Redox gradients at the low oxygen boundary of lakes   总被引：1，自引：0，他引：1  

Mathias K. Kirf  Hans Røy  Moritz Holtappels  Jan P. Fischer  Carsten J. Schubert  Bernhard Wehrli 《Aquatic Sciences - Research Across Boundaries》2015,77(1):81-93

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Exploratory seismic site response surveys in a complex geologic area: a case study from Mt. Etna volcano (southern Italy)     

F. Panzera  G. Lombardo  E. Longo  H. Langer  S. Branca  R. Azzaro  V. Cicala  F. Trimarchi 《Natural Hazards》2017,86(2):385-399

A preliminary study targeting to evaluate the local seismic response was performed in the eastern flank of Mt. Etna (southern Italy) using ambient noise measurements. The obtained spectral ratios were subdivided through cluster analysis into different classes of fundamental frequency permitting to draw an iso-frequency contour map. The analysis set into evidence the extreme heterogeneity of lava sequences, which makes difficult to identify a single seismic bedrock formation. Another important outcome, concerning the local seismic effects in terms of frequency and azimuth, is the important role played by the fracture fields associated with the main structural systems of the area. The existence of two zones with strong directional effects striking WNW–ESE and NW–SE, nearly orthogonal to the orientation of the main fracture fields, corroborate such hypothesis.  相似文献   

Ground-motion scenarios on Mt. Etna inferred from empirical relations and synthetic simulations     

Horst Langer  Giuseppina Tusa  Luciano Scarfì  Raffaele Azzaro 《Bulletin of Earthquake Engineering》2016,14(7):1917-1943

Ground motion scenarios for Mt. Etna are created using synthetic simulations with the program EXSIM. A large data set of weak motion records is exploited to identify important input parameters which govern the modeling of wave propagation effects, such as Q-values, high frequency cut-off and geometrical spreading. These parameters are used in the simulation of ground motion for earthquakes causing severe damage in the area. Two seismotectonic regimes are distinguished. Volcano-tectonic events, though being of limited magnitude (M_max ca. 5), cause strong ground shaking for their shallow foci. Being rather frequent, these events represent a considerable threat to cities and villages on the flanks of the volcano. A second regime is related to earthquakes with foci in the crust, at depths of 10–30 km, and magnitudes ranging from 6 to 7. In our synthetic scenarios, we chose two examples of volcano-tectonic events, i.e. the October 29, 2002, Bongiardo event (I = VIII) and the May 8, 1914, Linera earthquake (I = IX–X). A further scenario regards the February 20, 1818 event, considered representative for stronger earthquakes with foci in the crust. We were able to reproduce the essential features of the macroseismic field, in particular accounting for the possibility of strong site effects. We learned that stress drop estimated for weak motion events is probably too low to explain the intensity of ground motion during stronger earthquakes. This corresponds to findings reported in the literature claiming an increase of stress drop with earthquake size.  相似文献   

Book Reviews: Pharmaceuticals in the Environment: Sources,Fate, Effects and Risks. Edited by Klaus Kümmerer     

Moritz Schübler 《洁净——土壤、空气、水》2009,37(7):514-514

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Benthic nutrient fluxes along the Laurentian Channel: Impacts on the N budget of the St. Lawrence marine system     

Benoît Thibodeau  Moritz F. Lehmann  Jacqueline Kowarzyk  Alfonso Mucci  Yves Gélinas  Denis Gilbert  Roxane Maranger  Mohammad Alkhatib 《Estuarine, Coastal and Shelf Science》2010

Water column concentrations and benthic fluxes of dissolved inorganic nitrogen (DIN) and oxygen (DO) were measured in the Gulf of St. Lawrence and the Upper and Lower St. Lawrence Estuary (USLE and LSLE, respectively) to assess the nitrogen (N) budget in the St. Lawrence (SL) system, as well as to elucidate the impact of bottom water hypoxia on fixed-N removal in the LSLE. A severe nitrate deficit, with respect to ambient phosphate concentrations (N*∼−10 μmol L⁻¹), was observed within and in the vicinity of the hypoxic bottom water of the LSLE. Given that DO concentrations in the water column have remained above 50 μmol L⁻¹, nitrate reduction in suboxic sediments, rather than in the water column, is most likely responsible for the removal of fixed N from the SL system. Net nitrate fluxes into the sediments, derived from pore water nitrate concentration gradients, ranged from 190 μmol m⁻² d⁻¹ in the hypoxic western LSLE to 100 μmol m⁻² d⁻¹ in the Gulf. The average total benthic nitrate reduction rate for the Laurentian Channel (LC) is on the order of 690 μmol m⁻² d⁻¹, with coupled nitrification-nitrate reduction accounting for more than 70%. Using average nitrate reduction rates derived from the observed water column nitrate deficit, the annual fixed-N elimination within the three main channels of the Gulf of St. Lawrence and LSLE was estimated at 411 × 10⁶ t N, yielding an almost balanced N budget for the SL marine system.  相似文献   

Pressure dependence of color of natural uvarovite: the barochromic effect     

M. N. Taran  K. Langer  M. Koch-Müller 《Physics and Chemistry of Minerals》2008,35(3):175-177

The electronic absorption spectra of natural uvarovite containing 62 mole% of the Cr³⁺ end-member were studied at pressures between 10⁻⁴ and ca. 13 GPa using DAC techniques combined with microscope spectrometric device. With increasing pressure, a barochromic effect with change from green to red color of the garnet specimen was observed. This change could be interpreted on the basis of the spectra and the data points derived in an ICE color card. The evaluation of crystal field data from the spectra showed that 10Dq of chromium increases on pressure while the Racah parameter B, and thus the nature of the chemical bond of Cr–O does not change significantly.  相似文献   

Sr, C and O isotope systematics in the Pucará basin, central Peru     

R. Moritz  L. Fontboté  J. Spangenberg  S. Rosas  Z. Sharp  D. Fontignie 《Mineralium Deposita》1996,31(3):147-162

A combined Sr, O and C isotope study has been carried out in the Pucará basin, central Peru, to compare local isotopic trends of the San Vicente and Shalipayco Zn-Pb Mississippi Valley-type (MVT) deposits with regional geochemical patterns of the sedimentary host basin. Gypsum, limestone and regional replacement dolomite yield ⁸⁷Sr/⁸⁶Sr ratios that fall within or slightly below the published range of seawater ⁸⁷Sr/⁸⁶Sr values for the Lower Jurassic and the Upper Triassic. Our data indicate that the Sr isotopic composition of seawater between the Hettangian and the Toarcian may extend to lower ⁸⁷Sr/⁸⁶Sr ratios than previously published values. An ⁸⁷Sr-enrichment is noted in (1) carbonate rocks from the lowermost part of the Pucará basin, and (2) different carbonate generations at the MVT deposits. This indicates that host rocks at MVT deposits and in the lower-most part of the carbonate sequence interacted with ⁸⁷Srenriched fluids. The fluids acquired their radiogenic nature by interaction with lithologies underlying the carbonate rocks of the Pucará basin. The San Ramón granite, similar Permo-Triassic intrusions and their clastic derivatives in the Mitu Group are likely sources of radiogenic ⁸⁷Sr. The Brazilian shield and its erosion products are an additional potential source of radiogenic ⁸⁷Sr. Volcanic rocks of the Mitu Group are not a significant source for radiogenic ⁸⁷Sr; however, molasse-type sedimentary rocks and volcaniclastic rocks cannot be ruled out as a possible source of radiogenic ⁸⁷Sr. The marked enrichment in ⁸⁷Sr of carbonates toward the lower part of the Pucará Group is accompanied by only a slight decrease in ¹⁸O values and essentially no change in ¹³C values, whereas replacement dolomite and sparry carbonates at the MVT deposits display a coherent trend of progressive ⁸⁷Sr-enrichment, and ¹⁸O- and ¹³C-depletion. The depletion in ¹⁸O in carbonates from the MVT deposits are likely related to a temperature increase, possibly coupled with a ¹⁸O-enrichment of the ore-forming fluids. Progressively lower ¹³C values throughout the paragenetic sequence at the MVT deposits are interpreted as a gradually more important contribution from organically derived carbon. Quantitative calculations show that a single fluid-rock interaction model satisfactorily reproduces the marked ⁸⁷Sr-enrichment and the slight decrease in ¹⁸O values in carbonate rocks from the lower part of the Pucará Group. By contrast, the isotopic covariation trends of the MVT deposits are better reproduced by a model combining fluid mixing and fluid-rock interaction. The modelled ore-bearing fluids have a range of compositions between a hot, saline, radiogenic brine that had interacted with lithologies underlying the Pucará sequence and cooler, dilute brines possibly representing local fluids within the Pucará sequence. The composition of the local fluids varies according to the nature of the lithologies present in the neighborhood of the different MVT deposits. The proportion of the radiogenic fluid in the modelled fluid mixtures interacting with the carbonate host rocks at the MVT deposits decreases as one moves up in the stratigraphic sequence of the Pucará Group.  相似文献   

Spectral models of AM Her stars     

S. H. Langer 《Astrophysics and Space Science》1987,131(1-2):577-581

Most of the optical light from AM Her systems is cyclotron radiation. Simple models for the spectrum and polarization are successful for some systems, but in others the spectrum rolls over more gently at high frequencies and is polarized over a wider range of frequencies than the models predict. This paper considers the emission from both the sides and top of the accretion column and the effects of oscillations in the shock height. These features lead to a slower roll over at high frequencies than is found in the simple models, but it is still not as flat as in some of the AM Her systems.Paper presented at the IAU Colloquium No. 93 on Cataclysmic Variables. Recent Multi-Frequency Observations and Theoretical Developments, held at Dr. Remeis-Sternwarte Bamberg, F.R.G., 16–19 June, 1986.  相似文献   

Biases on the cosmological parameters and thermal Sunyaev–Zel'dovich residuals     

Nicolas Taburet  Nabila Aghanim  Marian Douspis  Mathieu Langer 《Monthly notices of the Royal Astronomical Society》2009,392(3):1153-1158

We examine the biases induced on cosmological parameters when the presence of secondary anisotropies is not taken into account in cosmic microwave background analyses. We first develop an exact analytical expression for computing the biases on parameters when any additive signal is neglected in the analysis. We then apply it in the context of the forthcoming Planck experiment. For illustration, we investigate the effect of the sole residual thermal Sunyaev–Zel'dovich signal that remains after cluster extraction. We find, in particular, that analyses neglecting the presence of this contribution introduce on the cosmological parameters n _s and τ biases, at least ∼6.5 and 2.9 times their 1σ confidence intervals. The Ω_b parameter is also biased to a lesser extent.  相似文献   

Synthesis and some properties of iron- and vanadium-bearing kyanites, (Al,Fe3+)2SiO5and (Al,V3+)2SiO5     

K. Langer  K. R. Frentrup 《Contributions to Mineralogy and Petrology》1973,41(1):31-46

Iron- and vanadium-bearing kyanites have been synthesized at 900 and 1100° C/20 kb in a piston-cylinder apparatus using Mn₂O₃/Mn₃O₄- and MnO/Mn-mixtures, respectively, as oxygen buffers. Solid solubility on the pseudobinary section Al₂SiO₅-Fe₂SiO₅(-V₂SiO₅) of the system Al₂O₃-Fe₂O₃(V₂O₃)-SiO₂ extends up to 6.5 mole% (14mole %) of the theoretical end member FeSiO₅(V₂SiO₅) at 900°C/20 kb. For bulk compositions with higher Fe₂SiO₅ (V₂SiO₅) contents the corundum type phases M₂O₃(M = Fe³⁺, V³⁺) are found to coexist with the Fe³⁺(V³⁺)-saturated kyanite solid solution plus quartz. The extent of solid solubility on the join Al₂SiO₅-Fe₂SiO₅ at 1 100°C was not found to be significantly higher than at 900° C. Microprobe analyses of iron bearing kyanites gave no significant indication of ternary solid solubility in these mixed crystals. Lattice constants a ₀, b ₀, c ₀, and V₀ of the kyanite solid solutions increase with increasing Fe₂SiO₅- and V₂SiO₅-contents proportionally to the ionic radii of Fe³⁺ and V³⁺, respectively, the triclinic angles ,, remain constant. Iron kyanites are light yellowish-green, vanadium kyanites are light green. Iron kyanites, (Al_1.87 Fe _0.13 ³⁺ )SiO₅, were obtained as crystals up to 700 m in length.  相似文献