Aplitische gänge in graniten und gneisen: F.K. Drescher-Kaden. Walter de Gruyter,Berlin-New York,N.Y., 1974, 214 S., DM 124,00     

Olaf Brockamp 《Chemical Geology》1975,15(4):317-318

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Explorative data analysis of heavy metal contaminated soil using multidimensional spatial regression   总被引：1，自引：0，他引：1  

Ute?SchnabelEmail author  Olaf?Tietje 《Environmental Geology》2003,44(8):893-904

To obtain data on heavy metal contaminated soil requires laborious and time-consuming data sampling and analysis. Not only has the contamination to be measured, but also additional data characterizing the soil and the boundary conditions of the site, such as pH, land use, and soil fertility. For an integrative approach, combining the analysis of spatial distribution, and of factors influencing the contamination, and its treatment, the Mollifier interpolation was used, which is a non-parametric kernel density regression. The Mollifier was capable of including additional independent variables (beyond the spatial dimensions x and y) in the spatial interpolation and hence explored the combined influence of spatial and other variables, such as land use, on the heavy metal distribution. The Mollifier could also represent the interdependence between different heavy metal concentrations and additional site characteristics. Although the uncertainty measure supplied by the Mollifier at first seems somewhat unusual, it is a valuable feature and supplements the geostatistical uncertainty assessment.  相似文献   

Statistical Revision of the Moment Method     

Joris De Ridder  Geert Molenberghs  Conny Aerts 《Astrophysics and Space Science》2003,284(1):125-128

The moment method is a well known technique, which uses a time series ofthe first 3 moments of a spectral line, to estimate the (discrete) modeparameters and m. The method, contrary to Doppler imaging,also yields other interesting(real-valued) parameters such as the inclination angle i, or v sin i,during its identification procedure.In this paper, we are not only interested in the estimation of thesereal-valued parameters themselves but also inreliable estimates for their uncertainty.We designed a statistical formalism for the moment method based on theso-called generalized estimating equations (GEE). This formalismaims to estimate the uncertainty of the real-valued parameters taking intoaccount that the different moments of a line profile are correlated and –more importantly – that the uncertainty of the observed moments depends onthe pulsation parameters. The latter property of the moment method makesthe least-squares technique a poor choice to estimate the uncertainty ofthe real-valued parameters. We implemented the GEE method and presentan application to a high-resolution spectroscopic dataset of the slowly pulsating B star HD181558.  相似文献   

Development and application of a CAD interface for fractured rock   总被引：2，自引：0，他引：2  

Thomas Kalbacher  Wenqing Wang  Chris McDermott  Olaf Kolditz  Takeo Taniguchi 《Environmental Geology》2005,47(7):1017-1027

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A study of the chemistry of pore fluids and authigenic carbonates in methane seep environments: Kodiak Trench, Hydrate Ridge, Monterey Bay, and Eel River Basin   总被引：3，自引：0，他引：3  

Joris Gieskes  Chris Mahn  Shelley Day  Jonathan B. Martin  Jens Greinert  Tony Rathburn  Brian McAdoo 《Chemical Geology》2005,220(3-4):329-345

Analyses of the chemical and isotopic composition of carbonates rocks recovered from methane seepage areas of the Kodiak Trench, Hydrate Ridge, Monterey Bay Clam Flats, and the Eel River Basin, coupled with the studies of the chemistry of the pore fluids, have shown that these carbonates have grown within the sediment column. Geochemical profiles of pore fluids show that, in deep water seeps (Kodiak Trench—4450 m; Monterey Bay—1000 m; Hydrate Ridge—650 m), δ¹³C (DIC) values are low (isotopically light), whereas in the Eel River area ( 350–500 m), δ¹³C (DIC) values are much higher (isotopically heavier). In all cases, the δ¹³C values indicate that processes of methane oxidation, associated with sulfate reduction, are dominant in the shallow sediments. Data on the isotopic composition of authigenic carbonates found at sites in Kodiak Trench, Eel River Basin South, and Eel River Basin North indicate a variable composition and origin in different geochemical environments. Some of the authigenic carbonates from the study sites show a trend in their δ¹³C values similar to those of the pore fluids obtained in their vicinity, suggesting formation at relatively shallow depths, but others indicate formation at greater sediment depths. The latter usually consist of high magnesium calcite or dolomite, which, from their high values of δ¹³C (up to 23‰;) and δ¹⁸O (up to 7.5‰), suggest formation in the deeper horizons of the sediments, in the zone of methanogenesis. These observations are in agreement with observations by other workers at Hydrate Ridge, in Monterey Bay, and in the Eel River Basin.  相似文献   

Predicting catchment sediment yield in Mediterranean environments: the importance of sediment sources and connectivity in Italian drainage basins   总被引：2，自引：0，他引：2  

Joris de Vente  Jean Poesen  Paolo Bazzoffi  Anton Van Rompaey  Gert Verstraeten 《地球表面变化过程与地形》2006,31(8):1017-1034

Predicting sediment yield at the catchment scale is one of the main challenges in geomorphologic research. The application of both physics‐based models and regression models has until now not provided very satisfying results for prediction of sediment yield for medium to large sized catchments (c. >50 km²). The explanation for this lies in a combination of the large data requirements of most models and a lack of knowledge to describe all processes and process interactions at the catchment scale. In particular, point sources of sediment (e.g. gullies, mass movements), connectivity and sediment transport remain difficult to describe in most models. From reservoir sedimentation data of 44 Italian catchments, it appeared that there was a (non‐significant) positive relation between catchment area and sediment yield. This is in contrast to what is generally expected from the theory of decreasing sediment delivery rates with increasing catchment area. Furthermore, this positive relation suggests that processes other than upland erosion are responsible for catchment sediment yield. Here we explore the potential of the Factorial Scoring Model (FSM) and the Pacific Southwest Interagency Committee (PSIAC) model to predict sediment yield, and indicate the most important sediment sources. In these models different factors are used to characterize a drainage basin in terms of sensitivity to erosion and connectivity. In both models an index is calculated that is related to sediment yield. The FSM explained between 36 and 61 per cent of the variation in sediment yield, and the PSIAC model between 57 and 62 per cent, depending on the factors used to characterize the catchments. The FSM model performed best based on a factor to describe gullies, lithology, landslides, catchment shape and vegetation. Topography and catchment area did not explain additional variance. In particular, the addition of the landslide factor resulted in a significantly increased model performance. The FSM and PSIAC model both performed better than a spatially distributed model describing water erosion and sediment transport, which was applied to the same catchments but explained only between 20 and 51 per cent of the variation in sediment yield. Model results confirmed the hypothesis that processes other than upland erosion are probably responsible for sediment yield in the Italian catchments. A promising future development of the models is by the use of detailed spatially distributed data to determine the scores, decrease model subjectivity and provide spatially distributed output. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Ellenbergerite,a new high-pressure Mg-Al-(Ti,Zr)-silicate with a novel structure based on face-sharing octahedra     

Christian Chopin  Rolf Klaska  Olaf Medenbach  Dominique Dron 《Contributions to Mineralogy and Petrology》1986,92(3):316-321

Ellenbergerite occurs as purple millimetre-size grains associated with talc, kyanite, clinochlore, rutile, and zircon in composite inclusions within decimetre-large pyrope crystals (90–98 mole percent end-member) in the quartzite layer of the Dora Maira massif, Western Alps, from which coesite has been recently reported (Chopin 1984). It is hexagonal, a=12.255(8), c=4.932(4) Å, Z=1, space group P6₃. Mohs hardness 6.5; D_mes 3.15, D_cal 3.10; no cleavage. Uniaxial negative and vividly pleochroic, colourless, colourless to deep lilac with colour zoning. The intensely coloured variety has 1.6789(5), 1.670(1); microprobe analysis yields SiO₂ 39.1, P₂O₅ 0.45, Al₂O₃ 25.1, TiO₂ 4.0, MgO 22.2, FeO 0.20, sum 99.05 wt.% including H₂O 8.0 (coulometrically). The formula calculated on a O₂₈(OH)₁₀ basis (implying 7.5 wt.% H₂O) is Mg_6.71 Fe_0.03 Ti_0.61 Al_6.00 Si_7.92 P_0.08 O₂₈(OH)₁₀ The colour zoning is due to nearly complete TiZr substitution. In addition ellenbergerite may contain more than 8 wt.% P₂O₅ with strictly correlated changes of Si, Mg, Al and Ti+Zr contents, over 80% of which represent the SiAlPMg substitution.The structure has been determined from 1049 observed independent reflections and refined to R=0.034, R_w=0.031, including six of ten protons. It consists of single chains of face-sharing octahedra with one third vacancies extending along the six-fold screw axes, and of pairs of fully occupied face-sharing octahedra linked by edge-sharing to form octahedral double chains parallel to the twofold screw axes, all interconnected by SiO₄ tetrahedra. It may be compared with the dumortierite polymorph with space group P6₃mc derived hypothetically by Moore and Araki (1978). The structural formula is (Mg,Ti,Zr,)₂ Mg₆(Al,Mg)₆ (Si,P)₂ Si₆ O₂₈(OH)₁₀ Face-sharing octahedra are an unusual feature in silicates which results in a dense structure and reflects, considering the common bulk composition, the uncommon high-pressure formation conditions (about 25–30 kbar, 700–800° C). Ti⁴⁺-Fe²⁺ charge transfer between face-sharing octahedra on the six-fold screw axes most likely accounts for the absorption scheme.  相似文献   

Particulate iron and manganese in the Santa Barbara Basin,California     

Alan M. Shiller  Joris M. Gieskes  N. Brian Price 《Geochimica et cosmochimica acta》1985,49(5):1239-1249

Particulate Fe and Mn may be important trace metal scavengers in the water column as well as being probable indicators of biologically mediated redox processes. A study has been made of suspended particulate composition in the Santa Barbara Basin, a shallow near-shore basin off southern California with sub-oxic conditions below sill depth. Observations have revealed several interesting phenomena relating to the geochemistry of Fe and Mn. Most striking is a profound enrichment of particulate Fe in samples from the bottom two hundred meters. These particulates have a constant Fe/P mole ratio of about three and may originate at the sediment-water interface or may be transported to the basin from local marshes. For particulate Mn, enrichments are observed both in the sub-sill waters and near the base of the euphotic zone. A consideration of particle removal rates suggests that the sub-photic zone enrichment has a biogenic origin. In the sub-sill waters, enrichment in Mn is apparently due to the precipitation of dissolved Mn diffusing from the anoxic basin sediments. A simple mass balance suggests that most of the Mn lost from the sediments is transported from the Santa Barbara Basin in dissolved form.  相似文献   

Spatial statistical techniques for aggregating point objects extracted from high spatial resolution remotely sensed imagery   总被引：3，自引：0，他引：3  

Trisalyn Nelson  K. Olaf Niemann  Michael A. Wulder 《Journal of Geographical Systems》2002,4(4):423-433

 Using a local maximum filter, individual trees were extracted from a 1 m spatial resolution IKONOS image and represented as points. The spatial pattern of individual trees was determined to represent forest age (a surrogate for forest structure). Point attributes, based on the spatial pattern of trees, were generated via nearest neighbour statistics and used as the basis for aggregating points into forest structure units. The forest structure units allowed for the mapping of a forested area into one of three age categories: young (1–20 years), intermediate (21–120 years), and mature (>120 years). This research indicates a new approach to image processing, where objects generated from the processing of image data (rather than pixels or spectral values) are subjected to spatial statistical analysis to estimate an attribute relating an aspect of forest structure. Received: 22 April 2002 / Accepted: 23 November 2002  相似文献   

Inter-annual and seasonal variations of energy and water vapour fluxes above a Pinus sylvestris forest in the Siberian middle taiga   总被引：2，自引：0，他引：2  

Nadejda M. Tchebakova  Olaf Kolle  Daniil Zolotoukhine  Almut Arneth  Julie M. Styles  Natalia N. Vygodskaya  E.-Detlef Schulze  Olga Shibistova  Jon Lloyd 《Tellus. Series B, Chemical and physical meteorology》2002,54(5):537-551

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