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471.
Abstract

A hydraulic parametrization is developed for peatland environments in the Canadian Land Surface Scheme (CLASS). Three ‐wetland soil classes account for the typical variation in the hydraulic characteristics of the uppermost 0.5 m of organic soils. Review of the literature reveals that saturated hydraulic conductivity varies from a median of 1.0 × 10?7m/s in deeply humified sapric peat to 2.8 × 10?4 m/s in relatively undecomposed fibric peat. Average pore volume fraction ranges from 0.83 to 0.93. Parameters have been designed for the soil moisture characteristic curves for fibric, hemic and sapric peat using the Campbell (1974) equation employed in CLASS, and the van Genuchten (1980) formulation. There is little difference in modelled soil moisture between the two formulations within the range of conditions normally found in peatlands. Validation of modelled water table depth and peat temperature is performed for a fen in northern Québec and a bog in north‐central Minnesota. The new parametrization results in a more realistic simulation of these variables in peatlands than the previous version of CLASS, in which unrealistic mineral soil “equivalents “ were used for wetland soil climate modelling.  相似文献   
472.
Fluvial systems and their preserved stratigraphic expression as the fill of evolving basins are controlled by multiple factors, which can vary both spatially and temporally, including prevailing climate, sediment provenance, localized changes in the rates of creation and infill of accommodation in response to subsidence, and diversion by surface topographic features. In basins that develop in response to halokinesis, mobilized salt tends to be displaced by sediment loading to create a series of rapidly subsiding mini‐basins, each separated by growing salt walls. The style and pattern of fluvial sedimentation governs the rate at which accommodation becomes filled, whereas the rate of growth of basin‐bounding salt walls governs whether an emergent surface topography will develop that has the potential to divert and modify fluvial drainage pathways and thereby dictate the resultant fluvial stratigraphic architecture. Discerning the relative roles played by halokinesis and other factors, such as climate‐driven variations in the rate and style of sediment supply, is far from straightforward. Diverse stratigraphic architectures present in temporally equivalent, neighbouring salt‐walled mini‐basins demonstrate the effectiveness of topographically elevated salt walls as agents that partition and guide fluvial pathways, and thereby control the loci of accumulation of fluvial successions in evolving mini‐basins: drainage pathways can be focused into a single mini‐basin to preserve a sand‐prone fill style, whilst leaving adjoining basins relatively sand‐starved. By contrast, over the evolutionary history of a suite of salt‐walled mini‐basins, region‐wide changes in fluvial style can be shown to have been driven by changes in palaeoclimate and sediment‐delivery style. The Triassic Moenkopi Formation of the south‐western USA represents the preserved expression of a dryland fluvial system that accumulated across a broad, low‐relief alluvial plain, in a regressive continental to paralic setting. Within south‐eastern Utah, the Moenkopi Formation accumulated in a series of actively subsiding salt‐walled mini‐basins, ongoing evolution of which exerted a significant control on the style of drainage and resultant pattern of stratigraphic accumulation. Drainage pathways developed axial (parallel) to salt walls, resulting in compartmentalized accumulation of strata whereby neighbouring mini‐basins record significant variations in sedimentary style at the same stratigraphic level. Despite the complexities created by halokinetic controls, the signature of climate‐driven sediment delivery can be deciphered from the preserved succession by comparison with the stratigraphic expression of part of the system that accumulated beyond the influence of halokinesis, and this approach can be used to demonstrate regional variations in climate‐controlled styles of sediment delivery.  相似文献   
473.
Trace and minor elements in sphalerite from metamorphosed sulphide deposits   总被引:1,自引:0,他引:1  
Sphalerite is a common sulphide and is the dominant ore mineral in Zn-Pb sulphide deposits. Precise determination of minor and trace element concentrations in sulphides, including sphalerite, by Laser-Ablation Inductively-Coupled-Plasma Mass-Spectrometry (LA-ICP-MS) is a potentially valuable petrogenetic tool. In this study, LA-ICP-MS is used to analyse 19 sphalerite samples from metamorphosed, sphalerite-bearing volcanic-associated and sedimentary exhalative massive sulphide deposits in Norway and Australia. The distributions of Mn, Fe, Co, Cu, Ga, Se, Ag, Cd, In, Sn, Sb, Hg, Tl, Pb and Bi are addressed with emphasis on how concentrations of these elements vary with metamorphic grade of the deposit and the extent of sulphide recrystallization. Results show that the concentrations of a group of trace elements which are believed to be present in sphalerite as micro- to nano-scale inclusions (Pb, Bi, and to some degree Cu and Ag) diminish with increasing metamorphic grade. This is interpreted as due to release of these elements during sphalerite recrystallization and subsequent remobilization to form discrete minerals elsewhere. The concentrations of lattice-bound elements (Mn, Fe, Cd, In and Hg) show no correlation with metamorphic grade. Primary metal sources, physico-chemical conditions during initial deposition, and element partitioning between sphalerite and co-existing sulphides are dominant in defining the concentrations of these elements and they appear to be readily re-incorporated into recrystallized sphalerite, offering potential insights into ore genesis. Given that sphalerite accommodates a variety of trace elements that can be precisely determined by contemporary microanalytical techniques, the mineral has considerable potential as a geothermometer, providing that element partitioning between sphalerite and coexisting minerals (galena, chalcopyrite etc.) can be quantified in samples for which the crystallization temperature can be independently constrained.  相似文献   
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