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581.
D.G. Pearson S.B. Shirey J.W. Harris R.W. Carlson 《Earth and Planetary Science Letters》1998,160(3-4):311-326
Re–Os isotope compositions of syngenetic sulphide inclusions in both eclogite suite (E-type) and peridotite suite (P-type) parageneses in diamonds from the Koffiefontein mine, South Africa have been analysed using a technique capable of analysing single inclusion grains, or, in some cases multiple inclusions from the same diamonds. Sulphide inclusion Ni contents broadly correlate with Os abundances in that low-Ni (6.8–8.7% Ni), E-type sulphides have 4.7 to 189 ppb Os whereas the two high-Ni (25%), P-type sulphides have 5986 and 6097 ppb Os. Two P-type sulphides from the same diamond define the first mineral isochron obtained for a single diamond which has an age of 69±30 Ma with chondritic initial 187Os/188Os. This indicates that the sulphides, and hence the host diamond, crystallised close to the time of kimberlite emplacement (90 Ma), in the Mesozoic. This is supported by Pb isotopic measurements of a fragment from one of the sulphides, together with the absence of significant Type IaB nitrogen aggregation in the host diamond lattice. E-type sulphide inclusions have radiogenic Os isotopic compositions, 187Os/188Os 0.346 to 2.28, and Re–Os model ages from 1.1 to 2.9 Ga. They define an array on a Re–Os isochron diagram that may be interpreted as defining a single period of E-type sulphide growth at 1.05±0.12 Ga, with an elevated initial 187Os/188Os. Alternatively, two episodes of sulphide crystallisation, from a chondritic reservoir, may be invoked in the Archaean and in the Proterozoic. The results for both P- and E-type diamonds point to a spectrum of diamond crystallisation ages. High contents of both Re and Os, and the similarity of Re/Os ratios of sulphide inclusions in diamonds to whole rock eclogite and peridotite xenoliths indicate that small amounts of sulphides can dominate the mantle budget of both these elements during melting. Recent addition to the lithospheric mantle of high-Os material similar to that from which the P-type sulphides crystallised may explain the variable, sometimes young Os model ages seen in whole rock xenolith Re–Os data. 相似文献
582.
Melting and metasomatism in the continental lithosphere: laser ablation ICPMS analysis of minerals in spinel lherzolites from eastern Australia 总被引:28,自引:0,他引:28
Marc D. Norman 《Contributions to Mineralogy and Petrology》1998,130(3-4):240-255
Olivine, low-Ca pyroxene, diopside, and spinel from a suite of protogranular lherzolite xenoliths from southeastern Australia
have been analysed for their major and trace element compositions using electron microprobe and laser ablation ICPMS. Bulk
compositions of the lherzolites range from fertile (12–13% modal diopside) to depleted (2–3% modal diopside), with equilibration
temperatures of 850–900 °C indicating entrainment of these lherzolites from relatively shallow depths (probably ≤ 35 km) within
the lithosphere. Mineral compositions and abundances indicate a primary control by partial melting, with decreasing abundance
of modal diopside accompanied by increasing Mg# of olivine and pyroxene, decreasing Al and Ti contents of diopside, increasing
Ni contents of olivine, and increasing Cr/Al of spinel. HREE, Y, and Ga in diopside also follow melting trends, decreasing
in concentration with increasing Mg#. In contrast, highly incompatible elements such as LREE, Nb, and Th reveal divergent
behaviour that cannot be ascribed entirely to partial melting. Diopsides from the fertile lherzolites have mantle-normalized
patterns that are depleted in Th, Nb, and the LREE relative to Y and the HREE, whereas, diopsides from the cpx-poor samples
are strongly enriched in Th, Nb and the LREE, and have elevated Sm/Hf and Zr/Hf, and low Ti/Nb. All diopsides have strongly
negative Nb anomalies relative to Th and the LREE. Trace element patterns of diopside in the fertile lherzolites can be reproduced
by ≤ 5% batch melting of a primitive source. The negative Nb anomalies are a consequence of this melting, and do not require
special conditions or tectonic environments. The low concentrations of Y and HREE in diopside from the cpx-poor lherzolites
cannot be produced by realistic degrees of batch melting, but can be accomplished by up to ∼20% fractional melting, suggesting
multiple episodes of melt depletion. Os isotopic compositions of these lherzolites show that the melt depletion events occurred
in the middle and late Proterozoic, demonstrating the long-term stability of lithospheric mantle beneath regions of eastern
Australia. The LREE-enriched diopsides are well equilibrated and record metasomatic enrichment events that pre-date the magmatism
that entrained these xenoliths. Trace element patterns of these pyroxenes suggest a carbonatitic melt as the metasomatic agent.
Received: 24 September 1996 / Accepted: 12 August 1997 相似文献
583.
Norman Kerle 《地球表面变化过程与地形》2002,27(7):759-772
In October 1998 a precipitation‐triggered flank collapse occurred at Casita volcano, Nicaragua, leading to a devastating lahar. In this paper the failure volume was calculated using a range of methods. Several pre‐ and post‐failure digital elevation models (DEMs) were created, based on photogrammetric, cartometric and surveying data. The wide range in resulting volumes prompted an assessment of the accuracies and potential problems associated with each of the datasets and techniques used. The best estimate for the failure volume is 1·6 × 106 m3. It is based on a vegetation‐corrected pre‐failure DEM, generated using automated digital photogrammetry, and a post‐failure surface based on a field survey carried out with a Total Station. The volume figure is approximately an order of magnitude higher than values reported in previous publications, all of which are based solely on field estimates. This demonstrates that values reported in the literature, if they are not based on rigorous quantitative analysis, must be regarded with caution. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
584.
585.
David W. Muenow Diana G. Graham Norman W.K. Liu John R. Delaney 《Earth and Planetary Science Letters》1979,42(1):71-76
High-temperature mass spectrometric studies have been made to determine the distribution of volatiles within glassy rims of submarine pillow basalts dredged from the east rift zone of Kilauea volcano, Hawaii. The CO2/H2O mole ratio for glass-vapor inclusions within olivine phenocrysts in the glassy rims is greater than 30 : 1 compared to 0.06 for matrix glasses. Enclosing matrix glasses contain 0.53–0.74 wt.% H2O, 0.02–0.04 wt.% carbon, 0.08–0.12 wt.% sulfur, 0.012–0.028 wt.% chlorine and 0.012–0.077 wt.% fluorine. 相似文献
586.
High temperature mass spectrometric analyses of glasses from quenched pillow rims of andesites dredged from 1170 m water depth in the northern portion of the Mariana Island arc indicate substantially less H2O (~ 1 wt.%) and more CO2 (~ 0.24 wt.%) than previously reported for volcanic arc rocks. Glass-vapor inclusions within plagioclase phenocrysts from quenched rims have ratios of 1:1. These results are similar to analyses of basaltic samples from the Mariana Trough (a back-arc basin). Generally, F and Cl contents are higher and S lower in the arc rocks compared to the samples from the back-arc basin. These results favor models for the production of island arc magmas which involve melting of the subducted slab, rather than just melting of the overlying mantle wedge because of the high volatile content needed to produce island arc magmas from peridotite (10–15 wt.%). The trough samples, although similar in non-volatile composition to mid-ocean ridge rocks, have much higher H2O. somewhat higher CO2 and lower S contents. Either near surface addition of voiatiles has enriched the magmas or H2O must be a more important component in the generation and evolution of back-arc basin lavas than in the genesis of mid-ocean ridge basalts. 相似文献
587.
Direct measurements on water samples from several CO2-charged warm springs are significantly higher than values calculated from field pH and alkalinity (and other constituents). In addition, calcite saturation indices calculated from field pH and solution composition indicated supersaturation in samples which, on the basis of hydrogeologic concepts, should be near saturation or undersaturated. We attribute these discrepancies to uncertainties in field pH, resulting from CO2 outgassing during pH measurement. Because samples for direct measurement can be taken with minimal disturbance to the water chemistry, we have used the measured to back calculate an estimate of the field pH and the carbon isotopic composition of the water before outgassing. By reconstructing water chemistry in this way, we find generally consistent grouping of , pH, and degree of calcite saturation in samples taken from the same source at different times, an observation which we expect based on our understanding of the hydrogeology and geochemistry of the ground-water systems. This suggests that for very careful geochemical work, particularly on ground-waters much above ambient temperature, measurements may provide more information on the system and a better estimate of its state of saturation with respect to carbonate minerals than can field measurements of pH. 相似文献
588.
589.
Gravel sediment freshly enriched with over 4.4 μg Cu g?1 significantly increased the burrowing and reburrowing times of Littleneck marine clams (Protothaca staminea). Abnormal burrowing behaviour was observed with time-lapse video. Aged (1 day) copper-enriched sediment did not affect clam burrowing time. Copper in sediment porewater declined three days after sediment enrichment to background levels without change in total sediment copper. In a long-term experiment, clams with increased burrowing time into copper-enriched sediment had up to 25% mortality after 12–29 days burial in the sediment. The majority of clam mortality was found in clams burrowing within the first 48 h. Over 7 weeks there was blackening of sediment and clam shells proportional to sediment copper enrichment. 相似文献
590.