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261.
The L1-SAIF (L1 Submeter-class Augmentation with Integrity Function) signal is one of the Quasi-Zenith Satellite System (QZSS) navigation signals, which provides an augmentation function for mobile users in Japan. The tropospheric delay correction in the L1-SAIF augmentation is discussed in detail. Because the topographical features in Japan are complicated, the correction information is generated from GPS observation data collected at 200 GPS stations which are densely distributed over Japan. A total of 210 Tropospheric Grid Points (TGPs) are arranged to fully cover Japan. The TGPs that provide the correction information are selected adaptively to achieve the expected correction accuracy. This selection of TGPs is provided by the TGP mask message. Mobile users acquire the zenith tropospheric delay (ZTD) value at neighboring TGPs from the correction messages, and can estimate the local ZTD value accurately by using a suitable ZTD model. Only up to seven L1-SAIF messages are sufficient to provide the full correction information. Accuracy evaluations have proven that it is possible to achieve a correction accuracy of 13.4 mm RMS. The strategy presented here has been implemented into the augmentation system using the L1-SAIF signal, and its application guidance is presented in the QZSS interface specification.  相似文献   
262.
We have investigated the chemical forms, reactivities and transformation kinetics of Fe(III) species present in coastal water with ion exchange and filtration methods. To simulate coastal water system, a mixture of ferric iron and fulvic acid was added to filtered seawater and incubated for a minute to a week. At each incubation time, the seawater sample was acidified with hydrochloric acid and then applied to anion exchange resin (AER) to separate negatively charged species (such as fulvic acid, its complexes with iron and iron oxyhydroxide coated with fulvic acid) from positively charged inorganic ferric iron (Fe(III)′). By monitoring the acid-induced Fe(III)′ over an hour, it was found that iron complexed by fulvic acid dissociated rapidly to a large extent (86–92% at pH 2), whereas amorphous ferric oxyhydroxide particles associated with fulvic acid (AFO-L) dissociated very slowly with the first-order dissociation rate constants ranging from 6.1 × 10− 5 for pH 3 to 2.7 × 10− 4 s− 1 for pH 2. Therefore, a brief acidification followed by the AER treatment (acidification/AER method) was likely to be able to determine fulvic acid complexes and thus differentiate the complexes from the AFO-L particles (the dissolution of AFO-L was insignificant during the brief acidification). The acidification/AER method coupled with a simple filtration technique suggested that the iron–fulvic acid complexes exist in both the < 0.02 μm and 0.02–0.45 μm size fractions in our coastal water system. The truly dissolved iron (< 0.02 μm) was relatively long-lived with a life-time of 14 days, probably due to the complexation by strong ligands. Such an acid-labile iron may be an important source of bioavailable iron in coastal environments, as a significant relationship between the chemical lability and bioavailability of iron has been well recognised.  相似文献   
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