Characterization of alkanes, hopanes, and polycyclic aromatic hydrocarbons (PAHs) in tar-balls collected from the East Coast of Peninsular Malaysia   总被引：1，自引：0，他引：1  

Chandru K  Zakaria MP  Anita S  Shahbazi A  Sakari M  Bahry PS  Mohamed CA 《Marine pollution bulletin》2008,56(5):950-962

The East Coast of Peninsular Malaysia faces the South China Sea and is vulnerable to oil pollution because of intense petroleum production activities in the area. The South China Sea is also a favored route for supertankers carrying crude oil to the Far East. Consequently, oil spills can occur, causing pollution and contamination in the surrounding areas. Residual oil spills stranded on coastal beaches usually end up as tar-balls. Elucidating the sources of tar-balls using a molecular marker approach is essential in assessing environmental impacts and perhaps settling legal liabilities for affected parties. This study utilizes a multimodal molecular marker approach through the use of diagnostic ratios of alkanes, hopanes, and polycyclic aromatic hydrocarbons (PAHs) to determine the source, distribution and weathering of tar-balls. Hopane ratios (e.g., C29/C30, and summation C31-C35/C30 ratios) were used to identify the sources of tar-balls. The weathering effects were distinguished by using alkanes, namely the unresolved complex mixture (UCM) and low molecular weight/high molecular weight (L/H) ratios. Similarly, PAHs were also used for the determination of weathering processes undergone by the tar-balls. This multimodal molecular marker gave a very strong indication of the sources of tar-balls in this study. For example, 16 out of 17 samples originated from South East Asian Crude Oil (SEACO) with one sample from Merang, Terengganu originating from North Sea Oil (Troll). The TRME-2 sample may have come from a supertanker's ballast water discharge. The second possibility is that the tar-ball may have been transported via oceanographic currents. All 'weathered' sample characterizations were based on the presence of UCM and other ratios. The multimodal molecular marker approach applied in this study has enabled us to partially understand the transport behavior of tar-balls in the marine environment and has revealed insights into the weathering process of tar-balls.  相似文献   

High‐frequency streamflow acquisition and bed level/flow angle estimates in a mountainous river using shallow‐water acoustic tomography          下载免费PDF全文

Kiyosi Kawanisi  Masoud Bahrainimotlagh  Mohamad Basel Al Sawaf  Mahdi Razaz 《水文研究》2016,30(13):2247-2254

The acquisition of reliable discharge estimates is crucial in hydrological studies. This study demonstrates a promising acoustic method for measuring streamflow at high sampling rate for a long period using the fluvial acoustic tomography system (FATS). The FATS recently emerged as an innovative technique for continuous measurements of streamflow. In contrast to the traditional point/transect measurements of discharge, the FATS enables the depth‐averaged and range‐averaged flow velocity along the ray path to be measured in a fraction of a second. The field test was conducted in a shallow gravel‐bed river (0.9 m deep under low‐flow conditions, 115 m wide) for 1 month. The parameters (stream direction and bottom elevation) required for calculating the streamflow were deduced by a nonlinear regression to the discharge data from the well‐established rating curve. The cross‐sectional average velocities were automatically calculated from the acoustic data, which were collected on both riverbanks every 30 s. The FATS was connected to the internet so that the real‐time flow data could be obtained. The FATS captured discharge variations at a cut‐off frequency of approximately 70 day^?1. The stream exhibited temporal discharge changes at multiple time scales ranging from a few tens of minutes to days. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Ionic liquid as a medium to remove iron and other metal ions: a case study of the North Kelantan Aquifer,Malaysia   总被引：1，自引：1，他引：0  

Nur Hayati Hussin  Ismail Yusoff  Yatimah Alias  Sharifah Mohamad  Nurul Yani Rahim  Muhammad Aqeel Ashraf 《Environmental Earth Sciences》2014,71(5):2105-2113

An alternative iron removal treatment method using liquid-liquid extraction with the room-temperature ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, as a solvent medium was studied. The chelating agent 1,10-phenanthroline was used as the extractant. The extraction of Fe(III) and Fe(II) was influenced significantly by the pH of the aqueous phase. The successful removal of iron was achieved; more than 95 % of the initial iron concentration was removed from the groundwater samples. However, detailed research is needed before the ionic liquid method can replace the conventional groundwater treatment protocol because the recovery rate was very low upon reuse (approximately 25–60 %). This low recovery was due to the ion exchange process; the appearance of anions from ionic liquids was also detected in groundwater samples.  相似文献   

Composition of selected heavy metals in road dust from Kuala Lumpur city centre   总被引：1，自引：1，他引：0  

Nur Mun’im Mohd Han  Mohd Talib Latif  Murnira Othman  Doreena Dominick  Noorlin Mohamad  Hafizan Juahir  Norhayati Mohd Tahir 《Environmental Earth Sciences》2014,72(3):849-859

This study was carried out in order to determine the concentration of heavy metals, e.g., lead (Pb), cadmium (Cd), copper (Cu), zinc (Zn), iron (Fe), manganese (Mn), nickel (Ni) and chromium (Cr) in road dust in Kuala Lumpur’s city centre. Samples were collected from four sampling locations, each of which had four sampling points and three replications. Heavy metals from different fractions of particles separated by different diameter sizes: d < 63 μm (Fraction A), 63 < d < 125 μm (Fraction B) and 125 < d < 250 μm (Fraction C) were analyzed using inductively coupled plasma mass spectrometry. The results from this study showed that concentration of heavy metals was dominated by the smallest particle size: <63 μm and that Fe was the most abundant heavy metal overall, followed by Cu > Mn > Zn > Pb > Ni > Cr > Cd. The fact that Cd had the highest enrichment factor value (EF) for all particle sizes indicates that anthropogenic activities contributed to the presence of this metal. There was also a higher EF value for heavy metals in small particle (Fraction A), compared to Fraction B and C, which suggests that fine particles were being produced through anthropogenic activities. Cluster analysis and principal component analysis demonstrated the likelihood of the heavy metals detected in the road dust, originating from road traffic and industrial activities.  相似文献   

Particle tracking analysis of river–aquifer interaction via bank infiltration techniques     

Mohd Khairul Nizar Shamsuddin  Saim Suratman  Mohamad Pauzi Zakaria  Ahmad Zaharin Aris  Wan Nor Azmin Sulaiman 《Environmental Earth Sciences》2014,72(8):3129-3142

Induced bank infiltration (BI) is commonly implemented in other countries, but remains new and unexplored in Malaysia. Increasing river pollution could affect drinking water resources. Given the threat of pollution to raw water sources, applying induced BI to sustain water management is essential. This paper presents a case study of the BI method, which evaluates the effects of groundwater pumping and BI operation on the installation of wells as well as determines the effect of pumping rate on flow paths, travel time, the size of the pumping and capture zone delineation, and groundwater mixing in a pumping well in Jenderam Hilir, Malaysia. The proposed method performs infiltration safely and achieves the ideal pumping rate. Numerical modeling packages, MODFLOW and MODPATH (particle tracking) were used. Results indicate that the migration of river water into the aquifer is generally slow and depends on the pumping rate and distance from well to the river. Most water arrives at the well by the end of a pumping period of 1–5 days at 3,072 m³/day for test wells DW1 and DW2, and during simultaneous pumping for DW2 and PW1 for a well located 36 and 18 m, respectively, from the river. During the 9.7-day pumping period, 33 % of the water pumped from the DW1 well was river water, and 38 % from DW2 throughout 4.6 days was river water. The models provide necessary information for water operators in the design and construction of pumping and sampling schedules of BI practices.  相似文献   

Elemental hydrochemistry assessment on its variation and quality status in Langat River, Western Peninsular Malaysia     

Wan Ying Lim  Ahmad Zaharin Aris  Tengku Hanidza Tengku Ismail  Mohamad Pauzi Zakaria 《Environmental Earth Sciences》2013,70(3):993-1004

This paper discusses the hydrochemistry variation and its quality status in Langat River, based on the chemistry of major ions, metal concentrations and suitability for drinking purposes. Water samples were collected from 30 different stations to assess their hydrochemical characteristics. The physico-chemical parameters selected were temperature, electrical conductivity, total dissolved solids (TDS), salinity, dissolved oxygen , pH, redox potential, HCO₃, Cl, SO₄, NO₃, Ca, Na, K, Mg, ²⁷Al, ¹³⁸Ba, ⁹Be, ¹¹¹Cd, ⁵⁹Co, ⁶³Cu, ⁵²Cr, ⁵⁷Fe, ⁵⁵Mn, ⁶⁰Ni, ²⁰⁸Pb, ⁸⁰Se and ⁶⁶Zn to investigate the variation of the constituents in the river water. Most of the parameters comply with the Drinking Water Quality Standard of the World Health Organization and the Malaysian National Standard for Drinking Water Quality by the Malaysia Ministry of Health except for EC, TDS, Cl, HCO₃, SO₄, Na, Mg, Al, Fe and Se. The results show that the Langat River is unsuitable for drinking purposes directly without treatment.  相似文献   

Distribution, classification, petrological and related gochemical (SRA) characteristics of a tropical lowland peat dome in the Kota Samarahan-Asajaya area, West Sarawak, Malaysia     

Mohamad Tarmizi Mohamad Zulkifley  Ng Tham Fatt  Wan Hasiah Abdullah  John Kuna Raj  S. Paramanathan Param  Roslan Hashim  Muhammad Aqeel Ashraf 《Central European Journal of Geosciences》2013,5(2):285-314

Petrographic studies indicate that lateral variations in the decomposition levels of peat are associated with the predominantly occurring peat macerals. Source Rock Analyzer (SRA) results indicate lateral variation in peat organic matter types from type II to III and back again to type II, occurring laterally within the top 0-m to 0.5-m layer at the basin margin to the midsection and further towards the near-center areas of the peat dome. This variation is most likely caused by a combination of factors: (a) Horizontal zonation and lateral variation of the dominant species of plant assemblages (b) Fibric (marginal) peats and hemic to sapric peats associated with type II organic matter (kerogen). Sample organic matter (coal-equivalent kerogen) typing indicates that the relative abundance of phytoclasts and palynomorphs generally supports the organic matter classification obtained by the SRA method. Lateral variations in the peat organic matter types may support the lateral vegetation variation concept. The classification of peat organic matter types (interpreted from visual analyses of palynological slides) occurring from the basin periphery to the mid-section and further towards the basin center yields organic matter of type II to type III and mixed types II to III (coal kerogen-equivalent), respectively.  相似文献   

A typical weathering profile of granitic rock in Johor,Malaysia based on joint characterization     

Alavi Nezhad Khalil Abad  S. V.  Mohamad  Edy Tonnizam  Komoo  Ibrahim  Kalatehjari  R. 《Arabian Journal of Geosciences》2015,8(4):2191-2201

Arabian Journal of Geosciences - One of the most important challenges in the study of slope stability, foundation, and excavation in rocks is understanding the weathering states. This issue is more...  相似文献   

The effect of biological operating system on capture of organic carbon in soil and plant     

Shahin Aghamirzadeh  Ali Reza Solimani  Yahya Parvizi  Najme Soleymani  Mohamad Navid Naghibi 《Arabian Journal of Geosciences》2015,8(12):10887-10892

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The effects of climate sensitivity and carbon cycle interactions on mitigation policy stringency     

Katherine Calvin  Ben Bond-Lamberty  James Edmonds  Mohamad Hejazi  Stephanie Waldhoff  Marshall Wise  Yuyu Zhou 《Climatic change》2015,131(1):35-50

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