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51.
This article examines the conditions under which the pressure-work and viscous dissipation terms should be retained in the energy balance relation for single (liquid water or vapor) and two-phase (liquid water and vapor) fluid flow through porous media. It is shown that if one wishes to retain the pressure-work term, then one must also keep the viscous dissipation term in the energy balance. Consideration of steady non-isothermal radial flow demonstrates that both pressure-work and viscous dissipation are liable to have negligibly small effects in single phase liquid water and in two-phase liquid-vapor systems. This conclusion is, however, not generally valid for pure vapor systems; in this case, pressure-work and viscous dissipation can produce significant variations in the computed reservoir response.  相似文献   
52.
Mercury in sediments of Ulhas estuary   总被引:5,自引:0,他引:5  
Hg levels in water, suspended particulate matter and sediment of the Ulhas estuary are under considerable environmental stress due to the indiscriminate release of effluents from a variety of industries including chlor-alkali plants. Concentration ranges of dissolved (0.04-0.61 micro gl(-1)) and particulate (1.13-6.43 micro gg(-1)) Hg reveal a definite enhancement of levels in the estuary. The Hg burden in sediment upstream of the weir that limits the tidal influence is low (0.08-0.19 micro gg(-1)) with low C(org) content (1.8-2.9%). The high Hg content of the sediment just below the weir varies seasonally (highest concentration recorded being 38.45 micro gg(-1)) due to incremental accretion of sediment as the fresh water flow over the weir progressively decreases. The 30 km segment of the estuary sustains markedly high levels of Hg in the sediment with an exponential decrease in the seaward direction from the weir. Higher concentrations than the expected background prevail in all the estuarine cores up to the bottom, though the overall concentration decreases from about 20 micro gg(-1) in core 7 (inner estuary) to 1 micro gg(-1) in core 31 (outer estuary). The Hg in sediment is associated with C(org), while its correlation with Al, Fe and Mn is poor. The Hg profiles in cores from the Arabian Sea (stations 34, 35 and 37) have a distinct horizon of enhanced concentration in the 5-60 cm segment. Based on 210Pb dating of core 37, the sediment at the bottom of this core is inferred to have been deposited in the year 1949, roughly two year prior to the establishment of the first chlor-alkali plant and represents the background (0.06-0.10 micro gg(-1)). The Hg profiles in the offshore cores indicate a marked increase in transfer of Hg to sediment subsequent to 1980, with a peak around 1990-1992. Based on the index of geoaccumulation it is considered that the estuarine segment between stations 4 and 23 is extremely polluted, while the sediment from the open coast is moderately polluted in the top 25-30 cm with respect to Hg. The enrichment factor of Hg in the sediment is 350-700 for core 4 and decreases to 0-7 for the open-shore cores.  相似文献   
53.
Motivated by the increasingly availability and importance of hyperspectral remote sensing data, this study aims to determine whether current generation narrowband hyperspectral remote sensing data could be used to estimate vegetation Leaf Area Index (LAI) accurately than the traditional broadband multispectral data. A comparative study has been carried out to evaluate the performance of the narrowband Normalized Difference Vegetation Index (NDV1) derived from Hyperion hyperspectral sensor with that of derived from IRS LISS-III for the estimation of LAI of some major agricultural crops (e.g. cotton, sugarcane and rice) in part of Guntur district, India. It has been found that the narrowband NDVI derived from Hyperion has shown better results over its counterpart derived from broadband LISS-III. Linear regression models have been used which with selected subsets of individual Hyperion bands performed better to predict LAI than those based on the broadband datasets, although the potential to overfit models using the large number of available Hyperion bands is a concern for further research.  相似文献   
54.
The mechanism and kinetics of superoxide-mediated reduction of a variety of organic iron(III) complexes has been investigated over the pH range 7-9. Our experimental results show that the rate of iron(II) formation is a function of pH, ligand type and ligand concentration with the measured rate varying between 0.44 ± 0.07 and 39.25 ± 1.77 pM s−1 in the systems investigated. Additionally, our results show that the presence of competing cations such as Ca2+ have a significant impact on iron(II) formation if the organic ligand is strongly complexed by Ca2+. Formation of iron(II) occurs by either (or, in some instances, both) reaction of superoxide with inorganic iron(III) after its dissociation from the complex (dissociative reduction) or by direct reaction of superoxide with the complex (non-dissociative reduction). In the presence of weak ligands, dissociative reduction (DR) dominates; however non-dissociative reduction (NDR) becomes important in the presence of either strongly binding ligands or high concentrations of weakly binding ligands. The major factors contributing to the pH dependence of the iron(II) formation rate are the complexation kinetics of inorganic iron(III) (which controls the DR contribution) and the reduction kinetics of the iron(III) complex (which controls the NDR contribution). The relative NDR contribution increases with increasing superoxide and ligand concentration and decreasing pH for all ligands examined. Since iron(II) formation occurring via NDR results in a significantly larger increase in the proportion of iron in free aquated form than does DR, this non-dissociative pathway of superoxide-mediated iron(III) reduction is particularly effective in increasing the lability of iron in aquatic systems.  相似文献   
55.
Snow cover is an important variable for climatic and hydrologic models due to its effects on surface albedo, energy, and moisture budgets. Passive microwave sensors can be used to monitor temporal and spatial variations in large-scale snow cover parameters, avoiding problems of cloud cover and polar nights. In the present study, brightness temperature values were estimated (using calibration curves) for moist snow on natural and blackbody/metal surface. TB response on snow depth, density, SWE and angular variation from nadir were measured and found that TB decreases with increase of snow depth and with increase of angle from nadir. Empirical relations were used to estimate emissivity, dielectric constant and dielectric loss factor. It was observed that emissivity decreases with the increase of dielectric constant. The dielectric constant and dielectric loss factor both increases with the increase of density. Experiments were performed during winter of year 2005 at Dhundi and Solang (H.P.), India, using ground based passive microwave radiometer having 6.9 and 18.7 GHz antenna frequencies at dual polarization.  相似文献   
56.
57.
Many geothermal anomalies are intersected by vertical fault zones (narrow zones of fractured material with large effective permeability). These conduits are probably responsible for much of the upwelling of hot water from depth. This paper considers a shallow aquifer intersected by a vertical fault. The fluid flow in the aquifer is numerically modeled as a two-dimensional problem. It is observed that the temperature distribution in the aquifer is governed primarily by lateral flow of hot water supplied from the intersecting vertical fault and only secondarily by conduction. The numerical results also provide a possible explanation for the local temperature maxima and inversions occasionally observed in borehole measurements. The present model is an alternative to that based on mushroom-shaped isotherm distributions found in high Rayleigh number large-scale circulation cell calculations.  相似文献   
58.
Large-scale structures, textures and mineral assemblages in the Precambrian rocks of the Banded Gneissic Complex and the overlying Delhi Group in north-central Aravalli Mountain reveal a complex deformational-crystallization history. In the basement Gneissic Complex at least three deformational events, D0, D1 and D2, and two separate episodes of metamorphism, M1 and M2, are recognized. The supracrustal Delhi Rocks display only two phases of deformation, D1 and D2, associated with a single protracted period of metamorphism, M2.The first phase of deformation (D1) of the Delhi orogeny (1650-900 m.y.) produced large isoclinal folds that are overturned towards the southeast and have gentle plunges in NE and SW directions. The second phase of deformation (D2) gave rise to tight open folds on the limbs and axial-plane surfaces of the D1 folds. These folds generally plunge towards the N and NNW at 30°–80°. In the Basement Complex one more deformation (D0) of the Pre-Delhi orogeny (> 2000 m.y.) is recorded by the presence of reclined and recumbent folds with W to WNW trending fold axes. The D0 folds were superimposed by D1 and D2 folds during the Delhi orogeny.The three deformational events have been correlated with the crystallization periods of minerals in the rocks and a setting in time is established for this part of the Aravalli range.  相似文献   
59.
A three-step hierarchical Semi Automated Empirical Methane Emission Model (SEMEM) has been used to estimate methane emission from wetlands and waterlogged areas in India using Moderate Resolution Imagine Spectroradiometer (MODIS) sensor data onboard Terra satellite. Wetland Surface Temperature (WST), methane emission fluxes and wetland extent have been incorporated as parameters in order to model the methane emission. Analysis of monthly MODIS data covering the whole of India from November 2004 to April 2006 was carried out and monthly methane emissions have been estimated. Interpolation techniques were adopted to fill the data gaps due to cloudy conditions during the monsoon period. AutoRegressive Integrated Moving Average (ARIMA) model has been fitted to estimate the emitted methane for the months of May 2006 to August 2006 using SPSS software.  相似文献   
60.
Radar altimetry provides an important geophysical parameter, backscatter coefficient (σ0), which is useful in studying target surface characteristics. Ku-band (Oceansat-2 scatterometer- OSCAT) and Ka-band (SARAL-AltiKa altimeter) data are concurrently used to characterize polar surface features over the Antarctic region. Maximum-likelihood classification has been employed to classify combined data set (AltiKa and OSCAT) for discrimination among sea ice, open water, and ice sheet (interior and exterior). The sea ice region obtained using the current approach has been compared with sea ice boundary derived from passive microwave data.  相似文献   
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