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91.
Qatar economy has been growing rapidly during the last two decades during which waste generation and greenhouse gas emissions increased exponentially making them among the main environmental challenges facing the country. Production of biochar from municipal solid organic wastes (SOWs) for soil application may offer a sustainable waste management strategy while improving crop productivity and sequestering carbon. This study was conducted to (1) investigate the physicochemical parameters of biochars for SOW, (2) select the best-performing biochars for soil fertility, and (3) evaluate the potential benefits of these biochars in lowering greenhouse gases (GHGs) during soil incubation. Biochars were produced from SOW at pyrolysis temperatures of 300–750 °C and residence times of 2–6 h. Biochars were characterized before use in soil incubation to select the best-performing treatment and evaluation of potential GHG-lowering effect using CO2 emission as proxy. Here, soil–biochar mixtures (0–2%w/w) were incubated in greenhouse settings for 120 days at 10% soil moisture. Soil properties, such as pH, EC, TC, and WHC, were significantly improved after soil amendment with biochar. Two biochars produced from mixed materials at 300–500 °C for 2 h and used at 0.5–1% application rate performed the best in enhancing soil fertility parameters. A significant decrease in CO2 emission was observed in vials with soil–biochar mixtures, especially for biochars produced at 500 °C compared the corresponding raw materials which exhibited an exponential increase in the CO2 emission. Hence, application of biochar to agricultural soils could be beneficial for simultaneously improving soil fertility/crop productivity while sequestering carbon, thereby reducing anthropogenic emissions of GHGs.  相似文献   
92.
Tailings resulted from sulphuric acid leaching process of uranium from sedimentary rocks contain high concentrations of 226Ra and its daughters, the most important of which is 222Rn. Movement of radon gas out of the tailings is strongly influenced by the physicochemical characteristics of these tailings especially their radium content and the grain size. So, the tailing samples were size fractionated into four sizes (>?250, 250–125, 125–74 and <?74 µm). The natural radioactivity was investigated using hyper-pure germanium detector and solid-state nuclear track detectors (CR-39) for bulk size and after size fractionation. The activity concentrations of different radionuclides in size-fractionated tailing samples have been shown to be strongly dependent on the size of the particles. In the range of >?250 and <?74 µm, the activity concentrations of 230Th, 226Ra, 214Pb, 214Bi, 210Pb, 232Th and 40K increased throughout with decreasing particle size, while that of 238U, 234U and 235U have an opposite effect. The results revealed an inverse relationship between the radon exhalation rate and size fractionation. Also, the results showed a good correlation between radium activity concentration and radon mass exhalation rate.  相似文献   
93.
The hydrogeochemical characteristics of shallow groundwater in the Grombalia region, northeastern Tunisia, were investigated to evaluate suitability for irrigation and other uses and to determine the main processes that control its chemical composition. A total of 21 groundwater samples were collected from existing wells in January–February 2015 and were analyzed for the major cations and anions concentrations. Conductivity, pH, T°, O2 and salinity were also measured. Interrelationships between chemical parameters were determined by using the scatter matrix method. The suitability of groundwater for irrigation and other uses was assessed by determining the sodium adsorption ratio, soluble-sodium percentage, total dissolved solids, total hardness, Kelly’s index and permeability index values of water samples. The spatial distribution of key parameters was assessed using a GIS-based spatial gridding technique. This analysis indicated that the chemical composition of groundwater in the study area is of Cl–SO4–Na–Ca mixed facies with concentrations of many chemical constituents exceeding known guideline values for irrigation. The salinity of groundwater is controlled by most dominant cation and anion (Na–Cl). A correlation analysis shows that Na+ is the dominant cation and that reverse ion exchange is a dominant process that controls the hydrogeochemical evolution of groundwater in the area. Geospatial mapping of hydrochemical parameters and indices analyzed with the USSL and Wilcox diagrams show distinctive areas of irrigation suitability. In contrast, 76.2% of samples fall in the highly doubtful to unsuitable category and indicate that the central and north-eastern parts of the study area are unsuitable for irrigation due to a high salinity and alkalinity.  相似文献   
94.
95.
Ras Abda plutonic suite, North Eastern Desert of Egypt, consists predominantly of Neoproterozoic calc-alkaline older granites. Minor exposures of pink microgranite are occurring along Wadi Ras Abda within the older granites. Previous studies on this area demonstrated that the microgranite is altered in some parts and contains anomalous concentrations of rare metal elements (Zr, Th, and U). These altered and mineralized zones are re-assessed using field observations, chemical analysis, and by the application of various transmitted light and electron microscopic techniques. The rare metals exist as mineral segregation grew freely into open cavities of the microgranite and concordant with the NNE strike-slip fault movement. The mineralized zones contain an assemblage of secondary magnetite, zircon, uranothorite, columbite-(Mn), fergusonite-(Y), and allanite-(Ce). The extreme abundance of zircon in the mineralized zone, along with other evidence, indicates a hydrothermal origin of this zircon together with associated rare metals. The geochemical investigation and mass balance calculations revealed extreme enrichment of Zr, Th, U, Y, Nb, Ta, and REE. Post-magmatic hydrothermal alterations resulted in such pronounced chemical and mineralogical heterogeneity. The hydrothermal fluids are thought to be oxidizing, alkaline and of medium temperature (>?250 °C). The average contents of the elements Zr (1606 ppm), Th (1639 ppm), U (306 ppm), Nb (955 ppm), and REE (1710 ppm) in the mineralized microgranite reach sub-economic levels and could be a potential source of these elements.  相似文献   
96.
A seismic source model is developed for the entire Arabian Plate, which has been affected by a number of earthquakes in the past and in recent times. Delineation and characterization of the sources responsible for these seismic activities are crucial inputs for any seismic hazard study. Available earthquake data and installation of local seismic networks in most of the Arabian Plate countries made it feasible to delineate the seismic sources that have a hazardous potential on the region. Boundaries of the seismic zones are essentially identified based upon the seismicity, available data on active faults and their potential to generate effective earthquakes, prevailing focal mechanism, available geophysical maps, and the volcanic activity in the Arabian Shield. Variations in the characteristics given by the above datasets provide the bases for delineating individual seismic zones. The present model consists of 57 seismic zones extending along the Makran Subduction Zone, Zagros Fold-Thrust Belt, Eastern Anatolian Fault, Aqaba-Dead Sea Fault, Red Sea, Gulf of Aden, Owen Fracture Zone, Arabian Intraplate, and a background seismic zone, which models the floating seismicity that is unrelated to any of the distinctly identified seismic zones. The features of the newly developed model make the seismic hazard results likely be more realistic.  相似文献   
97.
98.
For the 1993–2009 period, we analyzed the relationship between almond yield and three climatic variables (mean annual temperature, soil water reserve, and precipitation), and four bioclimatic variables (annual ombrothermic index, water deficit, simple continentality index, and compensated thermicity index), for one major Hebron crop (soft and hard almonds). Moreover, we obtained data almond production from the Palestinian Central Bureau of Statistics, while the climate data from the Palestinian meteorological station during the study period from 1993 to 2009, and analysis is it by using bioclimatic classification of the Earth of Salvador Rivas-Martinez to study the relationship between the almond yield and climate and bioclimate factors (variables). The climatic and bioclimate variables of greatest importance to almond were used to develop regressions analysis relating yield to climatic conditions. Hebron was positively affected by annual ombrothermic index, simple continentality index, precipitation, water soil reserve, and mean annual temperature, but negatively affected by water deficit, with a large proportion of the variance explained by axis F1 (72.48%), F2 (22.38%), and axes F1and F2 (94. 86%). However, in order to produce a high amount of almonds and quality, it can be grown in the regions of the mesomediterranean region, with the value of annual ombrothemic index more than 3, compensated thermicity index between 220/220 to 350/350, simple continentality index between 14 and 20, and in areas where the average annual temperature is between 15 and 20 °C.  相似文献   
99.
Temperature is one of the variables that influence the elasto-plastic behavior and integrity of rock outcrops. Fluctuations in temperature can trigger alteration of some of the mineral properties and impact the brittle-plastic transition. Initiation and propagation of thermally induced tension cracks tend to weaken most rock types. The principal goal of this study was to anticipate impacts of thermal stress-strain cycles on the dynamic response of representative rock units exposed in the Khewra Gorge of the Salt Range Punjab of Pakistan. Ten types of sedimentary rock units were sampled, including marl, dolomite, three types of limestone, and five different sandstones exhibiting varying characteristics in outcrop. Boulder specimens were collected from the field and transported to the laboratory to prepare 50 drill cores that could be subjected to thermal cycling between 50 and 200 °C in increments of 50 °C. Room temperature core samples were tested using an Erudite resonance frequency meter to measure their Q-factors and the resonance frequency (Fr) at an applied loading frequency of 7 KHz with 0.01 V output voltage. Results suggest that thermal cycling tends to reduce the dynamic Young’s modulus (Ed) and Q-factor. Other parameters, such as damping ratio (ξ), specific damping capacity (Ψ), and loss factor (?) appeared to increase with increasing temperature cycles, likely as a result of developing thermally induced tensile fractures. The resultant values of the null hypothesis (t-critical and t-stats) suggests that the null hypothesis can be discarded because there was no observable difference between the measured and expected values for the cores tested. The observations and data emanating from this study might be useful in designing low-level radioactive waste landfills, nuclear waste repositories, and deep underground excavations where the increased temperature could alter the mechanical behavior of the parent rock mass.  相似文献   
100.
The Bou Arada-El Fahs troughs system is a particularly E-W trending collapsed structure with the manifestation of normal-to-strike-slip faults. A combined multi-source and multi-scalar structural and geophysical investigation provides important insights on the geometry and the kinematics evolution of trough systems in the Atlas of Tunisia. New data, as well as a reappraisal of available data show that the studied troughs system is established during three main successive events: the Oligocene-Miocene, the Tortonian, and the Plio-Quaternary events. The goal of this paper is to present the structural evolution of the study area, on a pre-structured substratum. The structural evolution progressed from an extensional event, manifested by the formation of grabens, passing by an episode of reactivation of faults related troughs in strike-slip motion during the Atlas compression accompanied by an en-échelon folding in foot wall and hanging wall. These results acquired and presented in the following order: We will initially present the geological context by integrating and correlating the lithostratigraphic data. We continue by examining the geometry and kinematics of structure-related troughs via the detailed geological mapping, the interpretation of available 2D seismic data, and the interpretation of processed fault slip data. This integrated geological and geophysical study allows a better understanding of the BETS, and makes it possible to propose a new geometrical and kinetic model of the establishment of trough structure in the Tunisian Atlas.  相似文献   
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