Theoretical infrared spectra of some model polycyclic aromatic hydrocarbons: effect of ionization     

De Frees DJ  Miller MD  Talbi D  Pauzat F  Ellinger Y 《The Astrophysical journal》1993,408(2):530-538

In order to test the hypothesis of ionized polycyclic aromatic hydrocarbons (PAHs) as possible carriers of the UIR bands, we realized a computational exploration on selected PAHs of small dimension in order to identify which changes ionization would induce on their IR spectra. In this study we performed ab initio calculations of the spectra of neutral and positively ionized naphthalene, anthracene, and pyrene. The results are significantly important. The frequencies in the cations are slightly shifted with respect to the neutral species, but no general conclusion can be reached from the three molecules considered. By contrast, the relative intensities of most vibrations are strongly affected by ionization, leading to a much better agreement between the calculated CH/CC vibration intensity ratios and those deduced from observations.  相似文献   

山东省日照市蓝色经济区工程建设适宜性评价     

朱伟  李玲  杨鹏  杨崇敬  艾洪键 《地球学报》2024,45(1):112-122

本文以山东省日照市蓝色经济区为研究区, 通过野外地质调查和室内综合分析, 选取场地稳定性、工程地质条件、地下水条件, 地形排水条件、地质灾害及其他因素6个一级评价因子, 构造活动、场地土类型、建筑场地类别等13个二级评价因子, 利用专家-层次分析定权法进行区内工程建设适宜性评价, 得到了相应工程建设评价分区图。评价结果表明, 日照市场地工程建设适宜性总体较好, 大部分地区适宜进行高层建筑工程建设, 占84.50%; 地下空间开发利用条件优越, 全区多数地区属于城市地下空间建设适宜区, 适宜性差及不适宜区主要分布在付疃河两岸附近和海岸附近、大型高速公路和铁路沿线一带区域及城区; 轨道交通建设适宜性良好, 小部分不适宜区主要集中在付疃河下游夹仓和小古镇一带及其沿海地区。评价结果可有效地服务于该地区规划布局、建设发展和工程选址, 具有重要的理论和实践指导意义。  相似文献   

Cycle anatomy and variability in the storm-dominated type cincinnatian (Upper Ordovician): coming to grips with cycle delineation and genesis     

Holland SM  Miller AI  Dattilo BF  Meyer DL  Diekmeyer SL 《The Journal of geology》1997,105(2):135-152

Although parasequence and sequence are scale-independent terms, they are frequently applied only to specific scales of cycles. For example, meter-scale cycles are commonly assumed to be parasequences or PACs. In the Upper Ordovician Kope and Fairview Formations of northern Kentucky, we examined a succession of 50 meter-scale cycles that have been variously interpreted as deepening-upward, shallowing-upward, or showing no relationship with water depth. Our analysis shows that these cycles, characterized by shifts in storm-bed proximality, are highly variable in their thickness and internal construction. Most cycles are best considered high-frequency sequences, because deepening-upward intervals are common, and many cycles contain evidence of abrupt basinward shifts in facies as expected at sequence boundaries. A minority fit the parasequence model of shallowing-upward cycles bounded by flooding surfaces. Larger, 20 m scale cycles are defined by systematic thickening and thinning trends of meter-scale cycles. However, meter-scale cycles do not display any systematic trends in cycle anatomy as a function of position within the 20 m cycles or position within the Kope and Fairview Formations. The high cycle variability and the lack of systematic stratigraphic organization with respect to longer-term cyclicity reflect either the irregularity of relative sea-level changes, the poor recording of sea-level changes in this deep-water setting, or the generation of these cycles by climate-induced cyclicity in storm intensity. These three mechanisms would generate similar patterns at the outcrop scale, so it is not possible at the present to distinguish between them.  相似文献   

Association of orogenic activity with the Ordovician radiation of marine life     

Miller AI  Mao S 《Geology》1995,23(4):305-308

The Ordovician radiation of marine life was among the most substantial pulses of diversification in Earth history and coincided in time with a major increase in the global level of orogenic activity. To investigate a possible causal link between these two patterns, the geographic distributions of 6576 individual appearances of Ordovician vician genera around the world were evaluated with respect to their proximity to probable centers of orogeny (foreland basins). Results indicate that these genera, which belonged to an array of higher taxa that diversified in the Middle and Late Ordovician (trilobites, brachiopods, bivalves, gastropods, monoplacophorans), were far more diverse in, and adjacent to, foreland basins than they were in areas farther removed from orogenic activity (carbonate platforms). This suggests an association of orogeny with diversification at that time.  相似文献   

On the interpretation of Fraunhofer line Doppler shifts at supergranule boundaries     

P. Miller  P. Foukal  S. Keil 《Solar physics》1984,92(1-2):33-46

We have used the SPO tower telescope and echelle spectrograph to study differences in the profiles of three Fei lines, between magnetic network and cells. Ca K slit-jaw pictures were used to identify the network and cell areas, and mean network and cell profiles were computed from digitized spectra for the g = 0 lines 4065, 5434, and the g = 1.5 line 5233. The profile bisectors show that the wings of all three lines are red-shifted in the network by between 75–200 m s^–1 relative to the cell profiles. But the redshift decreases in the line core and becomes less than the standard error of 20 m s^–1 near the line core minimum. This disappearance of the redshift at the cores of all 3 lines formed over the height range 250–500 km above _0.5 = 1, argues against a steady downflow at supergranule boundaries. We show that such red-shifted wings and a relatively unshifted core can result if granular convection is suppressed near the network flux tubes, without implying any downflow in the vicinity of these flux tubes. Our results also indicate that searches for large-scale convective velocity patterns should measure shifts of the line core, rather than the line wings which appear to be very sensitive to inhomogeneities in granule structure.Visiting Astronomers, Sacramento Peak Observatory.  相似文献   

Part II. Evaluation of Ar-Ar quartz ages: Implications for fluid inclusion retentivity and determination of initial Ar/Ar values in Proterozoic samples     

M.A. Kendrick  J.McL. Miller  D. Phillips 《Geochimica et cosmochimica acta》2006,70(10):2562-2576

The argon isotope systematics of vein-quartz samples with two different K-reservoirs have been evaluated in detail. Potassium is hosted by ultra-high-salinity fluid inclusions in quartz samples from the Eloise and Osborne iron-oxide-copper-gold (IOCG) deposits of the Mt Isa Inlier, Australia. In contrast, K is hosted by accidentally trapped mica within lower-salinity fluid inclusions of a sample selected from the Railway Fault, 13 km south of the Mt Isa copper mine, Australia. Imprecise apparent ages have been obtained for all of the samples studied and conclusively demonstrate that quartz fluid inclusions are retentive to Ar and have not leaked over billions of years. IOCG samples that host K in fluid inclusions only, have K/Cl values of <1 and the ages obtained represent the maximum ages for mineralization. In contrast, the Railway Fault samples that include accidentally trapped mica have K/Cl values of ?1. Excess ⁴⁰Ar_E plus Cl hosted by fluid inclusions, and radiogenic ⁴⁰Ar_R plus K, are strongly correlated in these samples and define a plane in 3D ⁴⁰Ar-³⁶Ar-K-Cl space. In this case, the plane yields an ‘excess ⁴⁰Ar_E’ corrected age of ∼1030 Ma that is 100’s of Ma younger than nearby Cu-mineralization at Mt Isa. The age is interpreted to reflect ⁴⁰Ar-loss from the accidentally trapped mica into the surrounding fluid inclusions, and is not related to the samples’ age of formation. The initial ⁴⁰Ar/³⁶Ar value of fluid inclusions is widely used to provide information on fluid origin. For the IOCG samples that host K in fluid inclusions only, the initial ⁴⁰Ar/³⁶Ar values are close to the measured values at every temperature of stepped heating experiments. For samples that include accidentally trapped mica, the correction for post-entrapment radiogenic ⁴⁰Ar_R production is significant. Furthermore, because ³⁹Ar_K present in accidentally trapped mica crystals is released at different temperatures to radiogenic ⁴⁰Ar_R lost to the surrounding fluid inclusions, intra-sample ⁴⁰Ar/³⁶Ar variation cannot be reliably documented. The results demonstrate that noble gas analysis is readily applicable to Proterozoic, or older, samples but that if K-mineral impurities are present within quartz the abundance of K must be determined before calculation of mean ⁴⁰Ar/³⁶Ar values that are representative of the samples’ initial composition.  相似文献   

1990～2003年洪湖水体环境质量演变分析   总被引：16，自引：0，他引：16  

胡学玉  陈德林  艾天成 《湿地科学》2006,4(2):115-120

以详细的水质监测资料为基础,采用标准指数法并结合实地调查,分析了1990~2003年洪湖水质的变化状况。结果表明,14 a间,洪湖水质类别以Ⅲ类和Ⅳ类为主。水质恶化的驱动因子是氮、磷及其它有机污染物。1991年到1994年期间,水体中氨氮(NH4 -N)占溶解无机氮(D IN)的比例逐年增高;1995~2003年,以氨氮和硝酸盐(NO3--N)同时作为水体中溶解无机氮的主要存在形式,与1990~1994年的水质状况相比,亚硝酸盐(NO2--N)所占的比例呈增加之势。氨氮、硝酸盐和亚硝酸盐的年际变化表明,洪湖水体自净能力在逐渐降低。以总磷(TP)、总氮(TN)和溶解无机氮(D IN)作为评价指标,洪湖水体已属中富营养型湖泊。洪湖水质演变与该区域人类活动(围湖造田、围网养殖等)以及江湖连通的变化对水环境的作用相耦合。  相似文献   

紫金牛生长土壤微生物和养分特性     

杨霞 艾应伟刘浩  陈黎萍 《山地学报》2006,24(B10):149-152

研究了自然坡地坡上、坡中和坡下三种不同部位上紫金牛生长土壤的微生物特性和养分特性。结果表明，紫金牛只生长在坡下，紫金牛生长的坡下土壤中细菌比例最高、真菌比例最低，土壤全氮和有机质含量均高于对照的坡中和坡上。  相似文献   

Lead, zinc, and antimony contamination of the Rio Chilco-Rio Tupiza drainage system, Southern Bolivia     

Lionel F. Villarroel  Jerry R. Miller  Paul J. Lechler  Dru Germanoski 《Environmental Geology》2006,51(2):283-299

An intense, but localized rainfall event in February 2003, led to the severe erosion and failure of a tailings disposal impoundment at the Abarόa Antimony Mine in southern Bolivia. The failure released approximately 5,500 m³ of contaminated tailings into the Rio Chilco-Rio Tupiza drainage system. The impacts of the event on sediment quality are examined and compared to contamination resulting from historic mining operations in the headwaters of the basin. Of primary concern are contaminated floodplain soils located along downstream reaches of the Rio Tupiza which were found to contain lead (Pb), zinc (Zn), and antimony (Sb) concentrations that locally exceed Canadian, German, and Dutch guidelines for agricultural use. Spatial patterns in sediment-borne trace metal concentrations, combined with Pb isotopic data, indicate that Pb, Zn, and Sb are derived from three tributary basins draining the Abarόa, Chilcobija, and Tatasi-Portugalete mining districts. Downstream of each tributary, geographical patterns in trace metal concentrations reflect local geomorphic changes throughout the drainage system. Trace metal concentrations within the Rio Chilco decrease rapidly downstream as a result of dilution by uncontaminated sediments and storage of metal enriched particles (e.g., sulfide minerals) in the channel bed as a result of ongoing aggradation. Storage in the floodplains is limited. These processes significantly reduced the dispersal and, thus, the relative environmental affects of tailings eroded from the Abarόa Mine during the 2003 flood. In contrast, storage of Pb, Zn, and Sb in floodplains along the Rio Tupiza is significant, the majority of which is derived from historic mining operations, particularly mining within the Tatasi-Portugalete district.  相似文献   

小岩头滑坡稳定性分析     

张赣敏  艾桂根 《华东地质学院学报》2006,29(4):357-360

小岩头滑坡位于贵州省威宁县二(连浩特)河(口)高速公路K255 010~K255 240里程右侧,属一个大型古滑坡,发育于二叠系上统峨嵋山组玄武岩(P2β)地层中。在高速公路施工中对路堑进行深挖削坡,可能导致古滑坡中部、线路右侧斜坡失稳破坏,发生滑坡。因此,滑坡稳定性评价是重大工程地质问题之一。根据大量勘察试验资料,系统地揭示了滑坡的特征,分析了滑坡形成的控制因素、成因和形成机制,建立了滑坡体稳定性计算模型,利用反演计算法进行稳定性分析与评价,认为两滑体均处于滑动失稳状态。建议对滑坡体进行处理,采用排水、支挡、减压等措施进行整治。  相似文献