A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1     

William J. Chazey III  Clive R. Neal  Jinesh C. Jain  William S. Kinman 《Geostandards and Geoanalytical Research》2003,27(2):181-192

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).  相似文献   

Surface structure effects on direct reduction of iron oxides by Shewanella oneidensis     

Andrew L. Neal  Kevin M. Rosso  Yuri A. Gorby 《Geochimica et cosmochimica acta》2003,67(23):4489-4503

The atomic and electronic structure of mineral surfaces affects many environmentally important processes such as adsorption phenomena. They are however rarely considered relevant to dissimilatory bacterial reduction of iron and manganese minerals. In this regard, surface area and thermodynamics are more commonly considered. Here we take a first step towards understanding the nature of the influence of mineral surface structure upon the rate of electron transfer from Shewanella oneidensis strain MR-1 outer membrane proteins to the mineral surface and the subsequent effect upon cell “activity.” Cell accumulation has been used as a proxy for cell activity at three iron oxide single crystal faces; hematite (001), magnetite (111) and magnetite (100). Clear differences in cell accumulation at, and release from the surfaces are observed, with significantly more cells accumulating at hematite (001) compared to either magnetite face whilst relatively more cells are released into the overlying aqueous phase from the two magnetite faces than hematite. Modeling of the electron transfer process to the different mineral surfaces from a decaheme (protoporphyrin rings containing a central hexacoordinate iron atom), outer membrane-bound cytochrome of S. oneidensis has been accomplished by employing both Marcus and ab initio density functional theories. The resultant model of electron transfer to the three oxide faces predicts that over the entire range of expected electron transfer distances the highest electron transfer rates occur at the hematite (001) surface, mirroring the observed cell accumulation data. Electron transfer rates to either of the two magnetite surfaces are slower, with magnetite (111) slower than hematite (001) by approximately two orders of magnitude. A lack of knowledge regarding the structural details of the heme-mineral interface, especially in regards to atomic distances and relative orientations of hemes and surface iron atoms and the conformation of the protein envelope, precludes a more thorough analysis. However, the results of the modeling concur with the empirical observation that mineral surface structure has a clear influence on mineral surface-associated cell activity. Thus surface structure effects must be accounted for in future studies of cell-mineral interactions.  相似文献   

Characterisation of Memory Effects and Development of an Effective Wash Protocol for the Measurement of Petrogenetically Critical Trace Elements in Geological Samples by ICP-MS     

Cathleen E. McGinnis  Jinesh C. Jain  Clive R. Neal 《Geostandards and Geoanalytical Research》1997,21(2):289-305

High sensitivity and low detection limits would seem to make inductively coupled plasma-mass spectrometry (ICP-MS) an ideal analytical tool for determining low (sub-μg g^-1) concentrations of the rare earth elements (REE), Y, Zr, Nb, Hf, Ta, Sn, W, Mo, Th, and U in most mafic materials (e.g. Hall and Plant 1992). However, the generally "sticky" nature exhibited by most of the high field strength elements (HFSEs: Zr, Nb, Hf, Ta, Th and U) as well as Sn, W and Mo can result in spurious results due to memory effects transmitted between unknowns and calibration samples. This, in turn, can seriously compromise the sensitivity, accuracy, and precision of ICP-MS analyses for these elements in geological materials. Data resulting from analyses with poor accuracy and precision can lead to erroneous interpretation and misleading petrogenetic modelling. To resolve this problem, we propose an effective wash protocol for these critical trace elements.  相似文献   

Evaluating the influence of landform, surficial geology, and land use on streams using hydrologic simulation modeling   总被引：1，自引：0，他引：1  

Jesse D. Schomberg  George Host  Lucinda B. Johnson  Carl Richards 《Aquatic Sciences - Research Across Boundaries》2005,67(4):528-540

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The role of socio-environmental networking in the sustainability of rain-fed agriculture in the coastal savanna of Ghana     

Michael O’Neal Campbell 《GeoJournal》2005,61(1):79-88

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The influence of weather extremes on the spatial correlation of corn yields     

Jesse B. Tack  Matthew T. Holt 《Climatic change》2016,134(1-2):299-309

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Identification of Uranyl Minerals Using Oxygen K‐Edge X‐Ray Absorption Spectroscopy          下载免费PDF全文

Jesse D. Ward  Mark Bowden  C. Tom Resch  Steven Smith  Bruce K. McNamara  Edgar C. Buck  Gregory C. Eiden  Andrew M. Duffin 《Geostandards and Geoanalytical Research》2016,40(1):135-148

Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.  相似文献   

The effects of migration on <Emphasis Type="Italic">ca.</Emphasis> 100-year-old arsenic-rich mine tailings in Cobalt,Ontario, Canada     

Dale D. Sprague  Frederick A. Michel  Jesse C. Vermaire 《Environmental Earth Sciences》2016,75(5):405

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Jenniferann.com,regional development,and realising the aspirations of mana whenua in Pōkeno     

John Ryks  Jonathan Kilgour  Jesse Whitehead  Amy Whetu  James Whetu 《New Zealand geographer》2019,75(3):152-162

During the 1990s, the township of Pōkeno was held up as an example of a declining rural Aotearoa/New Zealand. By‐passed from the national state highway, it lost its status as a service hub and drastic measures were introduced to revitalise the town, including renaming the town “ Jenniferann.com .” Pōkeno has since undergone an unlikely transformation, with foreign investment and its location within an extended Auckland commuter zone meaning that the township has grown exponentially. This article describes the transformation of Pōkeno and uncovers what has been missing from discussions about Pōkeno's reinvention, namely, the place of mana whenua.  相似文献   

Geospatial data mining for digital raster mapping     

Bruce K. Wylie  Neal J. Pastick  Joshua J. Picotte  Carol A. Deering 《地理信息系统科学与遥感》2019,56(3):406-429

We performed an in-depth literature survey to identify the most popular data mining approaches that have been applied for raster mapping of ecological parameters through the use of Geographic Information Systems (GIS) and remotely sensed data. Popular data mining approaches included decision trees or “data mining” trees which consist of regression and classification trees, random forests, neural networks, and support vector machines. The advantages of each data mining approach as well as approaches to avoid overfitting are subsequently discussed. We also provide suggestions and examples for the mapping of problematic variables or classes, future or historical projections, and avoidance of model bias. Finally, we address the separate issues of parallel processing, error mapping, and incorporation of “no data” values into modeling processes. Given the improved availability of digital spatial products and remote sensing products, data mining approaches combined with parallel processing potentials should greatly improve the quality and extent of ecological datasets.  相似文献