Turbulent Transfer Between Street Canyons and the Overlying Atmospheric Boundary Layer   总被引：1，自引：1，他引：0  

Pietro Salizzoni  Massimo Marro  Lionel Soulhac  Nathalie Grosjean  Richard J. Perkins 《Boundary-Layer Meteorology》2011,141(3):393-414

The turbulent exchange of momentum between a two-dimensional cavity and the overlying boundary layer has been studied experimentally, using hot-wire anemometry and particle image velocimetry (PIV). Conditions within the boundary layer were varied by changing the width of the canyons upstream of the test canyon, whilst maintaining the square geometry of the test canyon. The results show that turbulent transfer is due to the coupling between the instabilities generated in the shear layer above the canyons and the turbulent structures in the oncoming boundary layer. As a result, there is no single, unique velocity scale that correctly characterizes all the processes involved in the turbulent exchange of momentum across the boundary layer. Similarly, there is no single velocity scale that can characterize the different properties of the turbulent flow within the canyon, which depends strongly on the way in which turbulence from the outer flow is entrained into the cavity and carried round by the mean flow. The results from this study will be useful in developing simple parametrizations for momentum exchange in the urban canopy, in situations where the street geometry consists principally of relatively long, uniform streets arranged in grid-like patterns; they are unlikely to be applicable to sparse geometries composed of isolated three-dimensional obstacles.  相似文献   

Anisotropic Closure in Squeezing Rocks: The Example of Saint-Martin-la-Porte Access Gallery     

The Manh Vu  Jean Sulem  Didier Subrin  Nathalie Monin  Judith Lascols 《Rock Mechanics and Rock Engineering》2013,46(2):231-246

In this paper, we analyse the convergence measurements recorded in a gallery excavated in severely squeezing ground. The procedure consists in a preliminary geometrical treatment of the raw data to evaluate the principal axes of deformation by assuming an elliptic deformation of the walls of the gallery. Then the convergence law proposed by Sulem et al. (Int J Rock Mech Min Sci Geomech Abstr 24(3):145–154, 1987a), which is extended to account for anisotropic closure, is fitted on the displacements along the two axes of the obtained ellipse. This procedure is more robust and relevant than fitting the convergence recorded on the most deforming segment or fitting the average value of the convergence along the various segments. An attempt is made to correlate the amount and the direction of anisotropic deformation with the lithology and some geological features described by the dominant discontinuity families.  相似文献   

Spatial and Temporal Variability of the CO2 Fluxes in a Tropical, Highly Urbanized Estuary     

Carlos E. D. Noriega  Moacyr Araujo  Nathalie Lefèvre 《Estuaries and Coasts》2013,36(5):1054-1072

The spatial and temporal variations of the flux of CO₂ were determined during 2007 in the Recife estuarine system (RES), a tropical estuary that receives anthropogenic loads from one of the most populated and industrialized areas of the Brazilian coast. The RES acts as a source of nutrients (N and P) for coastal waters. The calculated CO₂ fluxes indicate that the upstream inputs of CO₂ from the rivers are largely responsible for the net annual CO₂ emission to the atmosphere of +30 to +48 mmol m^?2 day^?1, depending on the CO₂ exchange calculation used, which mainly occurs during the late austral winter and early summer. The observed inverse relationship between the CO₂ flux and the net ecosystem production (NEP) indicates the high heterotrophy of the system (except for the months of November and December). The NEP varies between ?33 mmol m^?2 day^?1 in summer and ?246 mmol m^?2 day^?1 in winter. The pCO₂ values were permanently high during the study period (average ~4,700 μatm) showing a gradient between the inner (12,900 μatm) and lower (389 μatm) sections on a path of approximately 30 km. This reflects a state of permanent pollution in the basin due to the upstream loading of untreated domestic effluents (N/P?=?1,367:6 μmol kg^?1 and pH?=?6.9 in the inner section), resulting in the continuous mineralization of organic material by heterotrophic organisms and thereby increasing the dissolved CO₂ in estuarine waters.  相似文献   

The November 2002 eruption of Piton de la Fournaise,Réunion: tracking the pre-eruptive thermal evolution of magma using melt inclusions     

Nathalie Vigouroux  A. E. Williams-Jones  Paul Wallace  Thomas Staudacher 《Bulletin of Volcanology》2009,71(9):1077-1089

The November 2002 eruption of Piton de la Fournaise in the Indian Ocean was typical of the activity of the volcano from 1999 to 2006 in terms of duration and volume of magma ejected. The first magma erupted was a basaltic liquid with a small proportion of olivine phenocrysts (Fo₈₁) that contain small numbers of melt inclusions. In subsequent flows, olivine crystals were more abundant and richer in Mg (Fo_83–84). These crystals contain numerous melt and fluid inclusions, healed fractures, and dislocation features such as kink bands. The major element composition of melt inclusions in this later olivine (Fo_83–84) is out of equilibrium with that of its host as a result of extensive post-entrapment crystallization and Fe²⁺ loss by diffusion during cooling. Melt inclusions in Fo₈₁ olivine are also chemically out of equilibrium with their hosts but to a lesser degree. Using olivine–melt geothermometry, we determined that melt inclusions in Fo₈₁ olivine were trapped at lower temperature (1,182 ± 1°C) than inclusions in Fo_83–84 olivine (1,199–1,227°C). This methodology was also used to estimate eruption temperatures. The November 2002 melt inclusion compositions suggest that they were at temperatures between 1,070°C and 1,133°C immediately before eruption and quenching. This relatively wide temperature range may reflect the fact that most of the melt inclusions were from olivine in lava samples and therefore likely underwent minor but variable amounts of post-eruptive crystallization and Fe²⁺ loss by diffusion due to their relatively slow cooling on the surface. In contrast, melt inclusions in tephra samples from past major eruptions yielded a narrower range of higher eruption temperatures (1,163–1,181°C). The melt inclusion data presented here and in earlier publications are consistent with a model of magma recharge from depth during major eruptions, followed by storage, cooling, and crystallization at shallow levels prior to expulsion during events similar in magnitude to the relatively small November 2002 eruption.  相似文献   

Non-Locality,Causality and Aether in Quantum Mechanics     

J. P. Vigier 《Astronomische Nachrichten》1982,303(1):55-80

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Chlorine isotopic composition in seafloor serpentinites and high-pressure metaperidotites. Insights into oceanic serpentinization and subduction processes   总被引：1，自引：0，他引：1  

Magali Bonifacie  Vincent Busigny  Pascal Philippot  Nathalie Jendrzejewski  Marc Javoy 《Geochimica et cosmochimica acta》2008,72(1):126-139

Bulk-rock chlorine content and isotopic composition (δ³⁷Cl) were determined in oceanic serpentinites, high-pressure metaperidotites and metasediments in order to gain constraints on the global chlorine cycle associated with hydrothermal alteration and subduction of oceanic lithosphere. The distribution of insoluble chlorine in oceanic serpentinites was also investigated by electron microprobe. The hydrothermally-altered ultramafic samples were dredged along the South West Indian Ridge and the Mid-Atlantic Ridge. The high-pressure metamorphic samples were collected in the Western Alps: metaperidotites in the Erro-Tobbio unit and metasediments in the Schistes Lustrés nappe.Oceanic serpentinites show relatively large variations of bulk-rock Cl contents and δ³⁷Cl values with mean values of 1105 ± 596 ppm and −0.7 ± 0.4‰, respectively (n = 8; 1σ). Serpentines formed after olivine (meshes) show lower Cl content than those formed after orthopyroxene (bastites). In bastites of two different samples, Cl is positively correlated with Al₂O₃ and negatively correlated with SiO₂. These relationships are interpreted as reflecting preferential Cl-incorporation into the bastite structure distorted by Al (substituted for Si) rather than different alteration conditions between olivine and orthopyroxene minerals. High-pressure metaperidotites display relatively homogeneous Cl contents and δ³⁷Cl values with mean values of 467 ± 88 ppm and −1.4 ± 0.1‰, respectively (n = 7; 1σ). A macroscopic high-pressure olivine-bearing vein, formed from partial devolatilization of serpentinites at ∼2.5 GPa and 500-600 °C, shows a Cl content and a δ³⁷Cl value of 603 ppm and −1.6‰, respectively. Metasediments (n = 2) show low whole-rock Cl contents (<15 ppm Cl) that did not allow Cl isotope analyses to be obtained.The range of negative δ³⁷Cl values observed in oceanic serpentinites is likely to result from water-rock interaction with fluids that have negative δ³⁷Cl values. The homogeneity of δ³⁷Cl values from the high-pressure olivine-bearing vein and the metaperidotite samples implies that progressive loss of Cl inherited from oceanic alteration throughout subduction did not significantly fractionate Cl isotopes. Chlorine recycled in subduction zones via metaperidotites should thus show a range of δ³⁷Cl values similar to the range found in oceanic serpentinized peridotites.  相似文献   

Quantifying Li isotope fractionation during smectite formation and implications for the Li cycle     

N. Vigier  A. Decarreau  J. Carignan  C. France-Lanord 《Geochimica et cosmochimica acta》2008,72(3):780-792

Tri-octahedral Li-Mg smectites (hectorites) were synthesized at temperatures ranging from 25 to 250 °C, in the presence of solutions highly enriched in lithium. After removing all the exchangeable lithium from the synthesized clays, Li isotope fractionation (Δ⁷Li_{clay-solution}) was determined. This fractionation was linked to Li incorporation into the structural octahedral site, substituting for Mg²⁺. As predicted, experimental Δ⁷Li_{clay-solution} inversely correlates with temperature, and ranges from −1.6‰ ± 1.3‰ at 250 °C to −10.0‰ ± 1.3‰ at 90 °C, and then stays relatively constant down to 25 °C. The relatively constant isotope fractionation factor below 90 °C may be due to high concentrations of edge octahedra in low crystallinity smectites. The isotopic fractionation factor (α), for a given temperature, does not depend on the solution matrix, nor on the amount of structural Li incorporated into the clay. Empirical linear laws for α as a function of 1/T (K) were inferred. Smectite Li contents and smectite-solution distribution coefficients (D_Li/Mg) increase with temperature, as expected for a substitution process. The fractions of dissolved Li incorporated into the smectite octahedral sites are small and do not depend on the duration of the experiment. In a seawater-like matrix solution, less Li is incorporated into the smectites, probably as a result of competition with dissolved Mg²⁺ ions for incorporation into the octahedral sites. The high Li contents observed in marine smectites are therefore best explained either by a significant contribution from basalts, by adsorption processes, or by the influence of seawater chemical composition on distribution coefficients. We also calculate, using present-day estimates of hydrothermal water and river fluxes, that a steady-state ocean would require a relatively large global clay-water Li isotope fractionation (−12‰ to −21‰). This study demonstrates the ability of laboratory experiments to quantify the impact of secondary phases on the Li geochemical cycle and associated isotope fractionations.  相似文献   

Sensitivity of future U.S. Water shortages to socioeconomic and climate drivers: a case study in Georgia using an integrated human-earth system modeling framework   总被引：1，自引：0，他引：1  

Michael J. Scott  Don S. Daly  Mohamad I. Hejazi  G. Page Kyle  Lu Liu  Haewon C. McJeon  Anupriya Mundra  Pralit L. Patel  Jennie S. Rice  Nathalie Voisin 《Climatic change》2016,136(2):233-246

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Seasonal and Interannual Variability in the Distribution of Surface Nutrients and Dissolved Inorganic Carbon in the Northern North Pacific: Influence of El Niño     

Chi Shing Wong  Nathalie A. D. Waser  Yukihiro Nojiri  Wm. Keith Johnson  Frank A. Whitney  John S. C. Page  Jiye Zeng 《Journal of Oceanography》2002,58(2):227-243

The seasonal and interannual changes in surface nutrients, dissolved inorganic carbon (DIC) and total alkalinity (TA) were recorded in the North Pacific (30–54°N) from 1995 to 2001. This study focuses on the region north of the subarctic boundary (∼40°N) where there was extensive monthly coverage of surface properties. The nutrient cycles showed large interannual variations in the eastern and western subarctic gyres. In the Alaska Gyre the seasonal depletion of nitrate (ΔNO₃) increased from 8–14 μmol kg⁻¹ in 1995–1999 to 21.5 μmol kg⁻¹ in 2000. In the western subarctic the shifts were similar in amplitude but more frequent. The large ΔNO₃ levels were associated with high silicate depletions, indicating enhanced diatom production. The seasonal DIC:NO₃ drawdown ratios were elevated in the eastern and central subarctic due to calcification. In the western subarctic and the central Bering Sea calcification was significant only during 1997 and/or 1998, two El Ni?o years. Regional C/N stoichiometric molar ratios of 5.7 to 7.0 (>40°N) were determined based on the years with negligible or no calcification. The annual new production (NP_a) based on ΔNO₃ and these C/N ratios showed large interannual variations. NP_a was usually higher in the western than in the eastern subarctic. However, values of 84 gC m⁻²yr⁻¹ were found in the Alaska Gyre in 2000 which is similar to that in the most productive provinces of the northern North Pacific. There were also large increases in NP_a around the Alaska Peninsula in 1997 and 1998. Finally, the net removal of carbon by the biological pump was estimated as 0.72 Gt C yr⁻¹ in the North Pacific (>30°N). This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Predicting river water temperatures using stochastic models: case study of the Moisie River (Québec,Canada)     

Behrouz Ahmadi‐Nedushan  André St‐Hilaire  Taha B. M. J. Ouarda  Laurent Bilodeau  Élaine Robichaud  Nathalie Thiémonge  Bernard Bobée 《水文研究》2007,21(1):21-34

Successful applications of stochastic models for simulating and predicting daily stream temperature have been reported in the literature. These stochastic models have been generally tested on small rivers and have used only air temperature as an exogenous variable. This study investigates the stochastic modelling of daily mean stream water temperatures on the Moisie River, a relatively large unregulated river located in Québec, Canada. The objective of the study is to compare different stochastic approaches previously used on small streams to relate mean daily water temperatures to air temperatures and streamflow indices. Various stochastic approaches are used to model the water temperature residuals, representing short‐term variations, which were obtained by subtracting the seasonal components from water temperature time‐series. The first three models, a multiple regression, a second‐order autoregressive model, and a Box and Jenkins model, used only lagged air temperature residuals as exogenous variables. The root‐mean‐square error (RMSE) for these models varied between 0·53 and 1·70 °C and the second‐order autoregressive model provided the best results. A statistical methodology using best subsets regression is proposed to model the combined effect of discharge and air temperature on stream temperatures. Various streamflow indices were considered as additional independent variables, and models with different number of variables were tested. The results indicated that the best model included relative change in flow as the most important streamflow index. The RMSE for this model was of the order of 0·51 °C, which shows a small improvement over the first three models that did not include streamflow indices. The ridge regression was applied to this model to alleviate the potential statistical inadequacies associated with multicollinearity. The amplitude and sign of the ridge regression coefficients seem to be more in agreement with prior expectations (e.g. positive correlation between water temperature residuals of different lags) and make more physical sense. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献