Occurrence and geochemistry of arsenic in the groundwater of Eastern Croatia     

M. Ujević  Ž. Duić  C. Casiot  L. Sipos  V. Santo  Ž. Dadić  J. Halamić 《Applied Geochemistry》2010

In order to examine the extent of the As enrichment and the factors influencing this enrichment in the groundwater of Eastern Croatia, groundwater samples were collected from 56 production wells in two counties, Osijek-Baranja and Vukovar-Srijem, suspected to be more affected. Hydrochemical analyses were performed at all locations including in situ As speciation at 32 locations. Arsenic was detected in 46 out of 56 groundwater samples with total As concentrations up to 491 μg/L. Thirty-six of the studied wells yielded groundwater with total As concentrations that exceeded the WHO Maximum Contaminant Level for arsenic in drinking water of 10 μg/L. Only inorganic As species were detected with arsenite As(III) as the predominant form. The spatial distribution of As in the groundwater was significantly linked with geological, geomorphological and hydrogeological development of the alluvial basin of the Drava and Sava rivers. The most probable groundwater As sources are deeper sediments from the Middle and Upper Pleistocene. The results obtained suggest that biogeochemical processes controlling As concentration in the groundwater are complex and location-specific. Reductive dissolution of Fe oxides, desorption of As from Fe oxides and/or clay minerals as well as competition for the sorption sites with organic matter and phosphate could be the principal mechanisms that control As mobilization. The extent of those processes vary in the different parts of the Drava and Sava depressions and could be linked to different site related parameters, such as lithology, mineralogy, local hydrology and hydrogeology; thus different processes of As mobilization have been proposed for the different types of water in relation to groundwater evolution.  相似文献   

Annual and seasonal variability of precipitation in Vojvodina,Serbia     

Ivana Tošić  Ivana Hrnjak  Milivoj B. Gavrilov  Miroslava Unkašević  Slobodan B. Marković  Tin Lukić 《Theoretical and Applied Climatology》2014,117(1-2):331-341

Annual and seasonal variability of precipitation observed at 92 stations in Vojvodina (Serbia) were analyzed during the period 1946–2006. The rainfall series were examined by means of the empirical orthogonal functions (EOF). The first set of singular vectors explains from 68.8 % (in summer) to 81.8 % (in winter) of the total variance. The temporal variability of the time series associated with the main EOF configurations (the principal components, PCs) was examined using the Mann–Kendall test and the spectral analysis. The time series of PC1 revealed decreasing trend in the winter and spring precipitation and increasing trend in the autumn, summer, and annual precipitation. The relationships between the first PC and circulation patterns, such as the North Atlantic Oscillation (NAO), the East Atlantic (EA) pattern, and East Atlantic/West Russia pattern, were also investigated. The PC1, displaying temporal behavior of the first mode, demonstrated evident correspondence with the NAO index in analysis of the annual, winter, and autumn precipitation. Power spectra of the PC1 show statistically significant oscillations of about 3.3 years for the spring precipitation and about 8 and 15 years for the winter precipitation. Comparisons with spectral analysis of authors for some regions in Europe, most of them in the Mediterranean domain, show that similar periodicities are detected.  相似文献   

2D geological–geophysical model of the Timok Complex (Serbia,SE Europe): a new perspective from aeromagnetic and gravity data     

Snežana Ignjatović  Ivana Vasiljević  Milenko Burazer  Miodrag Banješević  Ivan Strmbanović  Vladica Cvetković 《Swiss Journal of Geoscience》2014,107(1):101-112

The study reports new aeromagnetic and gravity data for the northern part of the Timok Magmatic Complex (TMC), East Serbia. The TMC is part of the Tethyan Eurasian metallogenic zone well known for hosting large copper and gold deposits. The complex formed by continuous volcanic activity 90–78 Ma ago, that developed in roughly three phases: Turonian andesites, Santonian–Campanian andesites/basaltic andesites (both mostly volcanic) and Campanian latites/monzonites (mostly shallow intrusive). The aeromagnetic measurements included acquiring total magnetic intensity data that were corrected for diurnal variations, leveling, microleveling, calculated normal field values, calculated anomaly values of total magnetic field intensity and reduction to the pole. The gravity measurements were carried out in an irregular grid with relative gravity values obtained using a Worden gravity meter. 2D modeling reveals that the subsurface extension of the Campanian Valja Str? pluton is ten times larger than it is indicated by its surface outcrops. This implies that the area south and southeast from the pluton can be interesting in terms of finding new porphyry systems. The model indicates that this intrusive body should not be considered as a deeply dissected pluton. This sheds new light onto its potential with respect to epithermal gold mineralization, as well. The model also suggests that there are larger non-exposed bodies of Santonian–Campanian volcanics and near-surface hydrothermally altered rocks than it is inferred from geological maps. The results of our study suggest that further interdisciplinary investigations in the TMC, in particular those integrating geophysics and geology, may have potential of advancing the existing exploration models.  相似文献   

A critical evaluation of using bulk sediment instead of fine fraction in environmental marine studies, investigated on example of Rijeka harbor, Croatia     

Stanislav Frančišković-Bilinski  Neven Cukrov 《Environmental Earth Sciences》2014,71(1):341-356

This work tested the preferential use of fine (<63 μm) or bulk sediment (<2 mm) in environmental research of marine sediments in the Eastern Adriatic. Fine fraction sediment containing silt and clay (<63 μm), predominating in the studied area, was examined to evaluate past and present anthropogenic inputs and to test our hypothesis that investigation of bulk sediment should be preferred. Following aqua regia digestion, chemical analyses of 58 elements were performed by ICP/OES, ICP-MS and cold vapor AAS, and statistical analysis was performed. The concentrations of the majority of the analyzed elements increased with age of the sediment, except for Ag and Sn, which had higher concentrations in recent sediments. The previous main sources of metal contamination in Rijeka harbor were now abandoned municipal-sewage outflow and oil refinery, and continuing harbor activities and antifouling paint use. All activities except of antifouling paint use have been decreasing significantly. Anomalies of selected elements were determined by the box-plot method. More anomalies were found in the bulk sediment than in the fine fraction. Results of Q-modality clustering and factor analysis in the fine fraction almost correlate with that applied on bulk sediments. Thus, it can be said that the differences between the element distribution in the bulk and fine fraction are not statistically significant. Our conclusion is that analysis of bulk marine sediment gives a better insight into the state of pollution and supports previous recommendations to use bulk sediment as a chosen media for environmental studies.  相似文献   

3D modeling and monitoring of karst system as a base for its evaluation and utilization: a case study from eastern Serbia     

Saša Milanović  Zoran Stevanović  Ljiljana Vasić  Vesna Ristić-Vakanjac 《Environmental Earth Sciences》2014,71(2):525-532

Beljanica Mountain in eastern Serbia is a part of the Carpathian Balkan arch (northern Alpine branch). It covers an area of about 300 km² and consists mostly of Jurassic and Cretaceous limestones. Numerous surface karst features, long caves and several large karstic springs located in Beljanica’s piedmont along the contact of karstic and non-karstic rocks are all indicators of an intense karstification. Currently, the large karstic water reserves of Beljanica Mountain are not properly utilized because of their distance from main consumers, the objection by national water managers that the springs lack a stable and sufficient discharge particularly during recession periods. Due to its unpolluted and high quality water, the area is a great prospect for future water supply, and provides an opportunity for artificial regulation and for the design and implementation of specific tapping structures. This paper includes an analysis of the created 3D ArcGIS model of karst interior and its correlation with historical and newly collected data of spring discharges and groundwater physico-chemical characteristics. The results of karst aquifer monitoring (both quantitative and qualitative) are linked with the results of extensive field geological and speleological survey of the upper non-saturated part of the karst (such as sinkholes, pits and caves) and with the investigation of the permanently saturated deeper part of the aquifer (including the diving methods). The model of karst interior is based on the data from the 69 caves, 15 sinks and 1,682 dolines (sinkholes) surveyed. The total length of the karst channels network, calculated using the GIS model and presented in a 3D environment, is 647 km. The catchment areas of five major springs that drain the areas are estimated to range from only 7 km² (Malo Vrelo Spring) to 124 km² (Vrelo Mlave Spring). The groundwater exploitable reserves of Beljanica karst aquifer are estimated to be over 4 m³/s. The waters are low mineralized, unpolluted and have a great potential for water supply.  相似文献   

Dynamics of the Kopački Rit (Croatia) wetland floodplain water regime   总被引：1，自引：1，他引：0  

Lidija Tadić  Ognjen Bonacci  Tamara Dadić 《Environmental Earth Sciences》2014,71(8):3559-3570

Kopa?ki Rit Nature Park is part of the Danube River natural floodplain and one of the last oases of wild life in the Danube River Basin. Due to its extraordinary value, it was inscribed on the list of Wetlands of International Importance in 1993. More than 2,000 species have been registered in this area, which consists of lakes, canals, grassland, marshland and forests. Even the number of investigations which have been performed on its biological and ecological features, hydrological and water resources characteristics, as a prerequisite for ecohydrological analyses, are still rather unknown in the scientific community. Mainly the Danube River and partly the River Drava cause flooding of Kopa?ki Rit and inundations enter the area from both the northern and southern parts. Results of hydrological and meteorological analysis show a decreasing trend of both mean and minimum, annual water levels in the Rivers Drava and Danube (respectively 1.8 and 1.38 cm/year). These reductions in water level can reduce the replenishment periods of Kopa?ki Rit Nature Park. In addition, a significant rise of mean annual air temperature and consequently water temperature (data 1988–2011) may be causing increasing evapotranspiration and loss of water within Kopa?ki Rit. But an encouraging counteracting finding is that, the results of frequency analysis show, even a discharge of 5-years’ return period on the River Danube inundates 70 % of the Danube floodplain and Kopa?ki Rit Nature Park.  相似文献   

Groundwater quality on the territory of Kikinda municipality (Vojvodina,Serbia)     

Nenad Marić  Sanja Mrazovac Kurilić  Ivan Matić  Stanko Sorajić  Jelena Zarić 《Environmental Earth Sciences》2014,72(2):525-534

This paper provides insight into the quality of groundwater used for public water supply on the territory of Kikinda municipality (Vojvodina, Serbia) and main processes which control it. The following parameters were measured: color, turbidity, pH, KMnO₄ consumption, TDS, EC, NH₄ ⁺, Cl^?, NO₂ ^?, NO₃ ^?, Fe, Mn, total hardness, Ca²⁺, Mg²⁺, SO₄ ²⁺, HCO₃ ^?, K⁺, Na⁺, As. The correlations and ratios among parameters that define the chemical composition were determined aiming to identify main processes that control the formation of the chemical composition of the analyzed waters. Groundwater from 11 analyzed sources is Na–HCO₃ type. Intense color and elevated organic matter content of these waters originate from humic substances. The importance of organic matter decay is assumed by positive correlation between organic matter content and TDS, HCO₃ content. There is no evidence that groundwater chemistry is determined by the depth of captured aquifer interval. The main processes that control the chemistry of all analyzed water are cation exchange and feldspar weathering.  相似文献   

Environmental impact of blasting at Drenovac limestone quarry (Serbia)   总被引：1，自引：1，他引：0  

Dejan Vasović  Srđan Kostić  Marina Ravilić  Slobodan Trajković 《Environmental Earth Sciences》2014,72(10):3915-3928

In present paper, the blast-induced ground motion and its effect on the neighboring structures are analyzed at the limestone quarry "Drenovac" in central part of Serbia. Ground motion is examined by means of existing conventional predictors, with scaled distance as a main influential parameter, which gave satisfying prediction accuracy (R > 0.8), except in the case of Ambraseys–Hendron predictor. In the next step of the analysis, a feed-forward three-layer back-propagation neural network is developed, with three input units (total charge, maximum charge per delay and distance from explosive charge to monitoring point) and only one output unit (peak particle velocity). The network is tested for the cases with different number of hidden nodes. The obtained results indicate that the model with six hidden nodes gives reasonable predictive precision (R ≈ 0.9), but with much lower values of mean-squared error in comparison to conventional predictors. In order to predict the influence level to the neighboring buildings, recorded peak particle velocities and frequency values were evaluated according to United States Bureau of Mines, USSR standard, German DIN4150, Australian standard, Indian DMGS circular 7 and Chinese safety regulations for blasting. Using the best conventional predictor, the relationship between the allowable amount of explosive and distance from explosive charge is determined for every vibration standard. Furthermore, the effect of air-blast overpressure is analyzed according to domestic regulations, with construction of a blasting chart for the permissible amount of explosive as a function of distance, for the allowable value of air-blast overpressure (200 Pa). The performed analysis indicates only small number of recordings above the upper allowable limit according to DIN4150 and DMGS standard, while, for all other vibration codes the registered values of ground velocity are within the permissible limits. As for the air-blast overpressure, no damage is expected to occur.  相似文献   

Late cretaceous radiolarians and age of flyschoid sediments in the Struganik section (Western Serbia)     

L. G. Bragina  N. Yu. Bragin  N. Djerić  V. Gajić 《Stratigraphy and Geological Correlation》2014,22(2):202-218

The succession of radiolarian assemblages in the Struganik section of western Serbia is described for the first time. The following radiolarian beds are defined in carbonate flyschoid sequences represented by thin-platy limestones with calcarenite and bentonite clay intercalations (from the base upward): Theocampe urna-Dictyomitra koslovae (presumably lower Santonian); Afens perapediensis-Clathropyrgus titthium (presumably uppermost lower Santonian-basal upper Santonian); Alievium gallowayi-Crucella espartoensis (upper Santonian). The examined assemblages are characterized by high taxonomic diversity. The upper Santonian Alievium gallowayi-Crucella espartoensis Assemblage exhibits significant similarity with the coeval radiolarian assemblage of the Crimean Mountains (Ukraine). Archaeocenosphaera (?) karamatai sp. nov. is described.  相似文献   

Forcing mechanisms of a heavy precipitation event in the southeastern Adriatic area     

Branka Ivančan-Picek  Kristian Horvath  Nataša Strelec Mahović  Marjana Gajić-Čapka 《Natural Hazards》2014,72(2):1231-1252

The aim of this study was to identify the main mesoscale features and mechanisms responsible for the generation of an extreme precipitation event as a contribution to improving the modelling of processes that produce HPEs. The event occurred during the morning hours on 22 November 2010 over the Dubrovnik coast in Croatia and the hinterland mountain range of the southern Dinaric Alps and caused severe flash floods and landslides and consequent interruption of traffic and electricity supply as well as other infrastructural damage. The analysis is geographically focused on the southern portion of the eastern Adriatic region, which is prone to relatively frequent heavy precipitation events that occur mostly in autumn. This area is one of the rainiest in Europe with expected annual amounts of precipitation greater than 5,000 mm in the mountainous hinterland. The mechanisms responsible for the formation of convection were analysed using synop measurements, satellite data and numerical experiments performed with the WRF model, which was set up at the convection-permitting resolution in the innermost domain. Satellite data were used to identify the precipitation systems and to estimate the intensity of the precipitation during the period of interest. The development of the precipitation system was connected to a strong large-scale ascent over the southern Italy and southern Adriatic due to the advection of warm air and cyclonic vorticity advection, which increases with height. The numerical simulations highlighted the essential role of a southerly low-level jet stream in the transport of warm and moist air towards the affected area. The convergence of two branches of low-level marine air favoured convection triggered over the coast and sea. Furthermore, numerical sensitivity experiments suggested that the orography of the Dinaric Alps plays an essential role in the precipitation maximum over the mountainous hinterland, but also that the orography was not the crucial factor in the heavy precipitation near Dubrovnik. This study highlights the need for a dense network of observations, especially radar measurements, to validate the simulated mechanisms and improve numerical forecasts via data assimilation.  相似文献