Root‐related rhodochrosite and concretionary siderite formation in oxygen‐deficient conditions induced by a ground‐water table rise          下载免费PDF全文

Maciej J. Bojanowski  Elżbieta Jaroszewicz  Adrijan Košir  Maciej Łoziński  Leszek Marynowski  Anna Wysocka  Arkadiusz Derkowski 《Sedimentology》2016,63(3):523-551

Sedimentological, mineralogical, stable carbon and oxygen isotope determinations and biomarker analyses were performed on siderite concretions occurring in terrestrial silts to understand their formation and to characterize the sedimentary and diagenetic conditions favouring their growth. High δ¹³C values (6·4‰ on average) indicate that siderite precipitated in an anoxic environment where bacterial methanogenesis operated. The development of anoxic conditions during shallow burial was induced by a change in sedimentary environment from flood plain to swamp, related to a rise of the ground‐water table. Large amounts of decaying plant debris led to efficient oxygen consumption within the pore‐water in the peat. Oxygen depletion, in combination with a decrease in sedimentation rate, promoted anoxic diagenetic conditions under the swamp and favoured abundant siderite precipitation. This shows how a change in sedimentary conditions can have a profound impact on the early‐diagenetic environment and carbonate authigenesis. The concretions contain numerous rhizoliths; they are cemented with calcium‐rhodochrosite, a feature which has not been reported before. The rhodochrosite cement has negative δ¹³C values (?16·5‰ on average) and precipitated in suboxic conditions due to microbial degradation of roots coupled to manganese reduction. The exceptional preservation of the epidermis/exodermis and xylem vessels of former root tissues indicates that the rhodochrosite formed shortly after the death of a root in water‐logged sediments. Rhodochrosite precipitated during the initial stages of concretionary growth in suboxic microenvironments within roots, while siderite cementation occurred simultaneously around them in anoxic conditions. These suboxic microenvironments developed because oxygen was transported from the overlying oxygenated soil into sediments saturated with anoxic water via roots acting as permeable conduits. This model explains how separate generations of carbonate cements having different mineralogy and isotopic compositions, which would conventionally be regarded as cements precipitated sequentially in different diagenetic zones during gradual burial, can form simultaneously in shallow burial settings where strong redox gradients exist around vertically oriented permeable root structures.  相似文献   

Ionic conductivity in gem-quality single-crystal alkali feldspar from the Eifel: temperature,orientation and composition dependence     

Hamid El Maanaoui  Fabian Wilangowski  Aditya Maheshwari  Hans-Dieter Wiemhöfer  Rainer Abart  Nicolaas A. Stolwijk 《Physics and Chemistry of Minerals》2016,43(5):327-340

We measured the ion conductivity of single-crystal alkali feldspar originating from two different locations in the Eifel/Germany, named Volkesfeld and Rockeskyller sanidine and having potassium site fractions \(C_\mathrm{K}\) of 0.83 and 0.71, respectively. The dc conductivities resulting from electrochemical impedance spectroscopy over the temperature range of 300–900 \(^{\circ }\hbox {C}\) show a weak composition dependence but pronounced differences between the b-direction [\(\perp (010)\)] and \(c^{*}\)-direction [\(\perp (001)\)] of the monoclinic feldspar structure. Conductivity activation energies obtained from the observed linear Arrhenius plots are close to 1.2 eV in all cases, which is closely similar to the activation energies of the \(^{22}\mathrm{Na}\) tracer diffusivity in the same crystals. Taking into account literature data on K tracer diffusion and diffusion correlation effects, the present results point to a predominance of the interstitialcy mechanism over the vacancy mechanism in mass and charge transport on the alkali sublattice in potassium-rich alkali feldspar.  相似文献   

Trends in indices of daily temperature and precipitations extremes in Morocco   总被引：1，自引：0，他引：1  

S. Filahi  M. Tanarhte  L. Mouhir  M. El Morhit  Y. Tramblay 《Theoretical and Applied Climatology》2016,124(3-4):959-972

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Tectono-sedimentary evolution of the Miocene Oued Dayr Formation (Ghomaride Complex,Internal Domain of the Maghrebian Rif Belt,Morocco)     

Bilal?El OuaragliEmail author  Mohamed?Najib?Zaghloul  Hajar?El Talibi  Roberta?Somma 《Arabian Journal of Geosciences》2016,9(15):660

This work deals with sedimentological, petrographic, and structural analyses of a middle Miocene late-orogenic sedimentary cycle, denoted Oued Dayr Formation, recognized in the Rifian sector of the Maghrebian Chain (Morocco). The analyzed Formation (75 m thick) starts with 15–20 m of light colored polymict conglomerates, with minor sandstone beds, lying on the Paleozoic basement and Mesozoic cover of the Ghomaride Nappe. Facies analysis indicates a fining-upward deposition in a marine environment characterized by increasing deepening, reflecting a subsidence rate that exceeds sedimentary supply. Petrographic analysis points out that sandstones are represented by litharenites originated by erosion of recycled orogen. The conglomerates pebbles and cobbles consist of Alpine low- to high-grade metamorphic rocks as metarenites, phyllites, mylonitic quartzites, micaschists, augen gneisses deriving from the exhumed deep metamorphic basement, the overlying metasedimentary of the Sebtide Nappes and of sedimentary rocks as sandstones, jaspes, limestones, and shales deriving from the Ghomaride Nappes and their sedimentary cover. Data reveal mixed provenance indicating that the Oued Dayr Formation was fed by the Internal Nappes stack of the Maghrebian Chain. Structural analysis shows that the Oued Dayr Formation accumulated in a Thrust-Top basin, during an early extension (D₀ phase), recorded by synsedimentary normal faults within middle Langhian deposits on the rear of the Internal Nappes stack. Subsequent ductile and brittle compressional (D₁, D₂, D₃) and extensional (D₄) deformation phases occurred during and/or after the stacking, exhumation, and early unroofing of Sebtide Complex coeval with the opening of the western Mediterranean back-arc basins since middle Miocene time.  相似文献   

The influence of physical and biological processes on the ichthyoplankton communities in the Gulf of Sirte (Southern Mediterranean Sea)          下载免费PDF全文

Angela Cuttitta  Sergio Bonomo  Salem Zgozi  Angelo Bonanno  Bernardo Patti  Enza Maria Quinci  Marco Torri  Mohamed Hamza  Abdul Fatah  Daw Haddoud  Akram El Turki  Abdul Bari Ramadan  Simona Genovese  Salvatore Mazzola 《Marine Ecology》2016,37(4):831-844

This paper reports on the first study on the ichthyoplankton community structure in the Gulf of Sirte and its spatial distribution in relation to environmental conditions and zooplankton abundance. The results make an important contribution to the future management of fisheries in this unexplored, but much exploited, area. Biological samples were collected in July 2008 using a Bongo40 net. In total, 1914 larvae were found and 1652 of these were identified. In particular, bathypelagic taxa were the most abundant, followed by demersal, mesopelagic, pelagic and epipelagic taxa. The ichthyoplankton community had a patchwork distribution influenced by oligotrophic conditions, the bottom depth and oceanographical features. The results suggest that environmental forcings were able to transport the ichthyoplankton to productive areas. Indeed, maximum fish egg densities were found in coastal stations in correspondence with the Atlantic Tunisian Current inflow, whereas larvae were mainly concentrated in the east side of the Gulf, probably as a result of advection by the anticyclonic circulation. Additionally, the distribution patterns of the total larvae density and the different assemblages were well matched with the abundance of the zooplankton, probably determining final larval survival, growth and recruitment.  相似文献   

Isotopic signatures for the assessment of snow water resources in the Moroccan high Atlas mountains: contribution to surface and groundwater recharge     

Angoran Baudelaire N’da  Lhoussaine Bouchaou  Barbara Reichert  Lahoucine Hanich  Yassine Ait Brahim  Abdelghani Chehbouni  El Hassane Beraaouz  Jean-Luc Michelot 《Environmental Earth Sciences》2016,75(9):755

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Isolation and characterization of <Emphasis Type="Italic">Pseudomonas</Emphasis> sp. NAF1 and its application in biodegradation of crude oil     

Abdullah M. El Mahdi  Hamidi Abdul Aziz  Salem S. Abu Amr  Nour Sh El-Gendy  Hussein N. Nassar 《Environmental Earth Sciences》2016,75(5):380

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Contrasting sources of Late Paleozoic rhyolite magma in the Polish Lowlands: evidence from U–Pb ages and Hf and O isotope composition in zircon     

Słodczyk  Elżbieta  Pietranik  Anna  Glynn  Sarah  Wiedenbeck  Michael  Breitkreuz  Christoph  Dhuime  Bruno 《International Journal of Earth Sciences》2018,107(6):2065-2081

International Journal of Earth Sciences - The Polish Lowlands, located southwest of the Teisseyre–Tornquist Zone, within Trans-European Suture Zone, were affected by bimodal, but dominantly...  相似文献   

Phosphorus removal efficiency from wastewater under different loading conditions using sand biofilters augmented with biochar     

A. El Hanandeh  M. Gharaibeh  A. A. Albalasmeh 《International Journal of Environmental Science and Technology》2018,15(5):927-934

Treated wastewater is a valuable resource, particularly in countries facing water shortage such as Jordan. Nevertheless, excess nutrients, especially phosphorus, may have detrimental impacts on receiving waterbodies. Treated wastewater in Jordan often exceeds the recommended levels set by the Jordanian Standards for wastewater reuse and discharge. Therefore, it is important to reduce phosphorus loads to acceptable levels before discharge. Biofiltration is a low-cost technology that has shown good potential for wastewater treatment. The performance of biofilters largely depends on the media used. In this study, local sand and sand augmented with biochar prepared from the olive oil processing waste (SBC) were used as filter media for phosphorus removal from clarified secondary treated wastewater. The two media types were tested under different hydraulic and phosphorus loading conditions to simulate shock, flooding, and inundation conditions. The results showed that sand media was more effective in removing phosphorus (90.8 ± 2.6%) than sand amended with biochar (83.3 ± 3.2%). Both media showed resilience under extreme loading conditions. Although phosphorus removal efficiency was negatively affected following the extreme loading events, the observed effects were temporary. The simulated inundation event further showed that the media was able to retain the adsorbed phosphorus. Furthermore, the phosphorus concentration in the effluent remained within the prescribed discharge guidelines at all times.  相似文献   

Dependence of radon exhalation on grain size of sedimentary waste     

Eman M. Ibrahim  Ibrahim E. El Aassy  Hayam Ahmed Abdel Ghany  S. H. Gamil 《Environmental Earth Sciences》2018,77(14):534

Tailings resulted from sulphuric acid leaching process of uranium from sedimentary rocks contain high concentrations of ²²⁶Ra and its daughters, the most important of which is ²²²Rn. Movement of radon gas out of the tailings is strongly influenced by the physicochemical characteristics of these tailings especially their radium content and the grain size. So, the tailing samples were size fractionated into four sizes (>?250, 250–125, 125–74 and <?74 µm). The natural radioactivity was investigated using hyper-pure germanium detector and solid-state nuclear track detectors (CR-39) for bulk size and after size fractionation. The activity concentrations of different radionuclides in size-fractionated tailing samples have been shown to be strongly dependent on the size of the particles. In the range of >?250 and <?74 µm, the activity concentrations of ²³⁰Th, ²²⁶Ra, ²¹⁴Pb, ²¹⁴Bi, ²¹⁰Pb, ²³²Th and ⁴⁰K increased throughout with decreasing particle size, while that of ²³⁸U, ²³⁴U and ²³⁵U have an opposite effect. The results revealed an inverse relationship between the radon exhalation rate and size fractionation. Also, the results showed a good correlation between radium activity concentration and radon mass exhalation rate.  相似文献