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41.
A 2.5-m-thick sequence of lake sediments at the Étang de Grand-Case, Saint Martin (French West Indies) is studied here. Significant hydrological budget fluctuations allows distinction of three main climatic periods: (1) an overall dry period (4200 BP–2300 BP), characterised by carbonated mud, gypsum and storm sand layers; (2) a wet phase (2300 BP–1150 BP) dominated by organic mud; and (3) a more complex phase (1150 BP to present), with detrital inputs due to human activities. Comparison with other regional high-resolution records shows that similar climate modifications typify the whole Mesoamerican and Caribbean area. The climatic phenomena that are implicated in the variations of both precipitation and hurricane frequency over the Lesser Antilles are due to the latitudinal displacement of the inter-tropical convergence zone. These data give new support to the hypothesis of the existence of a correlation between peopling phases and climate variations in the Caribbean as previously proposed by some archaeologists. To cite this article: P. Bertran et al., C. R. Geoscience 336 (2004).  相似文献   
42.
A large collection of fluids (54 interstitial fluids and four expelled fluids) were sampled at the Manon site, at the outer edge of the Barbados accretionary complex. These warm fluids (up to 20°C) are expelled by sub-marine (5000 mbsl) mud volcanoes consisting of diapirs (unchanneled flow) and diatremes (channeled).Chlorine stable isotope ratios of these fluids were measured by IRMS with a reproducibility of ± 0.05‰ (1σ) versus SMOC (Standard Mean Ocean Chloride).A large range of δ37Cl between −5.3‰ and +0.1‰ is observed. Data from each volcanic structure describe a mixing between seawater and a low-δ37Cl fluid. The whole set of data is interpreted as the result of a mixing between two deep components and seawater. The two deep fluids are chemically distinct (e.g., in Ca, Mg, K, Li, Sr and Br contents and Br/Cl ratio). They display low and significantly different 87Sr/86Sr ratios (0.707790 and 0.707892, respectively) and δ37Cl values (−4.51 and −5.24‰, respectively).Physicochemical processes such as mineralogical transformation, diffusion, compaction or ion filtration are known to fractionate chlorine stable isotopes and can produce fluids with negative δ37Cl values. Ion filtration due to sediment compaction appears to be the more likely process to explain the negative δ37Cl values observed at the Manon site. A model for the generation of these signatures is proposed where a residual negative δ37Cl fluid reservoir is created at the bottom of the prism or the sediment pile. Further compaction/fracturing and/or dewatering of the slab may flush out these fluids and focus them towards the décollement zone. Mixing between the fluids and ultimately with seawater and water released during gas hydrate destabilizations may explain the data set within the individual cores and between the different structures.  相似文献   
43.
Classical multivariate analyses are based on matrix algebra and enable the analysis of a table containing measurements of a set of variables for a set of sites. Incomplete mapped data consist of measurements of a set of variables recorded for the same geographical region but for different zonal systems and with only a partial sampling of this zone. This kind of data cannot be analysed with usual multivariate methods because there is no common system of sites for all variables. We propose a new approach using GIS technology and NIPALS, an iterative multivariate method, to analyse the spatial patterns of this kind of data. Moreover, an extension of our method is that it can be used for areal interpolation purposes. We illustrate the method in analysing data concerning the distribution of roe deer weights over several years in a reserve.  相似文献   
44.
This paper is concerned with the problem of interpretation of anomalous seismic amplitudes, induced by the amplitude‐scattering phenomenon. This phenomenon occurs in the vicinity of a crack distribution at the interface between elastic layers. The purpose of this work is to obtain a better understanding of the physics of this distinctive phenomenon, in order to interpret correctly the amplitudes of the reflected events. By analogy with studies in optics and in acoustics, we suggest that diffraction is widely involved in the amplitude‐scattering phenomenon. Analytical evaluation of the amount of energy carried by the reflected and the diffracted waves shows that neglecting diffraction in numerical models leads to local underestimation of the amplitude of waves reflected at interfaces with gas‐filled crack distribution.  相似文献   
45.
Sedimentologic study of carbonated sediments of the Rmah-I member (Coniacian–Santonian) of Jabal Abtar, central southern Palmyrides (Central Syria), uncovers phosphatic levels, associated with marine vertebrate remains, that give evidence of an early episode of the Senonian phosphatogenesis in the Palmyrides. Sedimentary sequence analysis reveals a gradual marine transgression during the Senonian. Phosphatic sedimentation occurred in a shallow neritic marine environment almost connected with the open sea. Condensed sedimentation could have contributed to the phosphatogenesis. To cite this article: A.K. Al Maleh, N. Bardet, C. R. Geoscience 335 (2003).  相似文献   
46.
The Gulf of Cadiz lies astride the complex plate boundary between Africa and Eurasia west of the Betic-Rif mountain belt. We report on the results of recent bathymetric swathmapping and multi-channel seismic surveys carried out here. The seafloor is marked by contrasting morphological provinces, spanning the SW Iberian and NW Moroccan continental margins, abyssal plains and an elongate, arcuate, accretionary wedge. A wide variety of tectonic and gravitational processes appear to have shaped these structures. Active compressional deformation of the wedge is suggested by folding and thrusting of the frontal sedimentary layers as well as basal duplexing in deeper internal units. There is evidence for simultaneous gravitational spreading occurring upslope. The very shallow mean surface and basal slopes of the accretionary wedge (1° each) indicate a very weak decollement layer, geometrically similar to the Mediterranean Ridge accretionary complex. Locally steep slopes (up to 10°) indicate strongly focused, active deformation and potential gravitational instabilities. The unusual surface morphology of the upper accretionary wedge includes “raft-tectonics” type fissures and abundant sub-circular depressions. Dissolution and/or diapiric processes are proposed to be involved in the formation of these depressions.  相似文献   
47.
Holocene cooling events have been reconstructed for the southern Adriatic Sea (central Mediterranean) by means of analyses of organic walled dinoflagellate cysts, planktonic foraminifera, oxygen isotopes, calcareous nanoplankton, alkenones and pollen from a sediment core. Two cooling events have been detected, during which sea‐surface temperatures (SSTs) were ca. 2°C lower. Unravelling the SST signal into dominant seasonal components suggests maximum winter cooling of 2°C at around 6.0 ka, whereas the cooling at ca. 3.0 ka might be the result of a spring temperature cooling of 2–3°C. The events, lasting several hundred years, are apparently synchronous with those in the Aegean Sea, where they have been related to known cooling events from the Greenland ice‐core record. A distinct interruption in Adriatic Sea sapropel S1 is not clearly accompanied by a local drop in winter temperatures, but seems to be forced by ventilation, which probably occurred earlier in the Aegean Sea and was subsequently transmitted to the Adriatic Sea. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
48.
The CRPG (Nancy, France) has prepared secondary reference materials for Li isotope measurements by mixing 7Li or 6Li spikes and either L-SVEC or IRMM-016 certified reference materials to produce solutions having a known Li concentration and isotopic composition. The Li7-N and Li6-N solution samples (1.5 mol l−1 HNO3) have nominal δ7Li isotopic compositions of 30.1‰ and -9.7‰ respectively relative to L-SVEC and concentrations of 100 mg l−1. Repeated measurement of these samples using the QUAD-ICP-MS at the CRPG yielded δ7Li of 30.4 ± 1.1‰ (n = 13) and -8.9 ± 0.9‰ (n = 9) at the 2s level of confidence. An additional LiCl-N solution was measured and yielded a delta value of 9.5 ± 0.6‰ (n = 3). Identical results were obtained at the BRGM (Orléans, France) from determinations performed with a Neptune MC-ICP-MS (30.2 ± 0.3‰, n = 89 for the Li7-N, -8.0 ± 0.3‰, n = 38 for the Li6-N and 10.1 ± 0.2‰, n = 46 for LiCl-N at the 2s level of confidence). The deviation of measured composition relative to the nominal value for the Li6-N solution might be explained by either contamination during preparation or an error during sample weighing. These secondary reference materials, previously passed through ion exchange resin or directly analysed, may be used for checking the accuracy of Li isotopic measurements over a range of almost 40‰ and will be available to the scientific community upon request to J. Carignan or N. Vigier, CRPG.  相似文献   
49.
50.
The Beer–Lambert law is traditionally used to determine water and carbon concentrations in glasses from their infrared (IR) spectra. In practice, this method requires estimation of the thickness and density of the glass as well as the calibration of the molecular absorptivities of the species concerned. All of these parameters can be sources of practical difficulties and analytical uncertainty. These weaknesses in the application of the Beer–Lambert law have been overcome by an empirical analysis of the infrared spectra. Using a set of 292 spectra obtained on 113 natural and experimental tholeiitic glasses (SiO2 48.5–51 wt%; water contents 0–4000 ppm H2O), it can be shown that the thickness–density (ρ d) product of a glass sample can be directly and reliably inferred from its IR spectrum. This allows the Beer–Lambert law to be rewritten. The new form no longer requires thickness or density estimations to determine volatile contents. Moreover, if needed, the thickness of the glass slab can also be accurately determined from the IR spectra. This new method is developed for quantitative determination of water concentrations in MORB glasses but can also be applied to any minor species (carbon, sulfur, etc.) provided it is active in the IR domain and that a suitable independent frequency of IR absorption can be identified. Precision is about 60 ppm H2O on O–H contents. This method, tested on natural and experimental MORB-type glasses, can be applied to any chemical composition provided a set of reference spectra is available. Received: 16 September 1999 / Accepted: 18 February 2000  相似文献   
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