Intrinsic groundwater vulnerability determination at the aquifer scale: a methodology coupling travel time estimation and rating methods     

Vassilios?Pisinaras  Christos?Polychronis  Alexandra?GemitziEmail author 《Environmental Earth Sciences》2016,75(1):85

Groundwater vulnerability has been subject of much research due to the valuable information it provides concerning groundwater protection and exploitation potential. Up to now, most groundwater vulnerability studies adopt subjective systems of rating the various factors and subsequently, their results are often ambiguous and contradicting. Within the present study a methodology for the estimation of intrinsic groundwater vulnerability at the aquifer scale is presented. The methodology is based on travel time estimation from specified sources of pollution to the aquifer. Besides the deterministic calculation of travel times, the methodology provides a rating system for each pollution source, based on its relative severity and the estimated threat that it poses to the aquifer. Therefore, it can be regarded as a hybrid method that couples the advantages provided by the physically based methods with those of the subjective rating systems. The methodology is applied to the Neon Sidirochorion aquifer, Northeastern Greece, an overexploited aquifer where river waters, sea waters and lake waters interact, causing groundwater quality deterioration to the aquifer. The results indicated that the proposed groundwater vulnerability assessment methodology is well capturing pollution related to saltwater intrusion and agricultural activities, while it is concluded that the conceptual model is significantly affecting the vulnerability assessment results and therefore has to be previously developed.  相似文献   

Estimation of air-overpressure produced by blasting operation through a neuro-genetic technique     

Edy?Tonnizam Mohamad  Danial?Jahed ArmaghaniEmail author  Mahdi?Hasanipanah  Bhatawdekar?Ramesh?Murlidhar  Mohd?Nur?Asmawisham?Alel 《Environmental Earth Sciences》2016,75(2):174

Blasting operations usually produce significant environmental problems which may cause severe damage to the nearby areas. Air-overpressure (AOp) is one of the most important environmental impacts of blasting operations which needs to be predicted and subsequently controlled to minimize the potential risk of damage. In order to solve AOp problem in Hulu Langat granite quarry site, Malaysia, three non-linear methods namely empirical, artificial neural network (ANN) and a hybrid model of genetic algorithm (GA)–ANN were developed in this study. To do this, 76 blasting operations were investigated and relevant blasting parameters were measured in the site. The most influential parameters on AOp namely maximum charge per delay and the distance from the blast-face were considered as model inputs or predictors. Using the five randomly selected datasets and considering the modeling procedure of each method, 15 models were constructed for all predictive techniques. Several performance indices including coefficient of determination (R ²), root mean square error and variance account for were utilized to check the performance capacity of the predictive methods. Considering these performance indices and using simple ranking method, the best models for AOp prediction were selected. It was found that the GA–ANN technique can provide higher performance capacity in predicting AOp compared to other predictive methods. This is due to the fact that the GA–ANN model can optimize the weights and biases of the network connection for training by ANN. In this study, GA–ANN is introduced as superior model for solving AOp problem in Hulu Langat site.  相似文献   

Sedimentology and Sequence Stratigraphy of Marine to Lacustrine Deltaic Deposits in a Craton Basin and Their Controlling Factors: Shan 2 Member–He 8 Member (Guadalupian–Lopingian, Permian), Southeast Ordos Basin, North China     

SHAN Xin  YU Xinghe  Peter ?CLIFT  LI Yalong  JIN Lin  SU Dongxu  DU Yonghui  ZHOU Jinsong  HAN Xiaoqin 《《地质学报》英文版》2018,92(1):268-285

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Hydrochemical,isotopic, and reservoir characterization of the Pasinler (Erzurum) geothermal field,eastern Turkey     

Esra Hatipoğlu Temizel  Fatma Gültekin 《Arabian Journal of Geosciences》2018,11(1):3

The reservoir temperature and conceptual model of the Pasinler geothermal area, which is one of the most important geothermal areas in Eastern Anatolia, are determined by considering its hydrogeochemical and isotope properties. The geothermal waters have a temperature of 51 °C in the geothermal wells and are of Na–Cl–HCO₃ type. The isotope contents of geothermal waters indicate that they are of meteoric origin and that they recharge on higher elevations than cold waters. The geothermal waters are of immature water class and their reservoir temperatures are calculated as 122–155 °C, and their cold water mixture rate is calculated as 32%. According to the δ¹³C_VPDB values, the carbon in the geothermal waters originated from the dissolved carbon in the groundwaters and mantle-based CO₂ gases. According to the δ³⁴S_CDT values, the sources of sulfur in the geothermal waters are volcanic sulfur, oil and coal, and limestones. The sources of the major ions (Na⁺, Ca²⁺, Mg²⁺, Cl^?, and HCO₃ ^?) in the geothermal waters are ion exchange and plagioclase and silicate weathering. It is determined that the volcanic rocks in the area have effects on the water chemistry and elements like Zn, Rb, Sr, and Ba originated from the rhyolite, rhyolitic tuff, and basalts. The rare earth element (REE) content of the geothermal waters is low, and according to the normalized REE diagrams, the light REE are getting depleted and heavy REE are getting enriched. The positive Eu and negative Ce anomalies of waters indicate oxygen-rich environments.  相似文献   

Teleseismic finite-fault inversion of two <Emphasis Type="Italic">M</Emphasis><Subscript>w</Subscript> = 6.4 earthquakes along the East Anatolian Fault Zone in Turkey: the 1998 Adana and 2003 Bingöl earthquakes     

Murat Utkucu  Emrah Budakoğlu  Meltem Çabuk 《Arabian Journal of Geosciences》2018,11(22):721

The East Anatolian Fault Zone is a continental transform fault accommodating westward motion of the Anatolian fault. This study aims to investigate the source properties of two moderately large and damaging earthquakes which occurred along the transform fault in the last two decades using the teleseismic broadband P and SH body waveforms. The first earthquake, the 27 June 1998 Adana earthquake, occurred beneath the Adana basin, located close to the eastern extreme of Turkey’s Mediterranean coast. The faulting associated with the 1998 Adana earthquake is unilateral to the NE and confined to depths below 15 km with a length of 30 km along the strike (53°) and a dipping of 81° SE. The fixed-rake models fit the data less well than the variable-rake model. The main slip area centered at depth of about 27 km and to the NE of the hypocenter, covering a circular area of 10 km in diameter with a peak slip of about 60 cm. The slip model yields a seismic moment of 3.5?×?10¹⁸ N-m (M_w???6.4). The second earthquake, the 1 May 2003 Bingöl earthquake, occurred along a dextral conjugate fault of the East Anatolian Fault Zone. The preferred slip model with a seismic moment of 4.1?×?10¹⁸ N-m (M_w???6.4) suggests that the rupture was unilateral toward SE and was controlled by a failure of large asperity roughly circular in shape and centered at a depth of 5 km with peak displacement of about 55 cm. Our results suggest that the 1998 Adana earthquake did not occur on the mapped Göksun Yakap?nar Fault Zone but rather on a SE dipping unmapped fault that may be a split fault of it and buried under the thick (about 6 km) deposits of the Adana basin. For the 2003 Bingöl earthquake, the final slip model requires a rupture plane having 15° different strike than the most possible mapped fault.  相似文献   

Formation by silicate–fluoride + phosphate melt immiscibility of REE-rich globular segregations within aplite dikes     

Charles?R.?SternEmail author  Julien?M.?Allaz  Markus?B.?Raschke  G.?Lang?Farmer  M.?Alexandra?Skewes  Jeremy?T.?Ross 《Contributions to Mineralogy and Petrology》2018,173(8):65

Aplite dikes intruding the Proterozoic 1.42(±?3) Ga Longs Peak-St. Vrain Silver Plume-type peraluminous granite near Jamestown, Colorado, contain F, P, and rare earth element (REE)-rich globular segregations, with 40–46% REE, 3.7–4.8 wt% P₂O₅, and 5–8 wt% F. A combination of textural features and geochemical data suggest that the aplite and REE-rich globular segregations co-existed as two co-genetic liquids prior to their crystallization, and we propose that they are formed by silicate–fluoride?+?phosphate (+?S?+?CO₂) melt immiscibility following ascent, cooling, and decompression of what was initially a single homogeneous magma that intruded the granite. The REE distribution coefficients between the silica-rich aplites and REE-rich segregations are in good agreement with experimentally determined distribution coefficients for immiscible silicate–fluoride?+?phosphate melts. Although monazite-(Ce) and uraninite U–Th–Pb microprobe ages for the segregations yield 1.420(±?25) and 1.442(±?8) Ga, respectively, thus suggesting a co-genetic relationship with their host granite, ε_Nd1.42Ga values for the granites and related granitic pegmatites range from ??3.3 to ??4.7 (average ??3.9), and differ from the values for both the aplites and REE-rich segregations, which range from ??1.0 to ??2.2 (average ??1.6). Furthermore, the granites and pegmatites have (La/Yb)_N <50 with significant negative Eu anomalies, which contrast with higher (La/Yb)_N >100 and absence of an Eu anomaly in both the aplites and segregations. These data are consistent with the aplite dikes and the REE-rich segregations they contain being co-genetic, but derived from a source different from that of the granite. The higher ε_Nd1.42Ga values for the aplites and REE-rich segregations suggest that the magma from which they separated had a more mafic and deeper, dryer and hotter source in the lower crust or upper mantle compared to the quartzo-feldspathic upper crustal source proposed for the Longs Peak-St. Vrain granite.  相似文献   

Carbon and nitrogen isotope,and mineral inclusion studies on the diamonds from the Pozanti–Karsanti chromitite,Turkey     

Dongyang?LianEmail authorView author&#;s OrcID profile  Jingsui?Yang  Michael?Wiedenbeck  Yildirim?Dilek  Alexander?Rocholl  Weiwei?Wu 《Contributions to Mineralogy and Petrology》2018,173(9):72

The Pozanti–Karsanti ophiolite (PKO) is one of the largest oceanic remnants in the Tauride belt, Turkey. Micro-diamonds were recovered from the podiform chromitites, and these diamonds were investigated based on morphology, color, cathodoluminescence, nitrogen content, carbon and nitrogen isotopes, internal structure and inclusions. The diamonds recovered from the PKO are mainly mixed-habit diamonds with sectors of different brightness under the cathodoluminescence images. The total δ¹³C range of the PKO diamonds varies between ??18.8 and ??28.4‰, with a principle δ¹³C mode at ??25‰. Nitrogen contents of the diamonds range from 7 to 541 ppm with a mean value of 171 ppm, and the δ¹⁵N values range from ??19.1 to 16.6‰, with a δ¹⁵N mode of ??9‰. Stacking faults and partial dislocations are commonly observed in the Transmission Electron Microscopy foils whereas inclusions are rather rare. Combinations of (Ca_0.81Mn_0.19)SiO₃, NiMnCo-alloy and nano-sized, quenched fluid phases were observed as inclusions in the PKO diamonds. We believe that the ¹³C-depleted carbon signature of the PKO diamonds derived from previously subducted crustal matter. These diamonds may have crystallized from C-saturated fluids in the asthenospheric mantle at depth below 250 km which were subsequently carried rapidly upward by asthenospheric melts.  相似文献   

Experimental study of quartz inclusions in garnet at pressures up to 3.0 GPa: evaluating validity of the quartz-in-garnet inclusion elastic thermobarometer     

Jay?B.?ThomasEmail authorView author&#;s OrcID profile  Frank?S.?Spear 《Contributions to Mineralogy and Petrology》2018,173(5):42

Garnet crystals with quartz inclusions were hydrothermally crystallized from oxide starting materials in piston–cylinder apparatuses at pressures from 0.5 to 3 GPa and temperatures ranging from 700 to 800 °C to study how entrapment conditions affect remnant pressures of quartz inclusions used for quartz-in-garnet (QuiG) elastic thermobarometry. Systematic changes of the 128, 206 and 464 cm^?1 Raman band frequencies of quartz were used to determine pressures of quartz inclusions in garnet using Raman spectroscopy calibrations that describe the P–T dependencies of Raman band shifts for quartz under hydrostatic pressure. Within analytical uncertainties, inclusion pressures calculated for each of the three Raman band frequencies are equivalent, which suggests that non-hydrostatic stress effects caused by elastic anisotropy in quartz are smaller than measurement errors. The experimental quartz inclusions have pressures ranging from ??0.351 to 1.247 GPa that span the range of values observed for quartz inclusions in garnets from natural rocks. Quartz inclusion pressures were used to model P–T conditions at which the inclusions could have been trapped. The accuracy of QuiG thermobarometry was evaluated by considering the differences between pressures measured during experiments and pressures calculated using published equation of state parameters for quartz and garnet. Our experimental results demonstrate that Raman measurements performed at room temperature can be used without corrections to estimate garnet crystallization pressures. Calculated entrapment pressures for quartz inclusions in garnet are less than ~?10% different from pressures measured during the experiments. Because the method is simple to apply with reasonable accuracy, we expect widespread usage of QuiG thermobarometry to estimate crystallization conditions for garnet-bearing silicic rocks.  相似文献   

Electrical conductivity of the plagioclase–NaCl–water system and its implication for the high conductivity anomalies in the mid-lower crust of Tibet Plateau     

Ping?Li  Xinzhuan?GuoEmail author  Sibo?Chen  Chao?Wang  Junlong?Yang  Xingfan?Zhou 《Contributions to Mineralogy and Petrology》2018,173(2):16

In order to investigate the origin of the high conductivity anomalies geophysically observed in the mid-lower crust of Tibet Plateau, the electrical conductivity of plagioclase–NaCl–water system was measured at 1.2 GPa and 400–900 K. The relationship between electrical conductivity and temperature follows the Arrhenius law. The bulk conductivity increases with the fluid fraction and salinity, but is almost independent of temperature (activation enthalpy less than 0.1 eV). The conductivity of plagioclase–NaCl–water system is much lower than that of albite–NaCl–water system with similar fluid fraction and salinity, indicating a strong effect of the major mineral phase on the bulk conductivity of the brine-bearing system. The high conductivity anomalies of 10^?1 and 10⁰ S/m observed in the mid-lower crust of Tibet Plateau can be explained by the aqueous fluid with a volume fraction of 1 and 9%, respectively, if the fluid salinity is 25%. The anomaly value of 10^?1 S/m can be explained by the aqueous fluid with a volume fraction of 6% if the salinity is 10%. In case of Southern Tibet where the heat flow is high, the model of a thin layer of brine-bearing aqueous fluid with a high salinity overlying a thick layer of partial melt is most likely to prevail.  相似文献   

An experimental study of Fe–Ni exchange between sulfide melt and olivine at upper mantle conditions: implications for mantle sulfide compositions and phase equilibria     

Zhou?ZhangEmail authorView author&#;s OrcID profile  Anette?von der Handt  Marc?M.?Hirschmann 《Contributions to Mineralogy and Petrology》2018,173(3):19

The behavior of nickel in the Earth’s mantle is controlled by sulfide melt–olivine reaction. Prior to this study, experiments were carried out at low pressures with narrow range of Ni/Fe in sulfide melt. As the mantle becomes more reduced with depth, experiments at comparable conditions provide an assessment of the effect of pressure at low-oxygen fugacity conditions. In this study, we constrain the Fe–Ni composition of molten sulfide in the Earth’s upper mantle via sulfide melt–olivine reaction experiments at 2 GPa, 1200 and 1400 °C, with sulfide melt \(X_{{{\text{Ni}}}}^{{{\text{Sulfide}}}}=\frac{{{\text{Ni}}}}{{{\text{Ni}}+{\text{Fe}}}}\) (atomic ratio) ranging from 0 to 0.94. To verify the approach to equilibrium and to explore the effect of \({f_{{{\text{O}}_{\text{2}}}}}\) on Fe–Ni exchange between phases, four different suites of experiments were conducted, varying in their experimental geometry and initial composition. Effects of Ni secondary fluorescence on olivine analyses were corrected using the PENELOPE algorithm (Baró et al., Nucl Instrum Methods Phys Res B 100:31–46, 1995), “zero time” experiments, and measurements before and after dissolution of surrounding sulfides. Oxygen fugacities in the experiments, estimated from the measured O contents of sulfide melts and from the compositions of coexisting olivines, were 3.0?±?1.0 log units more reduced than the fayalite–magnetite-quartz (FMQ) buffer (suite 1, 2 and 3), and FMQ ??1 or more oxidized (suite 4). For the reduced (suites 1–3) experiments, Fe–Ni distribution coefficients \(K_{{\text{D}}}^{{}}=\frac{{(X_{{{\text{Ni}}}}^{{{\text{sulfide}}}}/X_{{{\text{Fe}}}}^{{{\text{sulfide}}}})}}{{(X_{{{\text{Ni}}}}^{{{\text{olivine}}}}/X_{{{\text{Fe}}}}^{{{\text{olivine}}}})}}\) are small, averaging 10.0?±?5.7, with little variation as a function of total Ni content. More oxidized experiments (suite 4) give larger values of K_D (21.1–25.2). Compared to previous determinations at 100 kPa, values of K_D from this study are chiefly lower, in large part owing to the more reduced conditions of the experiments. The observed difference does not seem attributable to differences in temperature and pressure between experimental studies. It may be related in part to the effects of metal/sulfur ratio in sulfide melt. Application of these results to the composition of molten sulfide in peridotite indicates that compositions are intermediate in composition (\(X_{{{\text{Ni}}}}^{{{\text{sulfide}}}}\)?~?0.4–0.6) in the shallow mantle at 50 km, becomes more Ni rich with depth as the O content of the melt diminishes, reaching a maximum (0.6–0.7) at depths near 80–120 km, and then becomes more Fe rich in the deeper mantle where conditions are more reduced, approaching (\(X_{{{\text{Ni}}}}^{{{\text{sulfide}}}}\)?~?0.28)?>?140 km depth. Because Ni-rich sulfide in the shallow upper mantle melts at lower temperature than more Fe-rich compositions, mantle sulfide is likely molten in much of the deep continental lithosphere, including regions of diamond formation.  相似文献