Reduction of nitrogen compounds in oceanic basement and its implications for HCN formation and abiotic organic synthesis     

Nils G Holm  Anna Neubeck 《Geochemical transactions》2009,10(1):9-11

Hydrogen cyanide is an excellent organic reagent and is central to most of the reaction pathways leading to abiotic formation of simple organic compounds containing nitrogen, such as amino acids, purines and pyrimidines. Reduced carbon and nitrogen precursor compounds for the synthesis of HCN may be formed under off-axis hydrothermal conditions in oceanic lithosphere in the presence of native Fe and Ni and are adsorbed on authigenic layer silicates and zeolites. The native metals as well as the molecular hydrogen reducing CO₂ to CO/CH₄ and NO₃ ^-/NO₂ ^- to NH₃/NH₄ ⁺ are a result of serpentinization of mafic rocks. Oceanic plates are conveyor belts of reduced carbon and nitrogen compounds from the off-axis hydrothermal environments to the subduction zones, where compaction, dehydration, desiccation and diagenetic reactions affect the organic precursors. CO/CH₄ and NH₃/NH₄ ⁺ in fluids distilled out of layer silicates and zeolites in the subducting plate at an early stage of subduction will react upon heating and form HCN, which is then available for further organic reactions to, for instance, carbohydrates, nucleosides or even nucleotides, under alkaline conditions in hydrated mantle rocks of the overriding plate. Convergent margins in the initial phase of subduction must, therefore, be considered the most potent sites for prebiotic reactions on Earth. This means that origin of life processes are, perhaps, only possible on planets where some kind of plate tectonics occur.  相似文献   

Influence of reversing currents on the erosion stability and bed degradation of widely graded grain material   总被引：1，自引：1，他引：0  

Alexander Schendel  Nils Goseberg  Torsten Schlurmann 《国际泥沙研究》2018,33(1):68-83

Physical model tests were done in a recirculating flume to investigate the overall erosion stability of widely graded bed material in estuarine and coastal conditions by means of simulating tidal flow conditions with reversing currents. As a result of the reversing flow conditions, previously protected sediment eventually became exposed again, leading to bidirectional displacement processes depending on the flow direction. Furthermore, eroded sediment fractions were slightly finer due to flow in the initially applied direction rather than under the subsequently applied flow in the reverse direction. This indicates higher critical shear stresses, and, thus, erosion stability for the initial flow direction. In comparison to the erosional pattern found when subjecting the material to unidirectional currents, this study finds an even higher erosional stability for sediment fractions smaller than the median (d₅₀) diameter of the parent bed material under reversing current conditions. Overall, no significant damage or failure of the bed was observed after subjecting the material to reversing currents, indicating only a small amount of bed degradation, and, thus, high potential for scour and bed protection under the tested flow conditions.  相似文献   

Geomorphic controls on floodplain sediment and soil organic carbon storage in a Scottish mountain river     

Ward Swinnen  Teun Daniëls  Eline Maurer  Nils Broothaerts  Gert Verstraeten 《地球表面变化过程与地形》2020,45(1):207-223

River floodplains constitute an important element in the terrestrial sediment and organic carbon cycle and store variable amounts of carbon and sediment depending on a complex interplay of internal and external driving forces. Quantifying the storage in floodplains is crucial to understand their role in the sediment and carbon cascades. Unfortunately, quantitative data on floodplain storage are limited, especially at larger spatial scales. Rivers in the Scottish Highlands can provide a special case to study alluvial sediment and carbon dynamics because of the dominance of peatlands throughout the landscape, but the alluvial history of the region remains poorly understood. In this study, the floodplain sediment and soil organic carbon storage is quantified for the mountainous headwaters of the River Dee in eastern Scotland (663 km²), based on a coring dataset of 78 floodplain cross-sections. Whereas the mineral sediment storage is dominated by wandering gravel-bed river sections, most of the soil organic carbon storage can be found in anastomosing and meandering sections. The total storage for the Upper Dee catchment can be estimated at 5.2 Mt or 2306.5 Mg ha^-1 of mineral sediment and 0.7 Mt or 323.3 Mg C ha^-1 of soil organic carbon, which is in line with other studies on temperate river systems. Statistical analysis indicates that the storage is mostly related to the floodplain slope and the geomorphic floodplain type, which incorporates the characteristic stream power, channel morphology and the deposit type. Mapping of the geomorphic floodplain type using a simple classification scheme shows to be a powerful tool in studying the total storage and local variability of mineral sediment and soil organic carbon in floodplains. © 2019 John Wiley & Sons, Ltd.  相似文献   

Characterizing Non-Industrial Private Forest Landowners' Forest Management Engagement and Advice Sources     

Morgan A. Crowley  Joel Hartter  Russell G. Congalton  Lawrence C. Hamilton  Nils D. Christoffersen 《社会与自然资源》2019,32(2):204-221

Non-industrial private forestland (NIPF) owners have options for engagement by following management strategies that reduce wildfire risk on their forestlands. Forest management engagement is a broad term with underlying categories and management implications. To better understand these categories, we examine interview data on the engagement of forest landowners from a case study of private forestland owner perspectives in northeast Oregon, USA. NIPF landowners outline two types of forest management engagement, one for property and one for community-focused forestland management. NIPF owners describe actions for engagement in public forestland management and how these actions differ from engagement in private management. Additionally, NIPF owners establish barriers to engagement in both public and private forestland management. Our findings can be used to better identify unengaged private forestland owners in the U.S. West, informing the design and implementation of extension and outreach for NIPF owners.  相似文献   

Where could catch shares prevent stock collapse?     

Florian K. Diekert  Anne Maria Eikeset  Nils Chr. Stenseth 《Marine Policy》2010

In a widely received study Costello and his colleagues found that catch shares give better stock persistence and higher catch for fishermen. The conclusions made by Costello et al. were further supported by Grafton and McIlgorm where they suggested a framework in order to determine the costs and benefits of separate ITQ management in seven Australian commonwealth fisheries, and what the alternatives should be if the net benefits do not justify ITQs. This raises the question why we do not see catch shares being used more often. We explore at a global scale which countries would have the potential to, and indeed do, fulfil the conditions necessary to implement such a management strategy.  相似文献   

The transmission of mass and angular momentum from a satellite or planetary system to its primary     

Nils Aall Barricelli 《Astrophysics and Space Science》1972,15(3):479-501

In this paper main implication of basic properties detected in the satellite systems of Jupiter, Saturn and Uranus, and presented by the author in an earlier contribution (Barricelli, 1971b) are investigated. The similarity between the primary periods in the three systems, their apparent relation to the axial rotation periods of the three planets and other features suggesting that collisions with the planetary surfaces may have played a role in the evolution of the three satellite systems are interpreted by assuming that in each case a satellite of unusually large size was originally disintegrated at the Roche limit of its primary. The disintegration of large satellites and their fusion with the respective planets is assumed to be a normal feature in the latest stage of planetary growth and the main cause of axial rotation in the respective planets.These assumptions make it possible to give a selfconsistent interpretation of the similarity between the axial rotation periods of the three planets and their relation to the primary periods (as defined by Barricelli, 1971b) in the three systems.Similar assumptions when applied to the Earth-Moon system make it possible to understand why the Moon, in its closest approach to the Earth is found to have been almost exactly at the Roche limit (Gerstenkorn, 1955; MacDonald, 1964), a coincidence which is too good to be accidental. According to this interpretation our Moon is a portion (representing about one third) of our original satellite, which survived its approach to the Roche limit and the ensuing fusion process with the Earth. It can be shown (see text) that under certain conditions this could leave a residual satellite with a stationary distance from the Earth (which in retrospect would be identified as its lowest distance from the Earth) at the Roche limit.The only other case in which we have observational evidence of parts of a satellite surviving its fusion process at the Roche limit is represented by the rings of Saturn and possibly the small innermost satellite Janus which seems to have been feeding on the rings.  相似文献   

The axial rotation of planets and transfer of mass and angular momentum from a satellite system to its primary     

Nils Aall Barricelli 《Earth, Moon, and Planets》1988,41(1):1-43

The main topic of this paper is to investigate the exchange of mass and angular momentum between a satellite or planetary system and its primary, and the effects of this exchange to axial rotations and satellite orbits. Various applications on the calculation of axial rotations, present and past satellite masses and orbits and other implications of the theory are presented.  相似文献   

Equilibrium and structural studies of silicon(IV) and aluminium(III) in aqueous solution. II. Formation constants for the monosilicate ions SiO(OH)3− and SiO2(OH)22−. A precision study at 25°C in a simplified seawater medium     

Staffan Sjöberg  Agneta Nordin  Nils Ingri 《Marine Chemistry》1981,10(6):521-532

The hydrolysis of silicic acid, Si(OH)₄, was studied in a simplified seawater medium (0.6 M Na(Cl)) at 25°C. The measurements were performed as potentiometric titrations (hydrogen electrode) in which OH^? was generated coulometrically. The total concentration of Si(OH)₄, B, and log[H⁺] were varied within the limits 0.00075 ? B ? 0.008 M and 2.5 ? -log[H⁺] ? 11.7, respectively. Within these ranges the formation of SiO(OH)₃^? and SiO₂(OH)₂^2? with formation constants log β_?11(Si(OH)₄ ? SiO(OH)₃^? + H⁺) = ?9.472 ±0.002 and log β_?21(Si(OH)₄ ? SiO₂(OH)₂^2? + 2H⁺) = ?22.07 ± 0.01 was established. With B > 0.003 M polysilicate complexes are formed, however, with $\text{-}\text{log[H}{}^{\mathrm{+}}\text{] ? 10.7}$ their formation does not significantly affect the evaluated formation constants. Data were analyzed with the least squares computer program LETAGROPVRID.  相似文献   

Equilibrium and structural studies of silicon(IV) and aluminium(III) in aqueous solution. II. Formation constants for the monosilicate ions SiO(OH)₃ and SiO₂(OH)₂. A precision study at 25°C in a simplified seawater medium     

Staffan Sjberg  Agneta Nordin  Nils Ingri 《Marine Chemistry》1981,10(6)

The hydrolysis of silicic acid, Si(OH)₄, was studied in a simplified seawater medium (0.6 M Na(Cl)) at 25°C. The measurements were performed as potentiometric titrations (hydrogen electrode) in which OH⁻ was generated coulometrically. The total concentration of Si(OH)₄, B, and log[H⁺] were varied within the limits 0.00075 B 0.008 M and 2.5 -log[H⁺] 11.7, respectively. Within these ranges the formation of SiO(OH)₃⁻ and SiO₂(OH)₂²⁻ with formation constants log β₋₁₁(Si(OH)₄ SiO(OH)₃⁻ + H⁺) = −9.472 ±0.002 and log β₋₂₁(Si(OH)₄ SiO₂(OH)₂²⁻ + 2H⁺) = −22.07 ± 0.01 was established. With B > 0.003 M polysilicate complexes are formed, however, with -log[H⁺] 10.7 their formation does not significantly affect the evaluated formation constants. Data were analyzed with the least squares computer program LETAGROPVRID.  相似文献   

Environmental responses to Lateglacial climatic fluctuations recorded in the sediments of pre‐Alpine Lake Mondsee (northeastern Alps)     

Stefan Lauterbach  Achim Brauer  Nils Andersen  Dan L. Danielopol  Peter Dulski  Matthias Hüls  Krystyna Milecka  Tadeusz Namiotko  Milena Obremska  Ulrich Von Grafenstein  Declakes Participants 《第四纪科学杂志》2011,26(3):253-267

Investigation of the sedimentary record of pre‐Alpine Lake Mondsee (Upper Austria) focused on the environmental reaction to rapid Lateglacial climatic changes. Results of this study reveal complex proxy responses that are variable in time and influenced by the long‐term evolution of the lake and its catchment. A new field sampling approach facilitated continuous and precisely controlled parallel sampling at decadal to sub‐annual resolution for µ‐XRF element scanning, carbon geochemistry, stable isotope measurements on ostracods, pollen analyses and large‐scale thin sections for microfacies analysis. The Holocene chronology is established through microscopic varve counting and supported by accelerator mass spectrometry ¹⁴C dating of terrestrial plant macrofossils, whereas the Lateglacial age model is based on δ¹⁸O wiggle matching with the Greenland NGRIP record, using the GICC05 chronology. Microfacies analysis enables the detection of subtle sedimentological changes, proving that depositional processes even in rather large lake systems are highly sensitive to climate forcing. Comparing periods of major warming at the onset of the Lateglacial and Holocene and of major cooling at the onset of the Younger Dryas reveals differences in proxy responses, reflecting threshold effects and ecosystem inertia. Temperature increase, vegetation recovery, decrease of detrital flux and intensification of biochemical calcite precipitation at the onset of the Holocene took place with only decadal leads and lags over a ca. 100 a period, whereas the spread of woodlands and the reduction of detrital flux lagged the warming at the onset of the Lateglacial Interstadial by ca. 500–750 a. Cooling at the onset of the Younger Dryas is reflected by the simultaneous reaction of δ¹⁸O and vegetation, but sedimentological changes (reduction of endogenic calcite content, increase in detrital flux) were delayed by about 150–300 a. Three short‐term Lateglacial cold intervals, corresponding to Greenland isotope substages GI‐1d, GI‐1c2 and GI‐1b, also show complex proxy responses that vary in time. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献