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91.
This study examines a sediment core (SR-63) from a mangrove ecosystem along the Sibun River in Belize, which is subject to both changes in sea-level and in the characteristics of the river's drainage basin. Radiocarbon dates from the core show a decreased sedimentation rate from ~ 6 ka to 1 cal ka BP and a marked change in lithology from primarily mangrove peat to fluvial-derived material at ~ 2.5 cal ka BP. Changes in the sedimentation rates observed in mangrove ecosystems offshore have previously been attributed to changes in relative sea-level and the rate of sea-level rise. Pollen analyses show a decreased abundance of Rhizophora (red mangrove) pollen and an increased abundance of Avicennia (black mangrove) pollen and non-mangrove pollen coeval with the decreased sedimentation rates. Elemental ratios ([N:C]a) and stable isotope analyses (δ15N and δ13C) show that changes in the composition of the organic material are also coeval with the change in lithology. The decrease in sedimentation rate at the site of core SR-63 and at offshore sites supports the idea that regional changes in hydrology occurred during the Holocene in Belize, influencing both mainland and offshore mangrove ecosystems.  相似文献   
92.
The health benefits of regular consumption of fish and seafood have been espoused for many years. However, fish are also a potential source of environmental contaminants that have well known adverse effects on human health. We investigated the consumption risks for largemouth bass (Micropterus salmoides; n = 104) and striped mullet (Mugil cephalus; n = 170), two commonly harvested and consumed fish species inhabiting fresh and estuarine waters in northwest Florida. Skinless fillets were analyzed for total mercury, inorganic arsenic, polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/F), polychlorinated biphenyls (PCBs), and organochlorine pesticides. Contaminant levels were compared to screening values (SV) calculated using U.S. Environmental Protection Agency (EPA) recommendations for establishing consumption advisories. Largemouth bass were found to contain high levels of total mercury at all sampling locations (0.37–0.89 ug/g) and one location exhibited elevated total PCBs (39.4 ng/g). All of the samples exceeded Florida fish consumption advisory trigger levels for total mercury and one location exceeded the U.S. EPA SV for total PCBs. As a result of the high mercury levels, the non-cancer health risks (hazard index–HI) for bass were above 1 for all locations. Striped mullet from several locations with known point sources contained elevated levels of PCBs (overall range 3.4–59.3 ng/g). However, total mercury levels in mullet were low. Eight of the 16 mullet sampling locations exceeded the U.S. EPA SV for total PCBs and two locations exceeded an HI of 1 due to elevated PCBs. Despite the elevated levels of total PCBs in some samples, only two locations exceeded the acceptable cancer risk range and therefore cancer health risks from consumption of bass and mullet were determined to be low at most sampling locations.  相似文献   
93.
Sharks play a critical role in the ocean environment yet many species are under threat. Over the last ten years, the international community has taken significant steps to protect shark species and address the threats to them through the adoption and implementation of international laws, plans and programmes. Nevertheless, despite the attention given to this issue, many shark species continue to deteriorate in numbers. While the reasons for this decline are complex and varied, regulatory fragmentation is one contributing factor. Legal regulation is a critical element in achieving effective conservation and management of sharks. This article considers the international laws, plans and programmes that seek to conserve shark species, explores the current fragmented regime and outlines possible strategies to overcome this challenge and enhance shark protection in the future.  相似文献   
94.
Abstract– We present initial results from hydrocode modeling of impacts on Al‐1100 foils, undertaken to aid the interstellar preliminary examination (ISPE) phase for the NASA Stardust mission interstellar dust collector tray. We used Ansys’ AUTODYN to model impacts of micrometer‐scale, and smaller projectiles onto Stardust foil (100 μm thick Al‐1100) at velocities up to 300 km s?1. It is thought that impacts onto the interstellar dust collector foils may have been made by a combination of interstellar dust particles (ISP), interplanetary dust particles (IDP) on comet, and asteroid derived orbits, β micrometeoroids, nanometer dust in the solar wind, and spacecraft derived secondary ejecta. The characteristic velocity of the potential impactors thus ranges from <<1 to a few km s?1 (secondary ejecta), approximately 4–25 km s?1 for ISP and IDP, up to hundreds of km s?1 for the nanoscale dust reported by Meyer‐Vernet et al. (2009) . There are currently no extensive experimental calibrations for the higher velocity conditions, and the main focus of this work was therefore to use hydrocode models to investigate the morphometry of impact craters, as a means to determine an approximate impactor speed, and thus origin. The model was validated against existing experimental data for impact speeds up to approximately 30 km s?1 for particles ranging in density from 2.4 kg m?3 (glass) to 7.8 kg m?3 (iron). Interpolation equations are given to predict the crater depth and diameter for a solid impactor with any diameter between 100 nm and 4 μm and density between 2.4 and 7.8 kg m?3.  相似文献   
95.
Middleton Run, a severely acid mine drainage (AMD) impacted tributary of Little Raccoon Creek, drains a sub-watershed area of 3.67 km2 (2.28 square miles). Averaging 58.7 kg/day (129.4 lbs/day) at its mouth, demonstrated aluminum loads from Middleton Run are particularly severe. A preliminary study of two previously unmonitored tributaries was conducted to justify future treatment projects. Monthly chemical water quality data were collected for 6 months. Soil leachate samples collected on five strip mining sites within the sub-watershed were analyzed for acidity, alkalinity, pH, aluminum and iron. Soil leachate tests have shown that one of the pits has a much larger pollution production potential and should be targeted for remediation.  相似文献   
96.
The stability of the high-pressure CaCO3 calcite (cc)-related polymorphs was studied in experiments that were performed in conventional diamond anvil cells (DAC) at room temperature as a function of pressure up to 30 GPa as well as in internally heated diamond anvil cells (DAC-HT) at pressures and temperatures up to 20 GPa and 800 K. To probe structural changes, we used Raman and FTIR spectroscopy. For the latter, we applied conventional and synchrotron mid-infrared as well as synchrotron far-infrared radiation. Within the cc-III stability field (2.2–15 GPa at room temperature, e.g., Catalli and Williams in Phys Chem Miner 32(5–6):412–417, 2005), we observed in the Raman spectra consistently three different spectral patterns: Two patterns at pressures below and above 3.3 GPa were already described in Pippinger et al. (Phys Chem Miner 42(1):29–43, 2015) and assigned to the phase transition of cc-IIIb to cc-III at 3.3 GPa. In addition, we observed a clear change between 5 and 6 GPa that is independent of the starting material and the pressure path and time path of the experiments. This apparent change in the spectral pattern is only visible in the low-frequency range of the Raman spectra—not in the infrared spectra. Complementary electronic structure calculations confirm the existence of three distinct stability regions of cc-III-type phases at pressures up to about 15 GPa. By combining experimental and simulation data, we interpret the transition at 5–6 GPa as a re-appearance of the cc-IIIb phase. In all types of experiments, we confirmed the transition from cc-IIIb to cc-VI at about 15 GPa at room temperature. We found that temperature stabilizes cc-VI to lower pressure. The reaction cc-IIIb to cc-VI has a negative slope of ?7.0 × 10?3 GPa K?1. Finally, we discuss the possibility of the dense cc-VI phase being more stable than aragonite at certain pressure and temperature conditions relevant to the Earth’s mantle.  相似文献   
97.
Climate change is leading to a redistribution of marine species, altering ecosystem dynamics as species extend or shift their geographic ranges polewards with warming waters. In marine systems, range shifts have been observed in a wide diversity of species and ecosystems and are predicted to become more prevalent as environmental conditions continue to change. Large-scale shifts in the ranges of marine species will likely have dramatic socio-economic and management implications. Australia provides a unique setting in which to examine the range of consequences of climate-induced range shifts because it encompasses a diverse range of ecosystems, spanning tropical to temperate systems, within a single nation and is home to global sea surface temperature change ‘hotspots’ (where range shifts are particularly likely to occur). We draw on global examples with a particular emphasis on Australian cases to evaluate these consequences. We show that in Australia, range shifts span a variety of ecosystem types, trophic levels, and perceived outcomes (i.e., negative versus positive). The effect(s) of range shifts on socio-economic change variables are rarely reviewed, yet have the potential to have positive and/or negative effects on economic activities, human health and ecosystem services. Even less information exists about potential management responses to range-shifting species. However, synthesis of these diverse examples provides some initial guidance for selecting effective adaptive response strategies and management tools in the face of continuing climate-mediated range shifts.  相似文献   
98.
Geochemical studies of the ecosystems of 184 Siberian lakes in three largest zones of northern Asia (humid, arid, and semiarid) and in mountainous area were carried out. The contents of natural radionuclides, radiocesium, and rare-earth elements in conjugate components of the systems and the types of the main sources of the bottom sediment material have been determined.Dating of the bottom sediments was made by the activity of radioisotopes 137Cs and 210Pb, which permitted estimation of the sedimentation rates in lakes in different regions of Siberia: 0.35 cm/year in the south and 0.25–0.3 cm/year in the north.Six main ions have been determined in the waters of the studied lakes: Ca2+, Mg2+, Na+, HCO3?, SO42?, and Cl?. The distribution of natural radionuclides in the stratified sections of bottom sediments of Siberian lakes evidences the stable sedimentation and characterizes their contents in the soils of water-catchment areas, which can be considered background contents there. Sediments enriched in organic matter have higher concentrations of U and lower ones of Th and K. The Th/K ratio in the studied bottom sediments is the same as in the soils. The Th/U ratios are somewhat lower than those in the soils because U is accumulated by chemogenic and organic components. The overall 137Cs pollution of bottom sediments of Siberian lakes is close to the global background (40 mCi /km2 in 2000), but in the Altai Territory and Buryatia and Altai Republics it is twice higher. The uneven areal and temporal distribution of residual radiocesium is observed not only in the lacustrine sediments but also in the lake water areas. The REE patterns of bottom sediments of different mineral types are similar to those of continental crust and clays of the Russian Platform, though organogenic and carbonate sediments have higher absolute REE contents than terrigenous ones. Pelitic fraction is the main REE concentrator in the bottom sediments.  相似文献   
99.
A numerical surface-water/groundwater model was developed for the lower San Antonio River Basin to evaluate the responses of low base flows and groundwater levels within the basin under conditions of reduced recharge and increased groundwater withdrawals. Batch data assimilation through history matching used a simulation of historical conditions (2006-2013); this process included history-matching to groundwater levels and base-flow estimates at several gages, and was completed in a high-dimensional (highly parameterized) framework. The model was developed in an uncertainty framework such that parameters, observations, and scenarios of interest are envisioned stochastically as distributions of potential values. Results indicate that groundwater contributions to surface water during periods of low flow may be reduced from 6% to 25% with a corresponding 25% reduction in recharge and a 25% increase in groundwater pumping over an 8-year planning period. Furthermore, results indicate groundwater-level reductions in some hydrostratigraphic units are more likely than in other hydrostratigraphic units over an 8-year period under drought conditions with the higher groundwater withdrawal scenario.  相似文献   
100.
Many geomorphologists who are mothers find it challenging to balance field research alongside pregnancy and caring for young children. We offer perspectives on the challenges to conducting fieldwork as mothers and possible solutions, as a means of promoting conversations and highlighting issues that are less commonly considered in field-based geomorphic research. Although every mother's experience and needs are different, we discuss strategies for conducting fieldwork, addressing childcare issues, and dealing with financial considerations. We call for our community to support geomorphologists who are pregnant or caring for young children in carrying out fieldwork to help enhance the diversity of voices and perspectives within our discipline.  相似文献   
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