Separation of Vanillin from Oil Palm Empty Fruit Bunch Lignin     

Mohamad Nasir Mohamad Ibrahim  Mohamad Yusof Nor Nadiah  Mohd Salleh Norliyana  Coswald Stephen Sipaut  Sollehuddin Shuib 《洁净——土壤、空气、水》2008,36(3):287-291

The separation of vanillin from the lignin of empty fruit bunch oil palm is presented in this study. The lignin was extracted from soda black liquor derived from oil palm empty fruit bunches (EFB) using 20% sulfuric acid. Nitrobenzene oxidation was carried out by adding 50 mg of dry EFB lignin into a mixture of 7 mL of 2 M NaOH and 4 mL of nitrobenzene in a 15 mL steel autoclave. The autoclave was sealed tightly with a screw cap fitted with a Teflon gasket and heated to 165°C for 3 h in a preheated thermostatic oil bath. High performance liquid chromatography (HPLC) was used to determine the concentration of each compound present in the lignin. There were eight compounds detected in the HPLC chromatogram. The crystallization process was then used as a method to separate vanillin from other compounds. Based on the solubility of vanillin in acetone, 15 mL of acetone was added to the residue of the oxidized products and heated to 60°C for 10 min. A yield of 1.6% vanillin was isolated from a 50 mg lignin sample. The isolated compound was analyzed with HPLC, Fourier transform infrared spectrophotometry (FT‐IR) and nuclear magnetic resonance (¹³C‐NMR) for structural verification. The results of the characterization studies proved that the isolated compound is vanillin.  相似文献   

Community forest management in Mexico: carbon mitigation and biodiversity conservation through rural development   总被引：1，自引：0，他引：1  

Daniel Klooster  Omar Masera   《Global Environmental Change》2000,10(4):2184

Forest management is an important carbon mitigation strategy for developing countries. As demonstrated by the case of Mexico, community forest management is especially effective because it offers tangible local benefits while conserving forests and sequestering carbon. Community forestry receives minimal government support now, but the clean development mechanism (CDM) of the Kyoto Protocol could leverage additional resources to promote the approach in Mexico and elsewhere. We argue that adequately designed and implemented, community forestry management projects can avoid deforestation and restore forest cover and forest density. They comprise promising options for providing both carbon mitigation and sustainable rural development. These kinds of projects should be included in the CDM.  相似文献   

Provenance, diagenesis, tectonic setting and geochemistry of Tawil Sandstone (Lower Devonian) in Central Saudi Arabia     

Omar A. Al-Harbi  M. Mujtaba Khan 《Journal of Asian Earth Sciences》2008,33(3-4):278-287

The Tawil Sandstone (Lower Devonian) in Central Saudi Arabia overlies the Sharwara Member of the Tayyarat Formation (Silurian) and succeeded conformly by the Shaiba Member of the Jauf Formation. Petrographical data reveal that the Tawil Sandstone comprises 96% quartz, 3% feldspar, and 1% rock fragments and all samples are classified as quartz arenites. The presence of well sorted, altered to fresh feldspar, and discriminate function analysis suggests that the sediments have been subjected to substartial reworking resulting in a high level of maturity. Modal analysis data (Q–F–L) suggest a stable cratonic provenance for the sediments and accumulation in a passive margin basin is indicated (binary plot of SiO₂ vs K₂O/Na₂O). Diagenetic features include dissolution of feldspar and rock fragments, compaction, reduction of the existing pore space through rearrangements, and rotation and fragmentation of grains resulting in dissolution of quartz grains and cementation.  相似文献   

Identifying spatial heterogeneity of coal resource quality in a multilayer coal deposit by multivariate geostatistics     

Mohamad Nur Heriawan  Katsuaki Koike   《International Journal of Coal Geology》2008,73(3-4):307-330

This study presents a new geostatistical approach to characterization of the geometry and quality of a multilayer coal deposit using the data of seam thickness as a geometric property and the contents of ash, sodium, total sulphur, and the heating value as quality properties. A coal deposit in East Kalimantan (Borneo), Indonesia, which has a synclinal geological structure, was chosen as the study site. Semivariogram analysis clarified the strong dependence of heating value on ash content in the top and bottom parts of each seam and the existence of a strong correlation with sodium content over the sub-seams in the same location. The correlations between the geometry and quality of the seams were generally weak. A linear coregionalization model was used to derive the spatial correlation coefficients of two variables at each scale component from the single- and cross-semivariogram matrices. Because the data were correlated spatially in the same seam or over different seams, multivariate techniques (ordinary cokriging and factorial cokriging) were mainly used and the resultant spatial estimates were compared to those derived using a univariate technique (ordinary kriging). A factorial cokriging was effective to decompose the spatial correlation structures with different scales. Another important characteristic was that the sodium content shows distinct segregation: the low zones are concentrated near the boundary of the sedimentary basin, while the high zones are concentrated in the central part. The main component of sodium originates from the abundance of saline water. Therefore, it can be inferred that seawater had stronger effects on the coal depositional process in the central basin than in the border part. The geostatistical modeling results suggest that the thicknesses of all the major seams were controlled by the syncline structure, while the coal qualities chiefly were originated from the coal depositional and diagenetic processes.  相似文献   

Quantifying deformation in North Borneo with GPS     

Mohamad?Asrul?MustafarEmail authorView author&#;s OrcID profile  Wim?J.?F.?Simons  Felix?Tongkul  Chalermchon?Satirapod  Kamaludin?Mohd?Omar  Pieter?N.?A.?M.?Visser 《Journal of Geodesy》2017,91(10):1241-1259

The existence of intra-plate deformation of the Sundaland platelet along its eastern edge in North Borneo, South-East Asia, makes it an interesting area that still is relatively understudied. In addition, the motion of the coastal area of North-West Borneo is directed toward a frontal fold-and-thrust belt and has been fueling a long debate on the possible geophysical sources behind it. At present this fold-and-thrust belt is not generating significant seismic activity and may also not be entirely active due to a decreasing shelfal extension from south to north. Two sets of Global Positioning System (GPS) data have been used in this study; the first covering a time period from 1999 until 2004 (ending just before the Giant Sumatra–Andaman earthquake) to determine the continuous Sundaland tectonic plate motion, and the second from 2009 until 2011 to investigate the current deformations of North Borneo. Both absolute and relative positioning methods were carried out to investigate horizontal and vertical displacements. Analysis of the GPS results indicates a clear trend of extension along coastal regions of Sarawak and Brunei in North Borneo. On the contrary strain rate tensors in Sabah reveal that only insignificant and inconsistent extension and compression occurs throughout North-West Borneo. Moreover, station velocities and rotation rate tensors on the northern part of North Borneo suggest a clockwise (micro-block) rotation. The first analysis of vertical displacements recorded by GPS in North-West Borneo points to low subsidence rates along the western coastal regions of Sabah and inconsistent trends between the Crocker and Trusmadi mountain ranges. These results have not been able to either confirm or reject the hypothesis that gravity sliding is the main driving force behind the local motions in North Borneo. The ongoing Sundaland–Philippine Sea plate convergence may also still play an active role in the present-day deformation (crustal shortening) in North Borneo and the possible clockwise rotation of the northern part of North Borneo as a micro-block. However, more observations need to be collected to determine if the northern part of North Borneo indeed is (slowly) moving independently.  相似文献   

Characterization of carbon monoxide,methane and nonmethane hydrocarbons in emerging cities of Saudi Arabia and Pakistan and in Singapore     

Barbara?BarlettaEmail authorView author&#;s OrcID profile  Isobel?J.?Simpson  Nicola?J.?Blake  Simone?Meinardi  Louisa?K.?Emmons  Omar?S.?Aburizaiza  Azhar?Siddique  Jahan?Zeb  Liya?E.?Yu  Haider?A.?Khwaja  Muhammad?A.?Farrukh  Donald?R.?Blake 《Journal of Atmospheric Chemistry》2017,74(1):87-113

We investigate the composition of 63 C₂-C₁₀ nonmethane hydrocarbons (NMHCs), methane (CH₄) and carbon monoxide (CO), in Jeddah, Mecca, and Madina (Saudi Arabia), in Lahore, (Pakistan), and in Singapore. We established a database with which to compare and contrast NMHCs in regions where ambient levels and emissions are poorly characterized, but where conditions are favorable to the formation of tropospheric ozone, and where measurements are essential for improving emission inventories and modeling. This dataset will also serve as a base for further analysis of air pollution in Western Saudi Arabia including, but not limited to, the estimation of urban emissions and long range pollution transport from these regions. The measured species showed enhanced levels in all Saudi Arabian cities compared to the local background but were generally much lower than in Lahore. In Madina, vehicle exhaust was the dominant NMHC source, as indicated by enhanced levels of combustion products and by the good correlation between NMHCs and CO, while in Jeddah and Mecca a combination of sources needs to be considered. Very high NMHC levels were measured in Lahore, and elevated levels of CH₄ in Lahore were attributed to natural gas. When we compared our results with 2010 emissions from the MACCity global inventory, we found discrepancies in the relative contribution of NMHCs between the measurements and the inventory. In all cities, alkenes (especially ethene and propene) dominated the hydroxyl radical (OH) reactivity (k _OH) because of their great abundance and their relatively fast reaction rates with OH.  相似文献   

Hybrid off-river augmentation system as an alternative raw water resource: the hydrogeochemistry of abandoned mining ponds     

Faradiella Mohd Kusin  Mohd Syakirin Md Zahar  Siti Nurjaliah Muhammad  Nur Diyana Mohamad  Zafira Md Zin  Sharifah Mohd Sharif 《Environmental Earth Sciences》2016,75(3):230

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Carbon dynamic in sandy soil artificially contaminated with petroleum in the presence of various forms of inorganic nitrogen for bioremediation     

Hamed Azari Moghaddam  Nor Kartini Abu Bakar 《Environmental Earth Sciences》2016,75(3):224

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Investigation of geological and soil influence on natural gamma radiation exposure and assessment of radiation hazards in Western Region,Peninsular Malaysia     

Mohammad Syazwan Mohd Sanusi  Ahmad Termizi Ramli  Husin Wagiran  Muhammad Hisyam Lee  Arien Heryanshah  Mohd Nor Said 《Environmental Earth Sciences》2016,75(6):485

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Geochemical evaluation and thermal modeling of the Eocene–Oligocene Pabdeh and Middle Cretaceous Gurpi Formations in the northern part of the Dezful Embayment     

Ahmad Reza Karimi  Ahmad Reza Rabbani  Mohammad Reza Kamali  Mohamad Hosein Heidarifard 《Arabian Journal of Geosciences》2016,9(5):423

Rock–Eval pyrolysis analysis, burial history, and 1D thermal maturity modeling have allowed the evaluation of the source rock potential, thermal maturation state, and impacts of the Pabdeh and Gurpi Formations in Cretaceous–Miocene petroleum system in the Naft Safid (NS) and Zeloi (ZE) oilfields, North Dezful Embayment. The total organic carbon (TOC) content of the Pabdeh and Gurpi Formations ranges from 0.2 to 4.7 wt% and 0.3 to 5.3 wt%, respectively. S2 values of the Pabdeh Formation in the ZE and NS oilfields vary from 0.41 to 13.77 and 0.29 to 14.5 mg HC (Hydrocarbon)/g rock, with an average value of 4.48 and 4.14 mg HC/g rock, respectively. These values for the Gurpi Formation in the ZE and NS oilfields range from 0.31 to 16.96 and 0.26 to 1.44 mg HC/g rock, with an average value of 8.54 and 2.43 mg HC/g rock, respectively. The S2 versus TOC diagram reveals a fair to good hydrocarbon generation potential of the Pabdeh Formation and poor to fair potential of the Gurpi Formation. The high values of S2 (S2 > S1) for samples of the both formations in the ZE and NS oilfields show that the samples are not contaminated with petroleum generated from underlying source rocks. The samples of the Pabdeh Formation in the ZE oilfield are characterized by a relatively narrow range of activation energy values with principal activation energy of 46 kcal/mol and frequency factor of 5.27 × 10⁺¹¹ s^?1. It seems that the high sulfur content of the Pabdeh organic matter probably caused the frequency factor and principal activation energy to be lower than usual. Hydrogen index (HI) values of the Pabdeh and Gurpi Formations in the ZE oilfield vary from 71 to 786 and 97 to 398 mg HC/g TOC, with an average value of 310 and 277 mg HC/g TOC, respectively. These values in the NS oilfield range from 66 to 546 and 51 to 525 mg HC/g TOC, with an average value of 256 and 227 mg HC/g TOC, respectively. Plot of HI vs. T _max value indicates that the majority of the Pabdeh and Gurpi samples contain predominantly type II kerogen and their organofacies are directly related to the more homogeneous precursor materials. Based on thermal maturity modeling results, kinetic parameters, and Rock–Eval analysis, both formations in the ZE and NS oilfields are thermally mature and immature or early mature stage, respectively.  相似文献