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An ion exchange technique has been used to determine the copper complexing capacity (CuCC) of strong organic complexing agents at 21 stations across the continental shelf of the southeastern United States and in the western Sargasso Sea. The concentration of dissolved organic carbon (DOC) and total particulate materal (TPM), two pools of potential complexing agents, was also measured at each station. The CuCC ranged from 0.014 to 1.681 μM Cu dm−3 on the inner shelf, from 0.043 to 0.095 μM Cu dm−3 in mid and outer shelf waters, and from < 0.010 to 0.036 μM Cu dm−3 at the Sargasso Sea stations. The correlation between CuCC and both DOC and TPM is highly significant (α < 0.01). Two synoptic surveys of the distribution of DOC and TPM across the shelf showed that DOC ranges from > 3 mg C dm−3 nearshore to <1 mg C dm−3 offshore and that TPM ranges from > 50 mg dm−3 nearshore to <1 mg dm−3 offshore. Both TPM and DOC are most variable on the inner shelf. These data are consistent with CuCC data which indicate that the CuCC of inner shelf waters was relatively high and very heterogeneous. In contrast, DOC, TPM and copper complexing capacity are low and nearly invariant at the Sargasso Sea stations. We present a model of the distribution of complexing agents in different marine environments and hypothesize that the mechanisms underlying differences between environments relate to differences in the source(s) and nature of complexing agents in each system. 相似文献
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A Navier–Stokes solver is used to examine steep waves as they run up a steep beach (10.54°). The volume of fluid method (VOF) is used to model the free surface. Comparison with experimental results shows reasonable overall agreement in the prediction of the free-surface, velocities and accelerations within the flow. A spurious feature at the free-surface was found which does reduce the quality of the results. For a steep wave we see the transition from a steep wave front to a smooth run-up tongue at the beach that is in qualitative agreement with experiment. 相似文献
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Shipley Thomas H. Bangs Nathan L. Henning Alison T. 《Marine Geophysical Researches》1998,20(6):479-494
In deep ocean settings where water depth greatly exceeds the source-to-receiver length, the geometry is insufficient for accurate determinations of velocity from reflection-moveout. However, velocities are crucial for estimates of physical properties and image processing. Focusing analyses with conventional post-stack two-dimensional migration improves images, but does not produce geologically meaningful velocities except in the special case of a two-dimensional earth. For the more general case of the three-dimensional earth there is no a priori method to determine the degree of geometrical complexity. We present a technique using a short-offset three-dimensional (3-D) data set over the 5 km deep trench west of the Lesser Antilles. These data illustrate highly sensitive post-stack 3-D focusing analyses (± 20 m s–1 interval velocities), and the relationship of these seismically derived velocities to rock velocities. In our Barbados example we were able to establish the presence of a widespread 80-160 m thick low-velocity zone at and above the main low-angle fault. This observation suggests the water-rich décollement leaks water into the overlying sections. Also evident is a low-velocity section associated with turbidite sands. These results are confirmed with sparse logging data and well samples. Deep-water short offset 3-D experiments provide a potentially effective approach for velocity estimation, replacing the operational complexity of long-offsets with simpler short-offset techniques. In areas of structural complications and abundant diffracted energy, it is a surprisingly accurate method, utilizing the high fidelity 3-D wavefield and the information carried in zero-offset diffraction ellipsoids. The velocity used to properly collapse a diffraction ellipsoid is explicitly the velocity of propagation in the media since the travel path is known exactly. Thus, the derived velocities should closely represent rock velocities, unlike the 2-D case where the propagation geometry is not known. 相似文献
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In the modern era, the world's refugee problem has changed magnitude and location; it has expanded from a local to a continental, and now global, scale issue. About 90% of the world's 10 million refugees are from developing countries, and over 90% of these will stay there. Refugee generating and receiving countries are concentrated in 5 world regions: Central America, Southwest Asia, Southeast Asia, and Sub-Saharan Africa. Each concentration is unique and is associated with a particular set of regional conflicts. International efforts address short-term relief needs, whereas political instability and repression that generate refugees continue unabated. Refugees along sensitive border regions affect bilateral relations, large groups of refugees can pose political and security problems for the host country, and disputes over refugee policies and their implementation can complicate diplomatic ties. Some highlights of the data follow. 1) The 3 million cross-border refugees and 5.5 million internally displaced persons make the many governments in Sub-Saharan Africa increasingly dependent on Western assistance to solve their problems. Refugees are fleeing armed conflict, tribal violence, and drought, and often generate additional regional turmoil. 2) 3-4 million Afghans have fled their country since the 1978 Marxist coup; about 2.5 million have entered Pakistan. Most choose to remain in camps near the Afghanistan border where they are targets of cross-border attacks. 3) 1.2 million Salvadorans, Guatemalans, and Nicaraguans live outside their native countries. Official refugee and unofficial migrant populations are active in various rebel insurgencies, contribute to strained bilateral relations and tensions in border areas, and are the subject of heated political debate in host countries. 4) 90% of the 1.7 million Indochinese who fled from 1975-May 1986 have been resettled; 168,000 refugees remain in 1st-asylum camps, not including 240,000 Khmer without refugee status, in temporary camps in Thailand. Thailand's large refugee population is involved in factional strife, smuggling, and guerrilla activities. The Thai are particularly concerned about Hmong refugees, who are accused of opium cultivation and destruction of Thai forests through slash-and-burn cultivation. 5) Nearly 62% of the thousands of present Vietnamese refugees to Hong Kong have been in camps 3 years, and 17% 6 years. Many have turned to crime, alcohol, drugs, or prostitution. 相似文献
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Nathan Paldor 《地球物理与天体物理流体动力学》2013,107(4):299-326
Abstract A Rayleigh integral is used to prove that an unbounded geostrophic front of uniform potential vorticity is stable with respect to small perturbations of arbitrary wavelength. The ageostrophic theory developed in this study yields a stable, near-inertial, long trapped mode. Recent oceanic observations of the increase in the energy of the inertial peak in the vicinity of fronts support the existence of this inertial trapped mode. In addition the theory yields a geostrophic mode which is expected to become unstable when the potential vorticity is not uniform. 相似文献