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51.
Available age data support the hypothesis that kimberlite intrusions are formed by mantle hotspots. The hypothesis has been tested by inverting the volcanic traces formed by three hotspots to determine the post-Triassic motions of Africa, South America, and North America relative to these hotspots. Then, using these motions, the kimberlites intruded on these continents within the last 150 m.y. are relocated to their place of origin in the present hotspot reference frame. The result indicates that a majority of the kimberlites formed within 5° of a mantle hotspot. Statistical analysis shows that this kimberlite/hotspot correlation is significant at above the 90% level.  相似文献   
52.
Rare earth element (REE) abundances were measured by neutron activation analysis in anhydrite (CaSO4), barite (BaSO4), siderite (FeCO3) and galena (PbS). A simple crystal-chemical model qualitatively describes the relative affinities for REE substitution in anhydrite, barite, and siderite. When normalized to ‘crustal’ abundances (as an approximation to the hydrothermal fluid REE pattern), log REE abundance is a surprisingly linear function of (ionic radius of major cation—ionic radius of REE)2 for the three hydrothermal minerals, individually and collectively. An important exception, however, is Eu, which is anomalously enriched in barite and depleted in siderite relative to REE of neighboring atomic number and trivalent ionic radius. In principle, REE analyses of suitable pairs of co-existing hydrothermal minerals, combined with appropriate experimental data, could yield both the REE content and the temperature of the parental hydrothermal fluid.The REE have only very weak chalcophilic tendencies, and this is reflected by the very low abundances in galena—La, 0.6 ppb; Sm, 0.06 ppb; the remainder are below detection limits.  相似文献   
53.
A Precambrian metadolerite dyke has two distinct types of remanence carriers; those with medium/high coercivities (unblocking fields of 20–120 mT) and those with low coercivities (unblocking fields of <15 mT). Optical examination reveals numerous submicron probably opaque inclusions in the plagioclase feldspar and also large opaque grains consisting of coarse oxidation-exsolution intergrowths of magnetite and ilmenite. All opaque phases have been examined using transmission electron microscopy together with microanalysis and electron diffraction. The submicron inclusions in the plagioclase are titanomagnetites(0 < x ≤ 0.14) with a size range between about 0.01 and 0.5 μm and axial ratios between 1 (equidimensional) and about 0.3. Many of these inclusions fall in the single-domain field but some are probably pseudo-single-domain. The large opaque grains contain almost pure magnetite and ilmenite and show no fine-scale exsolution; the magnetite regions of the intergrowths are of multidomain size and reveal multidomain structure under Lorentz electron microscopy. There are also some primary ilmenites containing very fine exsolved haematite, and there are very fine plates of ilmenite and very elongate needles of magnetite within the augite. Experiments on artificial samples containing very carefully prepared separates of plagioclase and large opaque grains show that the pure plagioclase acquires a remanence with unblocking fields of 20–140 mT and blocking temperatures of 390–590°C and the large opaque grains acquire a remanence with unblocking fields of less than 15 mT but a wide range of blocking temperatures up to about 570°C. It is concluded that the medium/high coercivity component of remanence in the rock is carried largely or possibly entirely by the submicron magnetites within the plagioclase and that the low coercivity component is carried largely or entirely by the multidomain magnetites in the large opaques. The contribution of the magnetite needles in the augite is uncertain as the rock does not contain any detectable component of remanence with the extremely high coercivities expected from their very elongate shape.  相似文献   
54.
Four ureilites (Dyalpur, Goalpara, Haverö, and Novo Urei) were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Rb, Re, Sb, Se, Te, Tl, and U. An attempt has been made to resolve the data into contributions from the parent ultramafic rock and the injected, carbon- and gas-rich vein material. Interelement correlations, supported by analyses of separated vein material (WANKE et al, 1972), suggest that the vein material is enriched about 10-fold in refractory Ir and Re over moderately volatile Ni and Au, and is low in volatiles except Ge, C, and noble gases. It appears to be a refractory-rich nebular condensate that precipitated carbon by surface catalytic reactions at ˜500K and trapped noble gases but few other volatiles. The closest known analogue is a Cr- and C-rich fraction from the Allende meteorite, highly enriched in heavy noble gases and noble metals. By analogy with Allende, the gas-bearing phase in ureilites may have been an Fe, Cr-sulfide.

The ultramafic rock contains siderophiles and chalcophiles (Ni, Au, Ge, S, Se) at ˜0.05 of Cl chondrite level, and highly volatile elements (Rb, Cs, Bi, Tl, Br, Te, In, Cd) at ˜0.01 Cl level. It probably represents the residue from partial melting of a C3V-like chondrite body, under conditions where phase separation was incomplete so that some liquid was retained. The vein material was injected into this rock at some later time.  相似文献   

55.
Four C3V chondrites (Grosnaja, Kaba, Mokoia, Vigarano) and three C3O chondrites (Felix, Kainsaz, and Lancé) were analyzed by radiochemical neutron activation for 17 trace elements. Both classes show a typical chondritic step pattern, reflecting loss of volatiles during chondrule formation. Elements condensing above 1300 K (U, Re, Ir, Ni) are present in essentially Cl chondrite proportions, while moderately volatile elements condensing between 1300 K and 800 K (Ge, Rb, Ag) are depleted by a factor of 0.44. However, elements condensing below 700 K (S, Cs, Bi, Tl, Br, Se, Te, In, Cd) are depleted to a still greater degree, and more so in the Ornans subclass (factor of 0.24, except Cd 0.007) than in the Vigarano subclass (factor of 0.29). This additional depletion may be due to a slight (less than 3-fold) dust-gas fractionation, by settling of dust to the median plane of the solar nebula. Among other chondrite classes, ordinary chondrites show a similar depletion, but C2 chondrites do not. Possibly the undepleted meteorites formed in one of the convection zones of the nebula predicted by Cameron and Pine, whereas the depleted meteorites formed in a quiescent region.The condensation of chalocophile elements as a function of H2S partial pressure is discussed, in an attempt to explain the drastic difference in Cd abundance between the two subclasses. It appears that the H2SH2 ratio is the key variable. C3O's seem to have condensed in a region where enough metallic Fe was present to buffer the H2S pressure, while C3V's condensed in a more oxidized region, where H2S was in excess. Accretion temperatures, for an assumed nebular pressure of 10?5 atm, were between 415 and 430 K for C3O's and less than 440 K for C3V's.Two slightly volatile elements, Sb and Au, show variable depletion, presumably reflecting variable loss during chondrule formation. Indeed, their depletion correlates with the abundance of iron-poor olivine, a measure of the peak temperature and time during chondrule formation.  相似文献   
56.
Seventeen trace elements (Ag, Au, Bi, Br, Cd, Cs, Ge, Ir, Ni, Rb, Re, Sb, Se, Te, Tl, U, Zn) were analyzed by radiochemical neutron activation and 13 other elements (Ce, Co, Cr, Eu, Fe, Hf, La, Lu, Na, Sc, Sm, Tb, Yb) by instrumental neutron activation in a total of 12 rocks from the layered anorthositic complex at Fiskenaesset, West Greenland and in the plagioclase-rich unbrecciated eucrite, Serra de Magé.Garnet anorthosite 84428, which has an unusually sodic plagioclase, is spectacularly enriched in Cs, K, Rb. Tl and, to a lesser degree, Te. This appears to be the result of later metasomatism and not a reflection of fractionation trends within the anorthositic complex. For the remaining Fiskenaesset rocks, a factor analysis yields 5 principal factors for linear data for 22 elements and 6 factors for data transformed (log, 3√, √) to give approximately normal distributions. Linear correlations are controlled by high values, whereas the logarithmic transform increases the influence of the lowest values. Enrichment of several elements in chromitite 132022 underlies linear Factor 1. Six of these elements Co, Cr, Fe, Ir, Ni, Zn and possibly Re are probably hosted by chromite. In other zones of the intrusion, different fractionation trends may be more important, since in the transformed analysis these elements divide between Factor 1 (Co, Zn, Ni, Fe) and Factor 4 (Ir, Cr and also Au). Linear Factor 2 reflects the strong mutual correlation between Tl, Rb and An, the anorthite content of plagioclase. Transformed Factor 3 emphasizes the anticorrelation of Na and Sm with An. The positive correlations of Cs, U and Ge (linear Factor 3; transformed Factor 2) are largely due to their concentration in later crystallizates, but enrichment in lower zone gabbros of high An content perhaps indicates concentration in minor or accessory cumulate minerals. Flat chondrite-normalized rare earth element patterns in several anorthosites (except for a small positive Eu anomaly) suggests that the Fiskenaesset magma was relatively unfractionated.Factor 4 (linear) and Factor 5 (transformed) reflects the geochemical coherence of Se and Te. The sympathetic enrichment of Sb and Cd in 3 rocks, resulting in Factor 5 (linear) and Factor 6 (transformed) may be due to the lack of a suitable Zn sulfide host for Cd.In 3 rocks of true anorthosite composition, 8 volatile elements show rather constant abundance when normalized to Cl chondrites (mean 4.2 ± 0.4% Cl), possibly suggesting that volatile-rich material was accreted late in the Earth's formation, perhaps after core segregation. These anorthosites are higher than lunar anorthosite 15415 by a factor of 58 ± 9 in volatile elements. Siderophile and chalcophile elements are much more variable in Cl-normalized abundances in both lunar and terrestrial anorthosites, but surprisingly give somewhat similar Earth/Moon abundance ratios.Volatile elements in terrestrial oceanic basalts and lunar mare basalts are not as uniformly abundant as in anorthosites. but nevertheless yield a similar Earth/Moon ratio of 44 ± 8.Volatile elements in Serra de Magé are more abundant than in lunar anorthosites, but lower than in terrestrial equivalents, averaging (3.6 ± 0.8) × 10?3C1.  相似文献   
57.
Xenon isotopic studies confirm natural spontaneous chain reactions at the Oklo mine site (Republic of Gabon) with an integrated neutron flux of approximately 4 × 1020n/cm2 and a duration between 14,000 and 70,000 years. Similar studies for the Rabbit Lake deposit (Saskatchewan), a slightly younger site with some evidence of continued geologic activity, shows no evidence of self-supporting reactions.  相似文献   
58.
The spectrum of the highest redshift QSO 2000–330 (z=3.78) contains four heavy-element absorption systems withz abs>3.0. Interesting features include velocity structure atz abs=3.552 which suggests a cluster origin and a purely low ionization system atz abs=3.1881 typical of a galactic disk sightline.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.  相似文献   
59.
The hornblende‐ and biotite‐bearing R chondrite LAP 04840 is a rare kind of meteorite possibly containing outer solar system water stored during metamorphism or postshock annealing deep within an asteroid. Because little is known regarding its age and origin, we determined 40Ar/39Ar ages on hornblende‐rich separates of the meteorite, and obtained plateau ages of 4340(±40) to 4380(±30) Ma. These well‐defined plateau ages, coupled with evidence for postshock annealing, indicate this meteorite records an ancient shock event and subsequent annealing. The age of 4340–4380 Ma (or 4.34–4.38 Ga) for this and other previously dated R chondrites is much older than most impact events recorded by ordinary chondrites and points to an ancient event or events that predated the late heavy bombardment that is recorded in so many meteorites and lunar samples.  相似文献   
60.
The development and transfer of clean energy technologies to achieve universal energy access is challenging due to the inherent complexities of the energy sector, and the energy governance and financial systems in developing economies. Innovation is an essential part of successfully addressing these difficulties. Duplicating the energy infrastructure models of developed countries will not be sufficient to meet the needs of poor consumers. To the extent that innovation can accelerate energy access, it is important to understand the specific types of innovations that are necessary and how they might be facilitated. The general features of existing international clean energy innovation systems, which are predominantly driven by the markets and emissions reduction mechanisms of developed and rapidly growing emerging economies, are reviewed and the alignment of these systems to the innovation processes required to extend energy access globally is evaluated. Drawing on the innovation policy literature, the attributes of effective international and domestic energy innovation systems that are pro-poor and the associated policy approaches are identified.  相似文献   
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