Iron in silicate glasses of granitic composition: a Mössbauer spectroscopic study     

Beate Spiering  Friedrich A. Seifert 《Contributions to Mineralogy and Petrology》1985,90(1):63-73

⁵⁷Fe Mössbauer spectra of natural glasses (pumices and obsidians) and of synthetic glasses of granitic composition have been analyzed. — Ferric iron is found in tetrahedral coordination if enough M⁺-cations are available to balance the charge of both M⁺Fe³⁺O₂ and M⁺AlO₂ complexes. In other compositions the ratio of tetrahedrally to octahedrally coordinated Fe³⁺ depends on the ratio of mono-to divalent cations. — Ferrous iron occurs in two distinctly different octahedral sites. The existence of these sites can be attributed to different anionic units adjacent to Fe²⁺. The degree of polymerization of these units is reflected in the quadrupole splitting. The anionic units adjacent to Fe²⁺ are depolymerized for increasing mean Z/r ² of the network modifiers, which do not stabilize M³⁺ in the tetrahedra by local charge balance. — Increasing pressure diminishes the geometric differences between these types of ferrous iron-oxygen-octahedra, which gives rise to a more even distribution of Fe²⁺ among these sites and thereby to an ordering in the network of melts.  相似文献   

Methoden zur Weltklimatologie der Hydrometeore. Der Anteil des festen Niederschlags am Gesamtniederschlag     

Univ.-Prof. Dr. Friedrich Lauscher 《Theoretical and Applied Climatology》1976,24(3):129-176

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The transformation of amorphous silica to crystalline silica under hydrothermal conditions     

Peter Bettermann  Friedrich Liebau 《Contributions to Mineralogy and Petrology》1975,53(1):25-36

Hydrothermal syntheses were made mainly in the binary system SiO₂-H₂O in a temperature range between 300 ° C and 500 ° C and pressures from 0.2 kbar up to 4.0 kbar with various starting materials. In this way the transformation behavior of different amorphous silicas via cristobalite and keatite to quartz were observed. This behavior depends mainly on the parameters: pressure, temperature, run duration and state of the starting material. Four reaction paths have been observed: in most experiments the complete reaction sequence “amorphous silica→cristobalite→keatite→quartz” took place. Less often the reactions: “amorphous silica→cristobalite→quartz” and: “amorphous silica→keatite→quarts” were observed. Very few samples were found with a direct transition of amorphous silica into quartz at high pressures. A kinetic model is given in form of a pressure-temperature-time diagram of the system SiO₂-H₂O under hydrothermal conditions.  相似文献   

Über einen Keuperton von Zaisersweiher bei Maulbronn     

Dr. Friedrich Lippmann 《Contributions to Mineralogy and Petrology》1954,4(1-2):130-134

Zusammenfassung Durch röntgenographisehe und differentialthermoanalytische Untersuchungen wurde in einem roten Keuperton (km 3) von Zaisersweiher bei Maulbronn ein quellfähiges chloritisches Mineral (Corrensit) als Hauptbestandteil gefunden, das sick durch doppelten Basisabstand (28 Å) auszeichnet. Daneben treten Illit (Glimmer) und Quarz auf. Nebengemengteile sind Hämatit und Feldspat.Herrn Professor Dr.Carl W. Correns zum 60. Geburtstag gewidmet.  相似文献   

Tracking and orbit determination performance of the GRAS instrument on MetOp-A   总被引：8，自引：3，他引：5  

Oliver Montenbruck  Yago Andres  Heike Bock  Tom van Helleputte  Jose van den Ijssel  Marc Loiselet  Christian Marquardt  Pierluigi Silvestrin  Pieter Visser  Yoke Yoon 《GPS Solutions》2008,12(4):289-299

The global navigation satellite system receiver for atmospheric sounding (GRAS) on MetOp-A is the first European GPS receiver providing dual-frequency navigation and occultation measurements from a spaceborne platform on a routine basis. The receiver is based on ESA’s AGGA-2 correlator chip, which implements a high-quality tracking scheme for semi-codeless P(Y) code tracking on the L1 and L2 frequency. Data collected with the zenith antenna on MetOp-A have been used to perform an in-flight characterization of the GRAS instrument with focus on the tracking and navigation performance. Besides an assessment of the receiver noise and systematic measurement errors, the study addresses the precise orbit determination accuracy achievable with the GRAS receiver. A consistency on the 5 cm level is demonstrated for reduced dynamics orbit solutions computed independently by four different agencies and software packages. With purely kinematic solutions, 10 cm accuracy is obtained. As a part of the analysis, an empirical antenna offset correction and preliminary phase center correction map are derived, which notably reduce the carrier phase residuals and improve the consistency of kinematic orbit determination results.

Oliver MontenbruckEmail:

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Sc- and REE-bearing ixiolite and associated minerals from the Sosedka pegmatite vein in the Malkhan pegmatite field, central Transbaikal region     

E. V. Badanina  V. V. Gordienko  A. Wiechowski  G. Friedrich 《Geology of Ore Deposits》2008,50(8):772-781

Composition and localization of REE mineralization in miarolitic pegmatites and its role in the pegmatite formation were studied at the Malkhan gem deposit (jewel-quality tourmaline, morganite, danburite, and hambergite) in the central Transbaikal region. The chemical composition of Ti-, Ta-, Nb- and REE-bearing minerals, their relationships with rock-forming and accessory minerals indicate that two geochemically specialized stages of pegmatite formation are distinguished. The early stage gave rise to the crystallization of quartz-feldspar aggregates including K-feldspar block zone with Sc and REE mineralization. The rare-metal (Li, Cs, F, B, Be) albite-lepidolite-cleavelandite complex with pockets of gem mineralization was formed at the late stage.  相似文献   

The evolution of dark matter halo properties in clusters, filaments, sheets and voids     

Oliver Hahn  C. Marcella Carollo  Cristiano Porciani  Avishai Dekel 《Monthly notices of the Royal Astronomical Society》2007,381(1):41-51

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Mining-Induced Stress Transfer and Its Relation to a \text{M}_w 1.9 Seismic Event in an Ultra-deep South African Gold Mine     

Moritz Ziegler  Karsten Reiter  Oliver Heidbach  Arno Zang  Grzegorz Kwiatek  Dietrich Stromeyer  Torsten Dahm  Georg Dresen  Gerhard Hofmann 《Pure and Applied Geophysics》2015,172(10):2557-2570

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Depth and character of rock weathering across a basaltic‐hosted climosequence on Hawai‘i          下载免费PDF全文

Bradley W. Goodfellow  Oliver A. Chadwick  George E. Hilley 《地球表面变化过程与地形》2014,39(3):381-398

Using field observations and geochemical and digital terrain analyses, we describe the structure and thickness of the regolith across a climosequence on the island of Hawai‘i to gain insight into the relative roles of precipitation and the near‐surface hydrologic structure in determining weathering patterns. In the wet portion of the climosequence, where the long‐term water balance is positive, the regolith thickness reaches an observed maximum of ~40 m and appears limited by the geomorphic base‐level of the landscape. However, even within this thick regolith, distinct units of varying weathering intensity occur; the vertical ordering of which largely reflects differences in the initial permeability structure of the basalt flows rather than a systematic decrease in weathering intensity downwards from the ground surface. In the dry portion of the climosequence, where the long‐term water balance is negative, the regolith thickness is confined to ~1 m, is highly dependent on the inferred permeability structure of the basalt flows, and is independent of geomorphic base‐level. Weathering intensity also varies according to permeability structure and decreases in this thin regolith with distance beneath the ground surface. The abrupt change in regolith depth and character that coincides with the transition from net‐positive to net‐negative long‐term water balance implies that small changes in precipitation rates around a neutral water balance result in large changes in the distribution and depth of weathering. Together our observations indicate that the distribution and depth of weathering in basalts (and probably other lithologies) might be best understood by considering how precipitation interacts with the complicated near‐surface permeability structure over regolith‐forming timescales to weather rock in the vadose zone. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Modelling basin-scale distribution of fish occurrence probability for assessment of flow and habitat conditions in rivers     

Pengzhe Sui  Akito Iwasaki  Oliver C. Saavedra V.  Chihiro Yoshimura 《水文科学杂志》2014,59(3-4):618-628

Abstract

Flow regimes play an important role in sustaining biodiversity in river ecosystems. However, the effects of flow regimes on riverine fish have not been clearly described. Therefore, we propose a new methodology to quantitatively link habitat conditions (such as flow indices and physical habitat conditions) to the occurrence probability (OP) of fish species. We developed a basin-scale fish distribution model by integrating the concept of habitat suitability assessment with a distributed hydrological model in order to estimate the OP of fish, with particular attention to flow regime. A generalized linear model was used to evaluate the relationship between the probabilities of fish occurrence and major environmental factors in river sections. A geomorphology-based hydrological model was adopted to simulate river discharge, which was used to calculate 10 flow indices. The occurrence probabilities of 50 fish species in the Sagami River in Japan were modelled. For the prediction accuracy, field survey results that included at least five observations of both the presence and the absence of each species were required to obtain relatively reliable prediction (accuracy > 60%). Using the developed model, important habitat conditions for each species were identified, which showed the importance of low-flow events for more than 10 species, including Hypomesus nipponensis and Rhinogobius fluviatilis. The model also confirmed the positive effects of natural flow and the negative effect of river-crossing structures, such as dams and weirs, on the OP of most species. The suggested approach enables us to evaluate and project the ecological consequences of water resource management policy. The results demonstrate the applicability of the fish distribution model to provide quantitative information on the flow required to maintain fish communities.