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121.
122.
The Moon likely accreted from melt and vapor ejected during a cataclysmic collision between Proto-Earth and a Mars-sized impactor very early in solar system history. The identical W, O, K, and Cr isotope compositions between materials from the Earth and Moon require that the material from the two bodies were well-homogenized during the collision process. As such, the ancient isotopic signatures preserved in lunar samples provide constraints on the bulk composition of the Earth. Two recent studies to obtain high-precision 142Nd/144Nd ratios of lunar mare basalts yielded contrasting results. In one study, after correction of neutron fluence effects imparted to the Nd isotope compositions of the samples, the coupled 142Nd-143Nd systematics were interpreted to be consistent with a bulk Moon having a chondritic Sm/Nd ratio [Rankenburg K., Brandon A. D. and Neal C. R. (2006) Neodymium isotope evidence for a chondritic composition of the Moon. Science312, 1369-1372]. The other study found that their data on the same and similar lunar mare basalts were consistent with a bulk Moon having a superchondritic Sm/Nd ratio [Boyet M. and Carlson R. W. (2007) A highly depleted Moon or a non-magma origin for the lunar crust? Earth Planet. Sci. Lett.262, 505-516]. Delineating between these two potential scenarios has key ramifications for a comprehensive understanding of the formation and early evolution of the Moon and for constraining the types of materials available for accretion into large terrestrial planets such as Earth.To further examine this issue, the same six lunar mare basalt samples measured in Rankenburg et al. [Rankenburg K., Brandon A. D. and Neal C. R. (2006) Neodymium isotope evidence for a chondritic composition of the Moon. Science312, 1369-1372] were re-measured for high-precision Nd isotopes using a multidynamic routine with reproducible internal and external precisions to better than ±3 ppm (2σ) for 142Nd/144Nd ratios. The measurements were repeated in a distinct second analytical campaign to further test their reproducibility. Evaluation of accuracy and neutron fluence corrections indicates that the multidynamic Nd isotope measurements in this study and the 3 in Boyet and Carlson [Boyet M. and Carlson R. W. (2007) A highly depleted Moon or a non-magma origin for the lunar crust? Earth Planet. Sci. Lett.262, 505-516] are reproducible, while static measurements in the previous two studies show analytical artifacts and cannot be used at the resolution of 10 ppm to determine a bulk Moon with either chondritic or superchondritic Sm/Nd ratios. The multidynamic data are best explained by a bulk Moon with a superchondritic Sm/Nd ratio that is similar to the present-day average for depleted MORB. Hafnium isotope data were collected on the same aliquots measured for their 142Nd/144Nd isotope ratios in order to assess if the correlation line for 142Nd-143Nd systematics reflect mixing processes or times at which lunar mantle sources formed. Based on the combined 142Nd-143Nd-176Hf obtained we conclude that the 142Nd-143Nd correlation line measured in this study is best interpreted as an isochron with an age of 229+24−20Ma after the onset of nebular condensation. The uncertainties in the data permit the sources of these samples to have formed over a 44 Ma time interval. These new results for lunar mare basalts are thus consistent with a later Sm-Nd isotope closure time of their source regions than some recent studies have postulated, and a superchondritic bulk Sm/Nd ratio of the Moon and Earth. The superchondritic Sm/Nd signature was inherited from the materials that accreted to make up the Earth-Moon system. Although collisional erosion of crust from planetesimals is favored here to remove subchondritic Sm/Nd portions and drive the bulk of these bodies to superchondritic in composition, removal of explosive basalt material via gravitational escape from such bodies, or chondrule sorting in the inner solar system, may also explain the compositional features that deviate from average chondrites that make up the Earth-Moon system. This inferred superchondritic nature for the Earth similar to the modern convecting mantle means that there is no reason to invoke a missing, subchondritic reservoir to mass balance the Earth back to chondritic for Sm/Nd ratios. However, to account for the subchondritic Sm/Nd ratios of continental crust, a second superchondritic Sm/Nd mantle reservoir is required.  相似文献   
123.
Historical reconstructions and predictions of streamwater acidification are presented for moorland and afforested catchments in the Welsh Uplands at Plynlimon. MAGIC (Model of Acidification of Groundwater In Catchments) is validated by application to an afforested catchment. MAGIC is used to illustrate that atmospheric deposition is primarily responsible for stream acidification but that conifer afforestation can enhance stream acidity. The historical trends determined by the model illustrate that long-term acidification has been present since the turn of the century and will continue unless either deposition levels are reduced significantly or liming is undertaken on a major scale.  相似文献   
124.
The International Center for Living Aquatic Resources Management (ICLARM) is a new, small research organization, working in fisheries and aquaculture in the developing countries. The Center has four programmes: (1) traditional fisheries in which socioeconomic studies have had wide impact in the literature and have resulted in legislative change; (2) resource development and management, the principal accomplishment of which has been compilation of new microcomputer and calculator programmes for tropical stock assessment and their adoption in 12 countries to date; (3) aquaculture, with major biological and economic research being carried out in integrated farming systems, and on the most important tropical culture commodities, tilapias and carps; (4) education and training, in which major thrusts in new educational materials and specialized training are planned.  相似文献   
125.
Results are presented of a study of stable hydrogen and oxygen isotopes in rainfall and streamwaters for the Montseny and Prades areas in northeastern Spain: results cover the full year of 1991. The isotopic pattern for rainfall is similar for both areas: there is a wide range in isotopic contents and the results show a strong, near-linear trend, δ2H = 7.9 × δ18O + 9.8 (N = 59; r2 = 0.952), the ‘local meteoric line’. There is slight curvature to the data which may be related to the sources of water vapour forming the rainfall. Within the streams, the isotopic variability is much less than that of the rainfall although the data lie on, or very near to, the meteoric line. Data for detailed collections during storm events show more scatter than those collected regularly on a fortnightly basis. The event data show a linear feature that conforms to the local meteoric line. These results indicate that: (1) the main supply of water to the stream stormflow comes from water stored in the catchment prior to the event; (2) waters of more than one isotopic composition reside within the catchment and are transferable to the stream during storm events; (3) the main process of water transfer from the catchment back to the atmosphere comes from transpiration by the trees and (possibly) complete evaporation from the near-surface soil horizons and the tree canopy; (4) the isotopic technique cannot be used for quantitative hydrograph separation in this instance — at least two water types can be present within the catchment at any given time.  相似文献   
126.
The problem of predicting future short-term chemical behaviour in acidic and acid-sensitive streams is addressed. A relatively simple method is presented which combines a chemical technique for splitting the hydrograph into ground water and soil water components, based on the conservative component acid neutralization capacity, with the long-term hydrochemical model (MAGIC) in a ‘two-box’ mode. This method, coupled with a chemical speciation program (ALCHEMI), is used to assess short-term variations in stream chemistry with change in atmospheric deposition chemistry. The method is applied for a semi-natural moorland catchment in mid-Wales (Afon Gwy). For both hydrogen ion and inorganic aluminium, the modelled stream mixing relationships are non-linear, particularly at low hydrogen ion concentrations. The results also show that the relationship between hydrogen ion and inorganic aluminium concentrations varies with time in the stream. This result has important implications as it implies that aluminium concentrations will not recover, with reduced anthropogenic sulphur deposition, as rapidly as has previously been thought. Two methods, for use with critical load evaluation of ecological stress, are presented for describing the changes occurring: the hydrogen ion and inorganic aluminium concentration duration curve; the hydrogen ion and inorganic aluminium incident frequenty diagram.  相似文献   
127.
The Gebbies Pass region consists of a saddle at a height of approximately 300 m, bounded by two ranges of hills approximately 500 m high. A survey technique which yielded mean wind speeds at a height of 10 m in this region is shown to provide excellent reproducibility for data collected 6 months apart. The survey results are also shown to correlate extremely well with those obtained from a 1:4000 scale model analysed in a Planetary Boundary Layer wind tunnel.Wind structure information obtained upstream of the saddle and at its crest is presented and compared with the wind tunnel model and other studies where possible. The velocity profile was measured up to 160 m at the crest and was found to be almost vertical; however, there was a noticeable jet at the 15 m height, which was not apparent on the model. Measurements at 10 m height showed a velocity increase of 40–60% at the crest compared to the approach terrain velocity at the same height above ground level. The longitudinal r.m.s. turbulence component u was found to increase at the saddle but still resulted in reduced turbulence intensity values relative to the upstream situation. The longitudinal component of the energy spectrum at the upwind site was in excellent agreement with the theoretical model proposed by Kaimal et al. (1972). However, at the saddle crest the theoretical spectrum was too high and required further modification to fit the measured data. It is proposed that a terrain factor be used to make the necessary adjustment since the theoretical spectra are strictly only valid for flat homogeneous terrain.  相似文献   
128.
Dissimilatory metal reducing bacteria (DMRB) can influence geochemical processes that affect the speciation and mobility of metallic contaminants within natural environments. Most investigations into the effect of DMRB on sediment geochemistry utilize various synthetic oxides as the FeIII source (e.g., ferrihydrite, goethite, hematite). These synthetic materials do not represent the mineralogical composition of natural systems, and do not account for the effect of sediment mineral composition on microbially mediated processes. Our experiments with a DMRB (Shewanella putrefaciens 200) and a divalent metal (ZnII) indicate that, while complexity in sediment mineral composition may not strongly impact the degree of “microbial iron reducibility,” it does alter the geochemical consequences of such microbial activity. The ferrihydrite and clay mineral content are key factors. Microbial reduction of a synthetic blend of goethite and ferrihydrite (VHSA-G) carrying previously adsorbed ZnII increased both [ZnII-aq] and the proportion of adsorbed ZnII that is insoluble in 0.5 M HCl. Microbial reduction of FeIII in similarly treated iron-bearing clayey sediment (Fe-K-Q) and hematite sand, which contained minimal amounts of ferrihydrite, had no similar effect. Addition of ferrihydrite increased the effect of microbial FeIII reduction on ZnII association with a 0.5 M HCl insoluble phase in all sediment treatments, but the effect was inconsequential in the Fe-K-Q. Zinc k-edge X-ray absorption spectroscopy (XAS) data indicate that microbial FeIII reduction altered ZnII bonding in fundamentally different ways for VHSA-G and Fe-K-Q. In VHSA-G, ZnO6 octahedra were present in both sterile and reduced samples; with a slightly increased average Zn-O coordination number and a slightly higher degree of long-range order in the reduced sample. This result may be consistent with enhanced ZnII substitution within goethite in the microbially reduced sample, though these data do not show the large increase in the degree of Zn-O-metal interactions expected to accompany this change. In Fe-K-Q, microbial FeIII reduction transforms Zn-O polyhedra from octahedral to tetrahedral coordination and leads to the formation of a ZnCl2 moiety and an increased degree of multiple scattering. This study indicates that, while many sedimentary iron minerals are easily reduced by DMRB, the effects of microbial FeIII reduction on trace metal geochemistry are dependent on sediment mineral composition.  相似文献   
129.
SHRIMP U–Pb zircon studies on two post-collisional granitic plutons and reassessment of the data previously reported for two anatectic gneissic granites are used to assess the late Neoproterozoic history of the Florianópolis Batholith, southern Brazil. The results, supported by SEM backscattered and cathodoluminescence imagery, identify inherited zircon populations and confirm the long-lived, crustal recycling processes responsible for the accretion of the batholith. The study casts new lights on the timing of the processes involved in the generation and modification of the internal structure of distinct zircon populations, and enables discrimination to be made between inherited cores and melt-precipitated overgrowths. New dating of two post-tectonic plutons (samples 1 and 2) revealed crystals showing magmatic-textured cores sharply bounded by melt-precipitated overgrowths. The U/Pb isotopic results from both samples spread along concordia by ca. 40 m.y. (sample 1) to 100 m.y. (sample 2), clustering in two closely spaced (bimodal), partially overlapping peaks. Melt-precipitated rims and homogeneous new grains, dated at ca. 600 Ma, furnish the crystallisation age of the plutons. The magmatic textured cores and xenocrysts dated at ca. 630–620 Ma are interpreted as inherited restitic material from supposedly short-lived (meta)granitic sources. The reassessment of previous SHRIMP data of two banded anatectic granitoids (samples 3 and 4) revealed more complex morphological patterns, in which the overgrown inherited cores are sharply bounded against large melt-precipitated rims, dated at ca. 600 Ma and 592±2 Ma, respectively. Major populations of magmatic-textured inherited cores dated at 2006±3 Ma and 2175±13 Ma characterise samples 3 and 4, respectively. The latter additionally shows metamorphic and magmatic inherited cores with a large range of ages (ca. 2900–620 Ma), suggesting partial melting of metasedimentary components. The main magmatic Paleoproterozoic core populations are interpreted as inherited restite from partial melting of the adjacent (meta)tonalitic gneiss and amphibolitic country-rock (paleosome). The recognition of the (melt-precipitated) Neoproterozoic overgrowths and new crystals, and the restite provenance of the cores, supplants a previous interpretation of Paleoproterozoic magmatism (cores) and Neoproterozoic (solid-state) metamorphic overprint. As a major consequence of the former interpretation, the unit was mistakenly considered part of major Paleoproterozoic gneissic remnant within the Neoproterozoic Florianópolis Batholith/arc.  相似文献   
130.
This article argues that insufficient attention has been paid in the recent literature to the social and environmental factors which regulate hunting in Ghanaian savannas, and to how this may influence the sustainability of their livelihoods. Despite the vital significance of this issue, the emphasis in the literature and media has been on the destructive impacts of hunting and the bushmeat trade on wildlife. Taking a case study from the coastal savanna of Ghana, a region commonly regarded as a degraded relict of former deciduous forest with a richer wildlife past, it investigates the hypothesis that structure/actor dualities, manifested by socio-cultural change, local environmental knowledge and livelihood activity options, are the primary regulators of hunting intensity and possible sustainability. Such an evaluation is effective if done from a structuration perspective. The integrated methodology incorporates social surveys, GIS based time series image analysis, ecological field methods and statistical analysis. The results provide evidence that the direct and indirect regulatory functions of the socioenvironmental context provide a core feature of the sustainability of hunting. It is concluded that local strategies of resource management may provide an effective complement to conservation policy.  相似文献   
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