the Plateau in the mid-lower troposphere from April to June with a maximum value in May.The heavier snow cover over the Plateau can reduce the intensity of the South Asian summer monsoon and rainfall to some extent, but this influence is only obvious in early summer and almost disappears in later stages.  相似文献   

A practical method for estimating dynamic soil stiffness on surface of multi‐layered soil     

Naohiro Nakamura 《地震工程与结构动力学》2005,34(11):1391-1406

It is important to estimate the influence of layered soil in soil–structure interaction analyses. Although a great number of investigations have been carried out on this subject, there are very few practical methods that do not require complex calculations. In this paper, a simple and practical method for estimating the horizontal dynamic stiffness of a rigid foundation on the surface of multi‐layered soil is proposed. In this method, waves propagating in the soil are traced using the conception of the cone model, and the impulse response function can be calculated directly and easily in the time domain with a good degree of accuracy. The characteristics of the impedance, that is the transformed value to the frequency domain of the obtained impulse response, are studied using two‐ to four‐layered soil models. The cause of the fluctuation of impedance is expressed clearly from its relation to reflected waves from the lower layer boundary in the model. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献