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411.
Interpolated geochemical maps contain problems of sample catchments and vacant sample areas. However, the resemblance of these maps with regional geological maps implies that there are strong correlations between them. A conceptual model of the geological units from multivariate chemical elements is constructed by decision tree technique. The reproducibility of the geological map with the conceptual model is about 80% in the Chungbuk province map of Korea. Statistical uncertainties indicate that rock units could be predicted reasonably well by decision tree if the geological map polygon is big enough. Misinterpreted points are due to interpolation problems between samples from adjacent rock units and from different sample catchments. In the Chungbuk example, the latter is less significant. The size of the map polygon is one of the most critical factors, and a polygon size greater than 50 km2 is reliable for such analyses for the Chungbuk example. Combined lithologies in a single mapping unit are not critically affected by decision tree prediction.  相似文献   
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Spherical calcium dioleate particles (∼ 10 μm in diameter) were used as AFM (atomic force microscope) probes to measure interaction forces of the collector colloid with calcite and fluorite surfaces. The attractive AFM force between the calcium dioleate sphere and the fluorite surface is strong and has a longer range than the DLVO (Derjaguin–Landau–Verwey–Overbeek) prediction. The repulsive AFM force between the calcium dioleate sphere and the fluorite surface does not agree with the DLVO prediction. Consideration of non-DLVO forces, including the attractive hydrophobic force, was necessary to explain the experimental results. The non-DLVO interactions considered were justified by the different interfacial water structures at fluorite– and calcite–water interfaces as revealed by the numerical computation experiments using molecular dynamics simulation. The density of interfacial water at the fluorite surface is low and the fluorite surface is not strongly wetted by water molecules. In contrast to the water at the fluorite surface, water molecules at the calcite surface form tightly packed monolayer structures and the calcite surface is extensively hydrated by water molecules. The interfacial water structure agrees with the AFM force measurements and the flotation recovery data. The strong attraction between the calcium dioleate colloid and the fluorite surface, and the moderately wetted fluorite surface by water molecules explain the better flotation response of fluorite with the oleate collector colloid.  相似文献   
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Three sediment stations in Himmerfjärden estuary (Baltic Sea, Sweden) were sampled in May 2009 and June 2010 to test how low salinity (5–7 ‰), high primary productivity partially induced by nutrient input from an upstream waste water treatment plant, and high overall sedimentation rates impact the sedimentary cycling of methane and sulfur. Rates of sediment accumulation determined using 210Pbexcess and 137Cs were very high (0.65–0.95 cm?year?1), as were the corresponding rates of organic matter accumulation (8.9–9.5 mol C?m?2?year?1) at all three sites. Dissolved sulfate penetrated <20 cm below the sediment surface. Although measured rates of bicarbonate methanogenesis integrated over 1 m depth were low (0.96–1.09 mol?m?2?year?1), methane concentrations increased to >2 mmol?L?1 below the sulfate–methane transition. A steep gradient of methane through the entire sulfate zone led to upward (diffusive and bio-irrigative) fluxes of 0.32 to 0.78 mol?m?2?year?1 methane to the sediment–water interface. Areal rates of sulfate reduction (1.46–1.92 mol?m?2?year?1) integrated over the upper 0–14 cm of sediment appeared to be limited by the restricted diffusive supply of sulfate, low bio-irrigation (α?=?2.8–3.1 year?1), and limited residence time of the sedimentary organic carbon in the sulfate zone. A large fraction of reduced sulfur as pyrite and organic-bound sulfur was buried and thus escaped reoxidation in the surface sediment. The presence of ferrous iron in the pore water (with concentrations up to 110 μM) suggests that iron reduction plays an important role in surface sediments, as well as in sediment layers deep below the sulfate–methane transition. We conclude that high rates of sediment accumulation and shallow sulfate penetration are the master variables for biogeochemistry of methane and sulfur cycling; in particular, they may significantly allow for release of methane into the water column in the Himmerfjärden estuary.  相似文献   
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The groundwater tracer injection and withdrawal tests are often carried out for the determination of aquifer solute transport parameters. However, the parameter analyses encounter a great difficulty due to the radial flow nature and the variability of the temporal boundary conditions. An adaptive methodology for the determination of groundwater solute transport parameters using tracer injection and withdrawal test data had been developed and illustrated through an actual case. The methodology includes the treatment of the tracer boundary condition at the tracer injection well, the normalization of tracer concentration, the groundwater solute transport finite element modelling and the method of least squares to optimize the parameters. An application of this methodology was carried out in a field test in the South of Hanoi city. The tested aquifer is Pleistocene aquifer, which is a main aquifer and has been providing domestic water supply to the city since the French time. Effective porosity of 0.31, longitudinal dispersivity of 2.2 m, and hydrodynamic dispersion coefficients from D = 220 m2/d right outside the pumping well screen to D =15.8 m2/d right outside the tracer injection well screen have been obtained for the aquifer at the test site. The minimal sum of squares of the differences between the observed and model normalized tracer concentration is 0.00119, which is corresponding to the average absolute difference between observed and model normalized concentrations of 0.035 5 (while 1 is the worst and 0 is the best fit).  相似文献   
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Abstract

The impact of climate and land-use changes on hydrological processes and sediment yield is investigated in the Be River catchment, Vietnam, using the Soil and Water Assessment Tool (SWAT) hydrological model. The sensitivity analysis, model calibration and validation indicated that the SWAT model could reasonably simulate the hydrology and sediment yield in the catchment. From this, the responses of the hydrology and sediment to climate change and land-use changes were considered. The results indicate that deforestation had increased the annual flow (by 1.2%) and sediment load (by 11.3%), and that climate change had also significantly increased the annual streamflow (by 26.3%) and sediment load (by 31.7%). Under the impact of coupled climate and land-use changes, the annual streamflow and sediment load increased by 28.0% and 46.4%, respectively. In general, during the 1978–2000 period, climate change influenced the hydrological processes in the Be River catchment more strongly than the land-use change.
Editor Z.W. Kundzewicz; Associate editor Q. Zhang

Citation Khoi, D.N. and Suetsugi, T., 2014. Impact of climate and land-use changes on hydrological processes and sediment yield—a case study of the Be River catchment, Vietnam. Hydrological Sciences Journal, 59 (5), 1095–1108.  相似文献   
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This article studies the effect of dynamic cyclic loading and surcharge preloading method on the post-construction settlement of low embankments. Soil samples obtained from the soft ground under an embankment were consolidated by surcharge preloading followed by static and dynamic cyclic loading in the odometer. The results show that the consolidation deformation of the soil samples is independent of the frequency of the dynamic cyclic loading, which was simulated to follow the half-sine wave, and this is consistent with the energy concept. The post-construction settlement increases with increasing amplitude of cyclic load and the effectiveness of surcharge preloading depends on the difference between magnitude of surcharge and amplitude of the cyclic load. Based on the consolidation theory combined with the test results, a formula has been proposed to compute the post-construction settlement of a low embankment under cyclic loading.  相似文献   
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