Determination of the REE in Geological Reference Materials DTS-1 (Dunite) and PCC-1 (Peridotite) by Ultrasonic and Microconcentric Desolvating Nebulisation ICP-MS     

Jinesh C. Jain  M. Paul Field  Clive R. Neal  James C. Ely  Robert M. Sherrell 《Geostandards and Geoanalytical Research》2000,24(1):65-72

Inductively coupled plasma-mass spectrometry is well suited for the precise, accurate and rapid determination of rare earth elements in most geological samples. However, determination of rare earth elements in certain mantle-derived materials, without applying preconcentration techniques, remains problematical due to low natural concentrations (generally < 1 ng g⁻¹). Consequently, USGS reference materials DTS-1 (a dunite) and PCC-1 (a partially serpentinized harzburgite) have only suggested rather than recommended values for the rare earth elements in reference material compilations. We compared results obtained using two ICP-MS instruments: a U-5000AT ultrasonic nebuliser coupled to a PQ2+ quadrupole ICP-MS and an ELEMENT sector field ICP-MS equipped with a MCN-6000 microconcentric desolvating nebuliser, with the suggested literature values for these two reference materials. Precision and accuracy of analytical methods employed by both instruments were demonstrated by excellent relative standard deviations (< 2%) and inter-laboratory agreement (< 5%) for numerous analyses of BHVO-1 and BIR-1, which are well established with rare earth elements contents at the μg g⁻¹ level. Repeat analyses of DTS-1 and PCC-1 at each laboratory indicate that each method is generally precise to better than 5% at sub-g g⁻¹ levels. Furthermore, values from both instruments generally agree to within 10%. Our DTS-1 and PCC-1 values agree reasonably well with selected data reported in the literature (except for Ce and Sm in DTS-1) but exhibit poorer agreement with reported compilation values. With the demonstrated level of precision and accuracy, we contend that these new values for DTS-1 and PCC-1, generated by two different instruments, are the best estimates of the true whole-rock composition of these samples reported to date.  相似文献   

Jenniferann.com,regional development,and realising the aspirations of mana whenua in Pōkeno     

John Ryks  Jonathan Kilgour  Jesse Whitehead  Amy Whetu  James Whetu 《New Zealand geographer》2019,75(3):152-162

During the 1990s, the township of Pōkeno was held up as an example of a declining rural Aotearoa/New Zealand. By‐passed from the national state highway, it lost its status as a service hub and drastic measures were introduced to revitalise the town, including renaming the town “ Jenniferann.com .” Pōkeno has since undergone an unlikely transformation, with foreign investment and its location within an extended Auckland commuter zone meaning that the township has grown exponentially. This article describes the transformation of Pōkeno and uncovers what has been missing from discussions about Pōkeno's reinvention, namely, the place of mana whenua.  相似文献   

Geospatial data mining for digital raster mapping     

Bruce K. Wylie  Neal J. Pastick  Joshua J. Picotte  Carol A. Deering 《地理信息系统科学与遥感》2019,56(3):406-429

We performed an in-depth literature survey to identify the most popular data mining approaches that have been applied for raster mapping of ecological parameters through the use of Geographic Information Systems (GIS) and remotely sensed data. Popular data mining approaches included decision trees or “data mining” trees which consist of regression and classification trees, random forests, neural networks, and support vector machines. The advantages of each data mining approach as well as approaches to avoid overfitting are subsequently discussed. We also provide suggestions and examples for the mapping of problematic variables or classes, future or historical projections, and avoidance of model bias. Finally, we address the separate issues of parallel processing, error mapping, and incorporation of “no data” values into modeling processes. Given the improved availability of digital spatial products and remote sensing products, data mining approaches combined with parallel processing potentials should greatly improve the quality and extent of ecological datasets.  相似文献   

Variability of stream extents controlled by flow regime and network hydraulic scaling     

Dana A. Lapides  Christine D. Leclerc  Hana Moidu  David N. Dralle  W. Jesse Hahm 《水文研究》2021,35(3):e14079

Stream networks expand and contract through time, impacting chemical export, aquatic habitat, and water quality. Although recent advances improve prediction of the extent of the wetted channel network (L ) based on discharge at the catchment outlet (Q ), controls on the temporal variability of L remain poorly understood and unquantified. Here we develop a quantitative, conceptual framework to explore how flow regime and stream network hydraulic scaling factors co-determine the relative temporal variability in L (denoted here as the total wetted channel drainage density). Network hydraulic scaling determines how much L changes for a change in Q , while the flow regime describes how Q changes in time. We compiled datasets of co-located dynamic stream extent mapping and discharge to analyze all globally available empirical data using the presented framework. We found that although variability in L is universally damped relative to variability in Q (i.e., streamflow is relatively more variable in time than network extent), the relationship is elastic, meaning that for a given increase in the variability in Q , headwater catchments will experience greater-than-proportional increases in the variability of L . Thus, under anticipated climatic shifts towards more volatile precipitation, relative variability in headwater stream network extents can be expected to increase even more than the relative variability of discharge itself. Comparison between network extents inferred from the L -Q relationship and blue lines on USGS topographic maps shows widespread underestimation of the wetted channel network by the blue line network.  相似文献   

Chloride in precipitation and streamwater for the upland catchment of river severn,mid-wales; some consequences for hydrochemical models     

Colin Neal  Nils Christophersen  Richard Neale  Christopher J. Smith  Paul G. Whitehead  Brian Reynolds 《水文研究》1988,2(2):155-165

Variations in the concentration of Cl in rainfall and stream runoff are presented for two catchments in the Hafren forest of mid-Wales, Great Britain. Despite the large fluctuations in rainfall concentrations, Cl in the streamwater remains relatively constant. Using the two-reservoir Birkenes model, an attempt was made to simulate observed Cl in streamwater. The original model was unable to reproduce the observations and several modifications are suggested to provide better simulations. The resulting model is not the only one capable of reproducing the observations; other hydrochemical models will most probably also achieve this although emphasis will in each case be placed on different aspects. In this paper, it is suggested that the stochastic properties of water movement and chemical processes can account for the streamwater chemistry responses observed. On the catchment scale these processes will lead to an apparently deterministic behaviour that may well be described by simple relationships.  相似文献   

The XXVth International Geographical Congress     

H. Jesse Walker 《The Professional geographer》1985,37(1):93-97

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Lyα flux power spectrum and its covariance     

Hu Zhan  Romeel Davé  Daniel Eisenstein  Neal Katz 《Monthly notices of the Royal Astronomical Society》2005,363(4):1145-1154

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How do galaxies get their gas?     

Du&#;an Kere&#;  Neal Katz  David H. Weinberg  Romeel Davé 《Monthly notices of the Royal Astronomical Society》2005,363(1):2-28

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On the Relevance of $$\ln (z_{0} /z_{0T})= kB^{-1}$$     

Bruce B. Hicks  William R. Pendergrass  Barry D. Baker  Rick D. Saylor  Debra L. O’Dell  Neal S. Eash  Jeffrey T. McQueen 《Boundary-Layer Meteorology》2018,167(2):285-301

The assumption that the roughness Reynolds number \(( Re_{*})\) can be used as a basis for quantifying the boundary-layer property \({ kB}^{-1} (= \ln (z_{0}/z_{0T}))\) as in some modern numerical models is questioned. While \({ Re}_{*}\) is a useful property in studies of pipe flow, it appears to have only marginal applicability in the case of treeless terrain, as studied in the two experimental situations presented here. For both the daytime and night-time cases there appears to be little correlation between \({ kB}^{-1}\) and \({ Re}_{*}\). For daytime, the present studies indicate that the assumption \({ kB}^{-1} \approx 2\) is acceptable, while for night-time, the scatter involved in relating \({ kB}^{-1}\) to \({ Re}_{*}\) suggests there is little reason to assume a direct relationship. However, while the scatter affecting all of the night-time results is large, there remains a significant correlation between the heat and momentum fluxes upon which an alternative methodology for describing bulk air–surface exchange at night could be constructed. The friction coefficient (\(C_{f}\)) and the turbulent Stanton number \(({ St}_{*})\) are discussed as possible alternatives for describing bulk properties of the air layer adjacent to the surface. While describing the surface roughness in terms of the friction coefficient provides an attractive simplification relative to the conventional methodologies based on roughness length and stability considerations, use of the Stanton number shares many of uncertainties that affect \({ kB}^{-1}\). The transitions at dawn and dusk remain demanding situations to address.  相似文献   

Increasing Iron Concentrations in UK Upland Waters     

C. Neal  S. Lofts  C. D. Evans  B. Reynolds  E. Tipping  M. Neal 《Aquatic Geochemistry》2008,14(3):263-288

Iron distributions in rainfall, streams, soils and groundwaters are described for the Upper River Severn catchment of mid-Wales. Iron is mainly supplied from within-catchment sources with highest concentrations occurring under reducing conditions. Iron concentrations have doubled over the past 20 years (~5.0 μg yr⁻¹ for the forest and ~3.7 μg yr⁻¹ for the moorland). For the forested sites, the gradients are particularly high post-1993. UK rivers/lakes monitored by the UK Acid Waters Monitoring Network show similar increases. Generally, Fe correlates with dissolved organic carbon (DOC). The greatest rates of Fe increase coincide with those for DOC. Thermodynamic modelling using WHAM/Model VI indicates that Fe(III) is mainly in microparticulate form (probably oxyhydroxides) apart from under reducing conditions. It is proposed that Fe increases for surface waters are associated with increased microparticulate Fe(III) due to stabilisation against aggregation by binding of DOM to its surface. The results relate to acidification declines and deforestation leading to land disturbance and wetter conditions within the soil. There will be greater acidification reversal following tree harvesting due to lowering of atmospheric SO_x scavenging and this may have resulted in the greater increase in Fe in the later years of the study.  相似文献