Removal of Copper,Nickel, and Zinc Ions from Electroplating Rinse Water     

Meyyappan Revathi  Mohan Saravanan  Ahmed Basha Chiya  Manickam Velan 《洁净——土壤、空气、水》2012,40(1):66-79

Removal of copper, nickel, and zinc ions from synthetic electroplating rinse water was investigated using cationic exchange resin (Ceralite IR 120). Batch ion exchange studies were carried out to optimize the various experimental parameters (such as contact time, pH, and dosage). Influence of co‐existing cations, chelating agent EDTA on the removal of metal ion of interest was also studied. Sorption isotherm data obtained at different experimental conditions were fitted with Langmuir, Freundlich, Redlich–Peterson, and Toth models. A maximum adsorption capacity of 164 mg g^?1 for Cu(II), 109 mg g^?1 for Ni(II), and 105 mg g^?1 for Zn(II) was observed at optimum experimental conditions according to Langmuir model. The kinetic data for metal ions adsorption process follows pseudo second‐order. Presence of EDTA and co‐ions markedly alters the metal ion removal. Continuous column ion exchange experiments were also conducted. The breakeven point of the column was obtained after recovering effectively several liters of rinse water. The treated rinse water could be recycled in rinsing operations. The Thomas and Adams–Bohart models were applied to column studies and the constants were evaluated. Desorption of the adsorbed metal ions from the resin column was studied by conducting a model experiments with Cu(II) ions loaded ion exchange resin column using sulfuric acid as eluant. A novel lead oxide coated Ti substrate dimensionally stable (DSA) anode was prepared for recovery of copper ions as metal foil from regenerated liquor by electro winning at different current densities (50–300 A cm^?2).  相似文献   

Dynamics of sea-ice biogeochemistry in the coastal Antarctica during transition from summer to winter     

Suhas Shetye  Babula Jena  Rahul Mohan 《地学前缘(英文版)》2017,8(3):507-516

The seasonality of carbon dioxide partial pressure(pCO_2).air-sea CO_2 fluxes and associated environmental parameters were investigated in the Antarctic coastal waters.The in-situ survey was carried out from the austral summer till the onset of winter[January 2012,February 2010 and March 2009) in the Enderby Basin.Rapid decrease in pCO_2 was evident under the sea-ice cover in January,when both water column and sea-ice algal activity resulted in the removal of nutrients and dissolved inorganic carbon(DIC) and increase in pH.The major highlight of this study is the shift in the dominant biogeochemical factors from summer to early winter.Nutrient limitation(low Si/N),sea-ice cover,low photosynthetically active radiation(PAR),deep mixed layer and high upwelling velocity contributed towards higher pCO_2during March(early winter).CO_2 fluxes suggest that the Enderby Basin acts as a strong CO_2 sink during January(-81 mmol m~2 d~(-1)),however it acts as a weak sink of CO_2 with-2.4 and-1.7 mmol m~(-2) d~(-1)during February and March,respectively.The present work,concludes that sea ice plays a dual role towards climate change,by decreasing sea surface PCO_2 in summer and enhancing in early winter.Our observations emphasize the need to address seasonal sea-ice driven CO_2 flux dynamics in assessing Antarctic contributions to the global oceanic CO_2 budget.  相似文献   

Multiband optical monitoring of the blazars S5 0716+714 and BL Lacertae     

C. S. Stalin  Gopal-Krishna  Ram Sagar  Paul J. Wiita  V. Mohan  A. K. Pandey 《Monthly notices of the Royal Astronomical Society》2006,366(4):1337-1345

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Evaluation of metal contamination in coastal sediments of the Bay of Bengal, India: geochemical and statistical approaches   总被引：11，自引：0，他引：11  

Selvaraj K  Ram Mohan V  Szefer P 《Marine pollution bulletin》2004,49(3):174-185

Surface sediment samples collected from the inner shelf region of the Bay of Bengal, were analysed for the major elements and total and acetic acid available trace elements (Al, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Pb, Si, Zn) to evaluate geochemical processes influencing their distribution. Major elemental analysis showed that the sediments had high concentrations of Si and relatively low concentrations of Al and Fe. Both major elemental and trace metal concentrations indicated that the sediments represent weathered products of granite and charnockite. Normalization of metals to Al indicated relatively high enrichment factors for Pb, Cd, Zn and Cr. The higher proportions of nondetrital Pb (66%), Cd (41%) and Co (28%) reveal metal contamination due to anthropogenic inputs. Factor analysis (FA) identified six possible types of sedimentological and geochemical associations. The dominant factor accounting for 26.9% of the total variance identifies an anthropogenic input and accumulation of nondetrital Cd, Co, Cr, Ni and Pb. Association of these metals with CaCO3 reveals that shell fragments in the surface sediments are likely act as a carrier phase for nondetrital metals. The results are discussed in the context of the sources and pathways of elements in the Bay of Bengal.  相似文献   

Equilibrium structures of rotationally and tidally distorted stellar models     

C. Mohan  R. M. Saxena  S. R. Agarwal 《Astrophysics and Space Science》1990,163(1):23-39

In this paper we present a method for computint the equilibrium structures of rotationally distorted stars as well as rotationally and tidally distorted primary components of the stars in binary systems. The method is based on the averaging technique of Kippenhahn and Thomas (1970) and utilizes the concepts of Roche equipotentials (Kopal, 1972). The method takes into account terms up to second-order of smallness in the rotational and tidal distortion parameters. The use of the method in obtaining the equilibrium structures of certain rotationally and (or) tidally distorted models of Main-Sequence stars is also illustrated.  相似文献   

Effects of partial frequency redistribution on the level population densities in a resonance line     

A. Peraiah  D. Mohan Rao 《Astrophysics and Space Science》1981,80(2):437-442

We have obtained a simultaneous solution of the statistical equilibrium equation for a non-LTE two-level atom and the radiative transfer equation in the comoving frames by employing the angle-averaged partial frequency redistribution.R _i with isotropic scattering. In the first iteration we have set the population density of the upper level equal to zero and allow it to be populated in the subsequent iterations. The solution converges within two to four iterations. The process of iteration is terminated when the ratios of population densities in two successive iterations at each radial point, attain an accuracy of 1%. The effects of partial frequency redistribution is to increase the population density of the upper level. Radial gas motions do not seem to have significant effects, although in highly extend geometries, velocity gradients change the population densities considerably.  相似文献   

Assessment of the groundwater potential and quality in Bhatsa and Kalu river basins of Thane district, western Deccan Volcanic Province of India   总被引：3，自引：0，他引：3  

M.N. Ravi Shankar  G. Mohan 《Environmental Geology》2006,49(7):990-998

Scarcity of groundwater necessitates the present study to evaluate groundwater potential and quality for designing suitable water management plans in the Bhatsa and Kalu river basins in the Thane district in the western Deccan volcanic province of India. A Geographical Information System platform is used to integrate and spatially analyse multiparametric data comprised of satellite, topographical, geological and hydrogeological information to generate several thematic maps, including groundwater potential zonation map. This study reveals that 70% of the area has medium to low groundwater potential, while only 10% has high potential. The static and dynamic groundwater potentials are estimated to be 10.7 and 4.8% of the annual rainfall. The groundwater quality in terms of hardness, total dissolved solids, salinity and chloride is suitable for domestic and irrigational purposes. A database is developed for sustainable water management program for the region and areas where suitable water conservation techniques need to be adopted are identified.  相似文献   

Value of Information in the Earth Sciences by Jo Eidsvik,Tapan Mukerji and Debarun Bhattacharjya     

Mohan Kelkar 《Mathematical Geosciences》2016,48(8):1013-1014

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Analytical solutions for transient temperature distribution in a geothermal reservoir due to cold water injection     

Sayantan Ganguly  M. S. Mohan Kumar 《Hydrogeology Journal》2014,22(2):351-369

An analytical solution to describe the transient temperature distribution in a geothermal reservoir in response to injection of cold water is presented. The reservoir is composed of a confined aquifer, sandwiched between rocks of different thermo-geological properties. The heat transport processes considered are advection, longitudinal conduction in the geothermal aquifer, and the conductive heat transfer to the underlying and overlying rocks of different geological properties. The one-dimensional heat transfer equation has been solved using the Laplace transform with the assumption of constant density and thermal properties of both rock and fluid. Two simple solutions are derived afterwards, first neglecting the longitudinal conductive heat transport and then heat transport to confining rocks. Results show that heat loss to the confining rock layers plays a vital role in slowing down the cooling of the reservoir. The influence of some parameters, e.g. the volumetric injection rate, the longitudinal thermal conductivity and the porosity of the porous media, on the transient heat transport phenomenon is judged by observing the variation of the transient temperature distribution with different values of the parameters. The effects of injection rate and thermal conductivity have been found to be profound on the results.  相似文献   

Si VII/Mg VII and Si IX/Mg IX line diagnostics for solar plasma     

Anita Mohan  B. N. Dwivedi 《Solar physics》1996,167(1-2):145-151

New calculations for Si vii/Mg vii and Si ix/Mg ix theoretical line ratios as a tool for plasma density diagnostics and for the estimation of relative element abundance in the solar atmosphere are presented, making use of the EUV spectrum of an active region obtained by the Solar EUV Rocket Telescope and Spectrograph (SERTS). Theoretical line ratios, hitherto not observed, are discussed for diagnosing solar plasma from the observations obtainable with the Coronal Diagnostic Spectrometer (CDS) instrument on board the SOHO mission.In the honour of Dr P. K. Raju, Indian Institute of Astrophysics, Bangalore, on the completion of his 60 years.  相似文献