Origin of the 3500-3300 Ma calc-alkaline rocks in the Pilbara Archaean: isotopic and geochemical constraints from the Shaw Batholith   总被引：1，自引：0，他引：1  

M.J. Bickle  L.F. Bettenay  H.J. Chapman  D.I. Groves  N.J. McNaughton  I.H. Campbell  J.R. de Laeter 《Precambrian Research》1993,60(1-4)

Calc-alkaline plutonic rocks, intruded at 3450Ma, comprise a major component of the Shaw Batholith in the Archaean east Pilbara Block, Western Australia. New whole-rock Pb isotopic geochronology confirms the extent of these rocks, but a minor plutonic phase is dated at 3338±52 Ma and represents a second plutonic event of the same age as much of the nearby Mt Edgar Batholith. The Sm----Nd isotopic systematics of the 3450Ma rocks imply their derivation from a heterogeneous source, which probably included a slightly older crustal component as well as a depleted mantle component. The 3338±52 Ma pluton includes components derived from crustal sources older than 3600 Ma. The geochemistry and Sm---Nd isotopic systematics of these rocks are consistent with crustal growth in the early Archaean from upper mantle sources as depleted as the modern upper mantle. The Shaw Batholith calc-alkaline suites exhibit very similar chemical trends on variation diagrams to modern calc-alkaline plutonic rocks which can be modelled by a combination of mixing and fractionation. A suite collected from outcrops displaying prominent igneous layering shows distinct geochemical trends which can be modelled by differentiation into a component enriched in ferromagnesian minerals, principally hornblende, and possibly sphene, magnetite and epidote, and into a leucocratic component containing quartz, plagioclase and K-feld-par. These Archaean calc-alkaline plutonic rocks, in common with rocks from many other Archaean calc-alkaline provinces, exhibit very fractionated REE patterns with depleted HREE contents, a feature considered to result from equilibrium with garnet at depth in lower crustal regions. The geochemistry of the Pilbara Archaean calc-alkaline rocks is identical to the subset of modern continental-margin calc-alkaline plutonic rocks with fractionated REE patterns, such as those from the central and eastern Peninsular Ranges Batholith, western USA. The tectonic setting in which the Archaean calc-alkaline rocks formed is still not known. This reflects both uncertainty associated with the petrogenesis and environments of modern calc-alkaline rocks, as well as the limited knowledge of the precise timing and relationships of plutonic, depositional and tectonic events in the Pilbara Archaean.  相似文献   

Chemical studies of L-chondrites—I. A study of possible chemical sub-groups     

Charles W. Neal  Robert T. Dodd  Eugene Jarosewich  Michael E. Lipschutz 《Geochimica et cosmochimica acta》1981,45(6):891-898

Radiochemical neutron activation analysis of Ag, As, Au, Bi, Co, Cs, Ga, In, Rb, Sb, Te, Tl and Zn and major element data in 14 L4-6 and 3 LL5 chondrites indicates that the L-group is unusually variable and may represent at least 2 sub-groups differing in formation history. Chemical trends in the S/Fe-rich sub-group support textural evidence indicating late loss of a shock-formed Fe-Ni-S melt; the S/Fe-poor sub-group seemingly reflects nebular fractionation only. Highly mobile In and Zn apparently reflect shock-induced loss from L-chondrites. Data for L5 chondrites suggest higher formation temperatures and/or degrees of shock than for LL5 chondrites.  相似文献   

Turbulence Structure of the Unstable Atmospheric Surface Layer and Transition to the Outer Layer   总被引：4，自引：4，他引：0  

K.G. McNaughton 《Boundary-Layer Meteorology》2004,112(2):199-221

We present a new model of the structure of turbulence in the unstable atmospheric surface layer, and of the structural transition between this and the outer layer. The archetypal element of wall-bounded shear turbulence is the Theodorsen ejection amplifier (TEA) structure, in which an initial ejection of air from near the ground into an ideal laminar and logarithmic flow induces vortical motion about a hairpin-shaped core, which then creates a second ejection that is similar to, but larger than, the first. A series of TEA structures form a TEA cascade. In real turbulent flows TEA structures occur in distorted forms as TEA-like (TEAL) structures. Distortion terminates many TEAL cascades and only the best-formed TEAL structures initiate new cycles. In an extended log layer the resulting shear turbulence is a complex, self-organizing, dissipative system exhibiting self-similar behaviour under inner scaling. Spectral results show that this structure is insensitive to instability. This is contrary to the fundamental hypothesis of Monin--Obukhov similarity theory. All TEAL cascades terminate at the top of the surface layer where they encounter, and are severely distorted by, powerful eddies of similar size from the outer layer. These eddies are products of the breakdown of the large eddies produced by buoyancy in the outer layer. When the outer layer is much deeper than the surface layer the interacting eddies are from the inertial subrange of the outer Richardson cascade. The scale height of the surface layer, z _s, is then found by matching the powers delivered to the creation of emerging TEAL structures to the power passing down the Richardson cascade in the outer layer. It is z _s = u _* ³ /k_s, where u _* is friction velocity, k is the von Kármán constant and _s is the rate of dissipation of turbulence kinetic energy in the outer layer immediately above the surface layer. This height is comparable to the Obukhov length in the fully convective boundary layer. Aircraft and tower observations confirm a strong qualitative change in the structure of the turbulence at about that height. The tallest eddies within the surface layer have height z _s, so z _s is a new basis parameter for similarity models of the surface layer.  相似文献   

Experimental calibration of lake-sediment spectral reflectance to chlorophyll a concentrations: methodology and paleolimnological validation   总被引：1，自引：0，他引：1  

Alexander P. Wolfe  Rolf D. Vinebrooke  Neal Michelutti  Benoit Rivard  Biplob Das 《Journal of Paleolimnology》2006,36(1):91-100

Chlorophyll a preserved in lake sediments reflects, in part, past primary production. This study assesses the spectral properties of sedimentary chlorophyll a using visible-near infrared reflectance (VNIR) spectroscopy, with the objective of establishing a new, non-destructive paleolimnological proxy. Reflectance spectra were determined from a dilution series (n = 10) involving incremental additions of pulverized modern algae to a lake sediment matrix of low organic content. This enabled an assessment of the development of sediment reflectance spectra in relation to different sediment chlorophyll a concentrations, and subsequent regression of spectral features against measured concentrations of chlorophyll a and derivatives obtained by high performance liquid chromatography (HPLC). The experiment demonstrates that ubiquitous troughs in sediment reflectance near 675 nm are attributable to chlorophyll a and derivative compounds. A significant correlation (r ² = 0.98, P < 0.01) was obtained between the area of the reflectance trough in the 650–700 nm interval and summed concentrations of chlorophyll a, all derivative isomers, and degradational pheopigments. A simple linear inference model derived from this experiment was applied to a down-core sequence of VNIR spectra from a productive prairie lake (Alberta, Canada), where it produced inferred sediment chlorophyll a concentrations in concordance with HPLC measurements. Although a larger training set is desirable to further refine the inference model, the analyses reported here demonstrate that reflectance spectroscopy provides a rapid, semi-quantitative method for assessing the chlorophyll a content of lake sediments.  相似文献   

Tsunami generation by pyroclastic flow during the 3500-year B.P. caldera-forming eruption of Aniakchak Volcano, Alaska     

C. F. Waythomas  C. A. Neal 《Bulletin of Volcanology》1998,60(2):110-124

 A discontinuous pumiceous sand, a few centimeters to tens of centimeters thick, is located up to 15 m above mean high tide within Holocene peat along the northern Bristol Bay coastline of Alaska. The bed consists of fine-to-coarse, poorly to moderately well-sorted, pumice-bearing sand near the top of a 2-m-thick peat sequence. The sand bed contains rip-up clasts of peat and tephra and is unique in the peat sequence. Major element compositions of juvenile glass from the deposit and radiocarbon dating of enclosing peat support correlation of the pumiceous sand with the caldera-forming eruption of Aniakchak Volcano. The distribution of the sand and its sedimentary characteristics are consistent with emplacement by tsunami. The pumiceous sand most likely represents redeposition by tsunami of climactic fallout tephra and beach sand during the approximately 3.5 ka Aniakchak caldera-forming eruption on the Alaska Peninsula. We propose that a tsunami was generated by the sudden entrance of a rapidly moving, voluminous pyroclastic flow from Aniakchak into Bristol Bay. A seismic trigger for the tsunami is unlikely, because tectonic structures suitable for tsunami generation are present only south of the Alaska Peninsula. The pumiceous sand in coastal peat of northern Bristol Bay is the first documented geologic evidence of a tsunami initiated by a volcanic eruption in Alaska. Received: 3 December 1997 / Accepted: 11 April 1998  相似文献   

Pb isotope fingerprinting of mesothermal gold deposits from central Victoria, Australia: implications for ore genesis   总被引：2，自引：0，他引：2  

F. P. Bierlein  N. J. McNaughton 《Mineralium Deposita》1998,33(6):633-638

New Pb isotope data from three major mesothermal lode gold deposits (Ballarat West, Tarnagulla, Maldon) in central Victoria support a model whereby the metals derived from a large reservoir with a long residence time in the crust below the Palaeozoic Lachlan Fold Belt. The Pb isotopic ratios of least radiogenic samples from these deposits are in close agreement with published Pb signatures for turbidite-hosted gold deposits, and for Devonian granites, elsewhere in the Lachlan Fold Belt. Despite their spatial distribution and variations in the geological setting, the Pb signatures point to the extraction and transport of metals from a crustal source area by long-lasting, large-scale hydrothermal systems, resulting in the prominent homogenisation of Pb isotopic ratios. The enduring interaction between large hydrothermal systems and an extensive crustal source reservoir were a vital pre-requisite in the formation of the Victorian gold province. In this regard, the prospectivity of Victoria is analogous to world-class ore provinces elsewhere, such as the Archaean Yilgarn Block in Western Australia. Received: 10 February 1998 / Accepted: 28 April 1998  相似文献   

A mixed-layer model for regional evaporation     

K. G. McNaughton  T. W. Spriggs 《Boundary-Layer Meteorology》1986,34(3):243-262

A simple mixed-layer model is developed to describe evaporation into a convective planetary boundary layer (PBL). The model comprises volume budget equations for temperature and humidity, equations to describe transport through the surface layer which is treated as part of the lower boundary, and equations to describe entrainment at the top of the PBL. The ground surface is modelled as a canopy resistance. The model was integrated with canopy resistance, surface-layer resistance and available energy, (R _n – G), input as given functions of time, and the simulated PBL was allowed to grow into an atmosphere with known temperature and humidity profiles.Two variants of the mixed-layer model were tested using data from the KNMI tower site at Cabauw in the Netherlands. These variants differed only in the formulation of entrainment: one used a formulation developed by Driedonks (1982) while the other was a simpler formulation. Simulated evaporation agreed very well with observations irrespective of which entrainment formulation was used, despite discrepancies between simulated and observed PBL height growth which were sometimes quite large for the simpler formulation. Sensitivity analysis of the model confirms that good PBL height-growth predictions are not always a prerequisite for good evaporation predictions.  相似文献   

Aluminium solubility controls in acid waters: the need for a reappraisal     

C. Neal  R.A. Skeffington  R. Williams  D.J. Roberts 《Earth and Planetary Science Letters》1987,86(1)

Stability diagrams have been frequently used to demonstrate aluminium solubility controls in acidic stream and soil waters. This paper shows that it is possible by this method to generate apparent controls using random numbers in place of stream chemistry data. Thermodynamic arguments demonstrate that a wide variety of reactions can produce relationships similar to Al(OH)₃ solubility controls. It is proposed that stability diagrams alone should be used with great caution in identifying aluminium solubility controls, taking care that their axes are independent. Thermodynamic solubility calculations should be used with due scepticism. Supplementary investigations should be used where possible to identify phases precipitating or dissolving.  相似文献   

Identification of a collapsing protostar     

Neal J. Evans II  Shudong Zhou  Carsten Kömpe  C. M. Walmsley 《Astrophysics and Space Science》1994,212(1-2):139-145

The globular molecular cloud B335 contains a single, deeply embedded, far-infrared source. Our recent observations of H₂CO and CS lines toward this source provide direct kinematic evidence for collapse. Both the intensity and detailed shape of the line profiles match those expected from inside-out collapse inside a radius of 0.036 pc. The collapse began about 1.5 × 10⁵ years ago, similar to the onset of the outflow. The mass accretion rate is about 10 times the outflow rate, and about 0.4M should have now accumulated in the star and disk. Because B335 rotates only very slowly, any disk would still be very small (about 3 AU). The accretion luminosity should be adequate to power the observed luminosity. Consequently, we believe that B335 is indeed a collapsing protostar.Paper presented at the Conference onPlanetary Systems: Formation, Evolution, and Detection held 7–10 December, 1992 at CalTech, Pasadena, California, U.S.A.  相似文献   

SHRIMP U–Pb geochronology of magmatism and thermal events in the Archaean Marymia Inlier, central Western Australia     

Noreen M. Vielreicher  Neal J. McNaughton 《International Journal of Earth Sciences》2002,91(3):406-432

Zircons from porphyry and granitoid samples collected in and around the Marymia Gold Mine in the Marymia Inlier, Western Australia, record a complex history. The results of U-Pb studies confirm that the Plutonic Well greenstone belt, and the surrounding granitoid envelope (including a 2,721Lj Ma intrusion), represent an Archaean terrain, which was intruded by high-level, felsic to intermediate porphyries at 2,694lj Ma and potentially also at 2,660dž Ma. Zircon xenocrysts (Sca. 3.35, 2.93 and 2.74 Ga) indicate that there was older crust within, or below, the greenstone belt at the time of porphyry emplacement. Zircons from the granitoid envelope and intrusions within the greenstone belt record subsequent metamorphism and/or hydrothermal activity coeval with magmatism in the Late Archaean (ca. 2.66-2.63 Ga), and peak metamorphism, magmatism and gold mineralisation in the Yilgarn Block. A later period of metamorphism and hydrothermal activity at ca. 1.72 Ga is coeval with orogenesis in the southern Capricorn Orogen. Both the Late Archaean and Palaeoproterozoic thermal events have altered zircons, redistributed trace elements and caused zircon recrystallisation, which is distinctive in its isotope chemistry (in particular Th/U ratios >1) and morphology (e.g. homogeneous in transmitted light and back-scattered electron images, but sector-zoned in cathodoluminescence).  相似文献