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排序方式: 共有103条查询结果,搜索用时 15 毫秒
61.
The nature, origin and distribution of US EPA polycyclic aromatic hydrocarbons (PAHs) in the sediments of Olbia harbor (North Sardinia, Italy) were investigated by gas-chromatography/mass spectrometry (GCMS). PAH concentrations in the sediments (SigmaPAHs) ranged from 0.16 to 0.77 microg g(-1), indicating a homogeneously low level of pollution. A rather exceptional prevalence of low molecular weight PAHs was substantiated: nearly 80% of SigmaPAHs include naphthalene (15.19%) and phenanthrene (64.47%). Carcinogenic compounds were present in very low (BaP, BkF, BaA and DBA) or negligible (BbF and Inp) concentrations. As indicated by the Phen/Ant molar ratio, the main source of PAHs is petrogenic, probably due to oil spills from shipping. The low/high molecular weight ratio (ranging between 1.2 and 26) distinguishes the sediments of the tourist harbor from those of the commercial/industrial harbor. Moreover, a slight but meaningful pyrolytic contribution to pollution was found in the tourist harbor, which has the most polluted sediments in the whole harbor. Finally, good linear correlations were found between a selected PAH (Phen and Naph) and selected sums of PAHs (i.e. the total amount of the other 15 US EPA and the sum of low molecular weight PAHs).  相似文献   
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RETRACTED ARTICLE: Numerical analysis of multiphase flow in porous material   总被引:7,自引:7,他引:0  
Recent developments in the application of x-ray micro-tomography in laboratory geomechanics have allowed all the individual grains of sand in a test sample to be seen and identified uniquely in 3D. Combining such imaging capabilities with experiments carried out “in situ” within an imaging set-up has led to the possibility of directly observing the mechanisms of deformation as they happen. The challenge has thus become extracting pertinent, quantified information from these rich time-lapse 3D images to elucidate the mechanics at play. This paper presents a new approach (ID-Track) for the quantification of individual grain kinematics (displacements and rotations) of large quantities of sand grains (tens of thousands) in a test sample undergoing loading. With ID-Track, grains are tracked between images based on some geometrical feature(s) that allow their unique identification and matching between images. This differs from Digital Image Correlation (DIC), which makes measurements by recognising patterns between images. Since ID-Track does not use the image of a grain for tracking, it is significantly faster than DIC. The technique is detailed in the paper, and is shown to be fast and simple, giving good measurements of displacements, but suffering in the measurement of rotations when compared with Discrete DIC. Subsequently, results are presented from successful applications of ID-track to triaxial tests on two quite different sands: the angular Hostun sand and the rounded Caicos Ooids. This reveals details on the performance of the technique for different grain shapes and insight into the differences in the grain-scale mechanisms occurring in these two sands as they exhibit strain localisation under triaxial loading.  相似文献   
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MOON (Mediterranean Operational Oceanography Network http://www.moon-oceanforecasting.eu) provides near-real-time information on oil-spill detection (ocean color and SAR) and predictions [ocean forecasts (MFS and CYCOFOS) and oil-spill predictions (MEDSLIK)]. We employ this system to study the Lebanese oil-pollution crisis in summer 2006 and thus to assist regional and local decision makers in Europe, regionally and locally. The MEDSLIK oil-spill predictions obtained using CYCOFOS high-resolution ocean fields are compared with those obtained using lower-resolution MFS hydrodynamics, and both are validated against satellite observations. The predicted beached oil distributions along the Lebanese and Syrian coasts are compared with in situ observations.The oil-spill predictions are able to simulate the northward movement of the oil spill, with the CYCOFOS predictions being in better agreement with satellite observations. Among the free MEDSLIK parameters tested in the sensitivity experiments, the drift factor appears to be the most relevant to improve the quality of the results.  相似文献   
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We present bulk solar wind isotopic and elemental ratios for Ar, Kr, and Xe averaged from up to 14 individual analyses on silicon targets exposed to the solar wind for ∼2.3 years during NASA’s Genesis mission. All averages are given with 1σ standard errors of the means and include the uncertainties of our absolute calibrations. The isotopic ratios 86Kr/84Kr and 129Xe/132Xe are 0.303 ± 0.001 and 1.06 ± 0.01, respectively. The elemental ratios 36Ar/84Kr and 84Kr/132Xe are 2390 ± 120 and 9.9 ± 0.3, respectively. Average fluxes of 84Kr and 132Xe in the bulk solar wind in atoms/(cm2 s) are 0.166 ± 0.009 and 0.017 ± 0.001, respectively. The flux uncertainties also include a 2% uncertainty for the determination of the extracted areas. The bulk solar wind 36Ar/38Ar ratio of 5.50 ± 0.01 and the 36Ar flux of 397 ± 11 atoms/(cm2 s) determined from silicon targets agree well with the 36Ar/38Ar ratio and the 36Ar flux determined earlier on a different type of target by Heber et al. (2009). A comparison of the solar wind noble gas/oxygen abundance ratios with those in the solar photosphere revealed a slight enrichment of Xe and, within uncertainties a roughly uniform depletion of Kr-He in the solar wind, possibly related to the first ionization potentials of the studied elements. Thus, the solar wind elemental abundances He-Kr display within uncertainties roughly photospheric compositions relative to each other. A comparison of the Genesis data with solar wind heavy noble gas data deduced from lunar regolith samples irradiated with solar wind at different times in the past reveals uniform 36Ar/84Kr ratios over the last 1-2 Ga but an increase of the 84Kr/132Xe ratio of about a factor of 2 during the same time span. The reason for this change in the solar wind composition remains unknown.  相似文献   
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Cosmic ray exposure ages of Rumuruti chondrites from North Africa   总被引:1,自引:0,他引:1  
We analyzed noble gases and determined 3He, 21Ne, and 38Ar cosmic ray exposure ages (CREAs) of Rumuruti chondrites from North West Africa (NWA) to rule on potential pairings and/or source pairings of North Africa R chondrite samples. The 21Ne exposure ages range between 10 and 74 Ma, with NWA 2897 and 1668 having the highest known exposure ages among R chondrites. We also include other R chondrites from North Africa (Schultz et al., 2005) and, based on their noble gas characteristics and their 21Ne CREAs, propose pairings of the following samples: NWA 2198, 5069, 755, 4615, 845, 851, 978, 1471, and possibly DaG 013 belonging to one fall with a CREA of ∼10 Ma, and NWA 753, 4360, 4419, 5606, 1472, 1476, 1477, 1478, and 1566 representing one fall with a CREA of ∼14 Ma. NWA 2821, 2503, 2289, 3364, 3146, 4619, 4392, 3098, and 2446 seem to belong to one single fall with a CREA of ∼20 Ma, and NWA 2897 and 1668 seem to be paired and show a common CREA of ∼66 Ma. Overall, all R chondrite samples from North Africa analyzed for noble gases so far represent ∼16 individual falls. Comparing falls from North Africa to literature CREAs of R chondrites worldwide, it seems possible that a significant number of all R chondrite falls studied for noble gases were ejected from the R chondrite parent body during one large collisional event between 15 and 25 Ma ago. However, the database is still too small to draw definitive conclusions. The large portion of brecciated R chondrites in collections suggests severe impact brecciation of the R chondrite parent body.  相似文献   
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Mangrove forests and saltmarshes are important habitats for carbon (C) sequestration in the coastal zone but variation in rates of C sequestration and the factors controlling sequestration are poorly understood. We assessed C sequestration in Moreton Bay, South East Queensland in mangrove forests and tidal marshes that span a range of environmental settings and plant communities, including mangrove forests and tidal marshes on the oligotrophic sand islands of the eastern side of Moreton Bay and on the nutrient enriched, western side of the bay adjacent to the city of Brisbane. We found that rates of C sequestration in sediments were similar among mangrove forests over the bay, despite large differences in the C density of sediments, because of different rates of vertical accretion of sediments. The C sequestration on the oligotrophic sand island tidal marshes, dominated by Juncus kraussii, had the highest rate of C sequestration in the bay while the western saltmarshes, which were dominated by Sarcocornia quinqueflora, had the lowest rate of C sequestration. Our data indicate C sequestration varies among different tidal wetland plant community types, due to variation in sediment characteristics and rates of sediment accretion over time.  相似文献   
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The development of the new seismic hazard map of metropolitan Tehran is based on probabilistic seismic hazard computation using the non-Poisson recurrence time model. For this model, two maps have been prepared to indicate the earthquake hazard of the region in the form of iso-acceleration contour lines. They display the non-Poisson probabilistic estimates of peak ground accelerations over bedrock for 10 and 63 % probability of exceedance in 50 years. To carry out the non-Poisson seismic hazard analysis, appropriate distributions of interoccurrence times of earthquakes were used for the seismotectonic provinces which the study region is located and then the renewal process was applied. In order to calculate the seismic hazard for different return periods in the probabilistic procedure, the study area encompassed by the 49.5–54.5°E longitudes and 34–37°N latitudes was divided into 0.1° intervals generating 1,350 grid points. PGA values for this region are estimated to be 0.30–0.32 and 0.16–0.17 g for 10 and 63 % probability of exceedance, respectively, in 50 years for bedrock condition.  相似文献   
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