Oxidation modes and thermodynamics of Fe oxyhydroxycarbonate green rust: Dissolution-precipitation versus in situ deprotonation     

Christian Ruby  Mustapha Abdelmoula  Aurélien Renard  Georges Ona-Nguema  Jean-Marie R. Génin 《Geochimica et cosmochimica acta》2010,74(3):953-966

Fe^II-III hydroxycarbonate green rust GR(CO₃²⁻), Fe^II₄ Fe^III₂ (OH)₁₂ CO₃·3H₂O, is oxidized in aqueous solutions with varying reaction kinetics. Rapid oxidation with either H₂O₂ or dissolved oxygen under neutral and alkaline conditions leads to the formation of ferric oxyhydroxycarbonate GR(CO₃²⁻)∗, Fe^III₆ O₁₂ H₈ CO₃·3H₂O, via a solid-state reaction. By decreasing the flow of oxygen bubbled in the solution, goethite α-FeOOH forms by dissolution-precipitation mechanism whereas a mixture of non-stoichiometric magnetite Fe_(3−x)O₄ and goethite is observed for lower oxidation rates. The intermediate Fe^II-III oxyhydroxycarbonate of formula Fe^II_6(1−x) Fe^III_6x O₁₂ H_2(7−3x) CO₃·3H₂O, i.e. GR(x)∗ for which x ? [1/3, 1], is the synthetic compound that is homologous to the fougerite mineral present in hydromorphic gleysol; in situ oxidation accounts for the variation of ferric molar fraction x = [Fe^III]/{[Fe^II]+[Fe^III]} observed in the field as a function of depth and season but limited to the range [1/3, 2/3]. The domain of stability for partially oxidized green rust is observed in the E_h-pH Pourbaix diagrams if thermodynamic properties of GR(x)∗ is compared with those of lepidocrocite, γ-FeOOH, and goethite, α-FeOOH. Electrochemical equilibrium between GR(x)∗ and Fe^II in solution corresponds to E_h-pH conditions close to those measured in the field. Therefore, the reductive dissolution of GR(x)∗ can explain the relatively large concentration of Fe^II measured in aqueous medium of hydromorphic soils containing fougerite.  相似文献   

High-order Statistics of Spatial Random Fields: Exploring Spatial Cumulants for Modeling Complex Non-Gaussian and Non-linear Phenomena   总被引：9，自引：7，他引：2  

Roussos Dimitrakopoulos  Hussein Mustapha  Erwan Gloaguen 《Mathematical Geosciences》2010,42(1):65-99

The spatial distributions of earth science and engineering phenomena under study are currently predicted from finite measurements and second-order geostatistical models. The latter models can be limiting, as geological systems are highly complex, non-Gaussian, and exhibit non-linear patterns of spatial connectivity. Non-linear and non-Gaussian high-order geostatistics based on spatial connectivity measures, namely spatial cumulants, are proposed as a new alternative modeling framework for spatial data. This framework has two parts. The first part is the definition, properties, and inference of spatial cumulants—including understanding the interrelation of cumulant characteristics with the in-situ behavior of geological entities or processes, as examined in this paper. The second part is the research on a random field model for simulation based on its high-order spatial cumulants. Mathematical definitions of non-Gaussian spatial random functions and their high-order spatial statistics are presented herein, stressing the notion of spatial cumulants. The calculation of spatial cumulants with spatial templates follows, including anisotropic experimental cumulants. Several examples of two- and three-dimensional images, including a diamond bearing kimberlite pipe from the Ekati Mine in Canada, are analyzed to assess the relations between cumulants and the spatial behavior of geological processes. Spatial cumulants of orders three to five are shown to capture directional multiple-point periodicity, connectivity including connectivity of extreme values, and spatial architecture. In addition, they provide substantial information on geometric characteristics and anisotropy of geological patterns. It is further shown that effects of complex spatial patterns are seen even if only subsets of all cumulant templates are computed. Compared to second-order statistics, cumulant maps are found to include a wealth of additional information from underlying geological patterns. Further work seeks to integrate this information in the predictive capabilities of a random field model.  相似文献   

Observations of sea ice interannual variations and spring bloom occurrences at the Japanese scallop farming area in the Okhotsk Sea using satellite imageries   总被引：1，自引：0，他引：1  

Muzzneena Ahmad Mustapha  Sei-Ichi Saitoh 《Estuarine, Coastal and Shelf Science》2008,77(4):577-588

The dynamics of ice formation and phytoplankton bloom development in the coastal region of the Okhotsk Sea, Hokkaido, where the Japanese scallop, Mizuhopecten yessoensis, are cultured were investigated using seven years (1998–2004) satellite data from the Special Sensor Microwave/Imager (SSM/I) and Sea-viewing Wide Field-of-view Sensor (SeaWiFS). The interannual variability of sea ice cover and timing of spring bloom occurrences were analyzed. Longer ice cover in 1999, 2001 and 2003 with the presence of ice until early April and shortened ice cover in 1998, 2000, 2002 and 2004 with the occurrence of ice until early March were recognized at this area. Variability in the timing of sea ice retreat and development of spring blooms at the scallop areas were observed. Progression of a single ice edge bloom showed higher Chl-a concentration compared to development of an initial ice edge bloom followed by a later open water bloom. Higher concentration of phytoplankton biomass was observed in the initial bloom when sea ice melting is delayed compared to when the sea ice leaves earlier. Wind events were also observed to affect the occurrences of spring bloom.  相似文献   

Report on the Diatoms and Dinoflagellates Distribution along the Algerian Coasts: Inter-Region Comparison     

Zakia MOKRANE  Mustapha BOUDJENAH  Yasmina BELKACEM  EL Hadi MORSLI  Ahmed INAL  Fahima BOUARAB 《资源与生态学报(英文版)》2019,10(4):432-440

The phytoplankton group’s composition is an excellent indicator of the state of coastal waters. The aim of this study is to explore spatial variability of phytoplankton in shallow coastal areas from different regions (East, Center and West) of the Algerian coast. The quantitative and qualitative study of the phytoplankton population was conducted on samples taken during the 2012-2013 period by the research vessel GRINE BELKACEM. The qualitative results show a significant diversity of diatoms and dinoflagellates, which rank first and second in the total flora (Fr > 50%). This finding is also confirmed quantitatively by the abundance values in both 2013 and 2012 samples which largely exceeds the average value in most other areas of the western region (56%) and slightly exceeding 52% in all central areas which represent an equi-distribution between diatoms and dinoflagellates. The Dinoflagellates contribute significantly to the quantitative richness in the eastern region (>60%). The minimum value of Dia/Dino index, recorded in the eastern region confirms the dominance of the dinoflagellates especially in Skikda (0.31) (Skikda).However, our results reveal the presence, in smaller proportion, of other groups such as the cocolithophoridae and euglenophyceae.  相似文献