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581.
The Deep Impact flyby spacecraft includes a 1.05 to 4.8 μm infrared (IR) spectrometer. Although ice was not observed on the surface in the impact region, strong absorptions near 3 μm due to water ice are detected in IR measurements of the ejecta from the impact event. Absorptions from water ice occur throughout the IR dataset beginning three seconds after impact through the end of observations, ∼45 min after impact. Spatially and temporally resolved IR spectra of the ejecta are analyzed in conjunction with laboratory impact experiments. The results imply an internal stratigraphy for Tempel 1 consisting of devolatilized materials transitioning to unaltered components at a depth of approximately one meter. At greater depths, which are thermally isolated from the surface, water ice is present. Up to depths of 10 to 20 m, the maximum depths excavated by the impact, these pristine materials consist of very fine grained (∼1±1 μm) water ice particles, which are free from refractory impurities.  相似文献   
582.
The EW-striking Variscan Mérens shear zone (MSZ), located on the southern border of the Aston dome (Pyrenees), corresponds to variously mylonitized gneisses and plutonic rocks that are studied using the Anisotropy of Magnetic Susceptibility (AMS) technique. The plutonic rocks form EW-striking bands with, from south to north, gabbro-diorites, quartz diorites and granodiorites. The MSZ underwent a mylonitic deformation with an intensity progressively increasing from the mafic to the more differentiated rocks. The foliations are EW to NW–SE striking and subvertical. A first set of lineations shows a moderate WNW plunge, with a dextral reverse kinematics. More recent subvertical lineations correspond to an uplift of the northern compartment. To the east, the MSZ was cut by a N120°E-striking late shear band, separating the MSZ from the Quérigut pluton. The different stages of mylonitization relate to Late Variscan dextral transpression. This regime allowed the ascent of magmas along tension gashes in the middle crust. We interpret the MSZ as a zone of magma transfer, which fed a pluton now eroded that was similar to the Quérigut and Millas plutons located to the east. We propose a model of emplacement of these plutons by successive pulses of magmas along en-échelon transfer zones similar to the MSZ.  相似文献   
583.
Abundant ferroan, metaluminous granitoids (970–950 Ma) emplaced at the end of the Sveconorwegian collisional orogeny (1130–900 Ma) are dominated by intermediate to silicic compositions with rare mafic facies. Both 73% fractional crystallization of an amphibole-bearing gabbroic cumulate substracted from the parent mafic composition and 30% non-modal batch melting of an amphibolitic source equivalent in composition to the mafic facies produce a monzodioritic liquid with appropriate trace element composition. A better fit is obtained for the partial melting process. Both processes could have occurred simultaneously to produce mafic cumulates and restites. As there is no evidence for large volumes of dense mafic rocks in the Sveconorwegian upper crust, these dense mafic rocks were probably produced in the lower crust. Formation of these granitoids, thus, contributed to the vertical stratification of the Proterozoic continental crust and also to the transfer of water from the lower crust to the surface.  相似文献   
584.
Recent studies demonstrated that Zn-phyllosilicate- and Zn-layered double hydroxide-type (Zn-LDH) precipitates may form in contaminated soils. However, the influence of soil properties and Zn content on the quantity and type of precipitate forming has not been studied in detail so far. In this work, we determined the speciation of Zn in six carbonate-rich surface soils (pH 6.2-7.5) contaminated by aqueous Zn in the runoff from galvanized power line towers (1322-30,090 mg/kg Zn). Based on 12 bulk and 23 micro-focused extended X-ray absorption fine structure (EXAFS) spectra, the number, type and proportion of Zn species were derived using principal component analysis, target testing, and linear combination fitting. Nearly pure Zn-rich phyllosilicate and Zn-LDH were identified at different locations within a single soil horizon, suggesting that the local availabilities of Al and Si controlled the type of precipitate forming. Hydrozincite was identified on the surfaces of limestone particles that were not in direct contact with the soil clay matrix. With increasing Zn loading of the soils, the percentage of precipitated Zn increased from ∼20% to ∼80%, while the precipitate type shifted from Zn-phyllosilicate and/or Zn-LDH at the lowest studied soil Zn contents over predominantly Zn-LDH at intermediate loadings to hydrozincite in extremely contaminated soils. These trends were in agreement with the solubility of Zn in equilibrium with these phases. Sequential extractions showed that large fractions of soil Zn (∼30-80%) as well as of synthetic Zn-kerolite, Zn-LDH, and hydrozincite spiked into uncontaminated soil were readily extracted by 1 M NH4NO3 followed by 1 M NH4-acetate at pH 6.0. Even though the formation of Zn-precipitates allows for the retention of Zn in excess to the adsorption capacity of calcareous soils, the long-term immobilization potential of these precipitates is limited.  相似文献   
585.
The Ronda orogenic peridotite (southern Spain) contains a varietyof pyroxene-rich rocks ranging from high-pressure garnet granulitesand pyroxenites to low-pressure plagioclase–spinel websterites.The ‘asthenospherized’ part of the Ronda peridotitecontains abundant layered websterites (‘group C’pyroxenites), without significant deformation, that occur asswarms of layers showing gradual modal transitions towards theirhost peridotites. Previous studies have suggested that theselayered pyroxenites formed by the replacement of refractoryspinel peridotites. Here, we present a major- and trace-element,and numerical modelling study of a layered outcrop of groupC pyroxenite near the locality of Tolox aimed at constrainingthe origin of these pyroxenites after host peridotites by pervasivepyroxene-producing, refertilization melt–rock reactions.Mg-number [= Mg/(Mg + Fe) cationic ratio] numerical modellingshows that decreasing Mg-number with increasing pyroxene proportion,characteristic of Ronda group C pyroxenites, can be accountedfor by a melt-consuming reaction resulting in the formationof mildly evolved, relatively low Mg-number melts (0·65)provided that the melt fraction during reaction and the time-integratedmelt/rock ratio are high enough (>0·1 and > 1,respectively) to balance Mg–Fe buffering by peridotiteminerals. This implies strong melt focusing caused by melt channellingin high-porosity domains resulting from compaction processesin a partial melted lithospheric domain below a solidus isothermrepresented by the Ronda peridotite recrystallization front.The chondrite-normalized rare earth element (REE) patterns ofgroup C whole-rocks and clinopyroxenes are convex-upward. Numericalmodeling of REE variations in clinopyroxene produced by a pyroxene-forming,melt-consuming reaction results in curved trajectories in the(Ce/Nd)N vs (Sm/Yb)N diagram (where N indicates chondrite normalized).Based on (Ce/Nd)N values, two transient, enriched domains betweenthe light REE (LREE)-depleted composition of the initial peridotiteand that of the infiltrated melt may be distinguished in thereaction column: (1) a lower domain characterized by convex-upwardREE patterns similar to those observed in Ronda group C pyroxenite–peridotite;(2) an upper domain characterized by melts with strongly LREE-enrichedcompositions. The latter are probably volatile-rich, small-volumemelt fractions residual after the refertilization reactionsthat generated group C pyroxenites, which migrated throughoutthe massif—including the unmelted lithospheric spinel-tectonitedomain. The Ronda mantle domains affected by pyroxenite- anddunite- or harzburgite-forming reactions (the ‘layeredgranular’ subdomain and ‘plagioclase-tectonite’domain) are on average more fertile than the residual, ‘coarsegranular’ subdomain at the recrystallization front. Thisindicates that refertilization traces the moving boundariesof receding cooling of a thinned and partially melted subcontinentallithosphere. This refertilization process may be widespreadduring transient thinning and melting of depleted subcontinentallithospheric mantle above upwelling asthenospheric mantle. KEY WORDS: subcontinental mantle; refertilization; pyroxenite; peridotite; websterite; melt–rock reaction; plagioclase; trace elements  相似文献   
586.
587.
588.
This paper presents a comprehensive experimental investigation on time-dependent swelling behaviour at both macroscale and microscale of a natural Australian expansive soil in compacted state. A number of one-dimensional swelling tests under different vertical pressures, different initial void ratios and initial water contents were performed. The characterization at macroscale was complemented by extensive microstructural investigations through mercury intrusion porosimetry and scanning electron microscope observation on both as-compacted and swollen specimens. The results were discussed at two different scales within a framework of double-porosity, which was finalized by linking the macrostructural–microstructural strains ratio with secondary swelling/compression coefficients. The multi-scale correlation appears to be largely independent of the specimen initial conditions. The study showed that the secondary swelling and primary swelling are governed by the same factors and that secondary swelling takes place mainly in macropores, of which the change magnitude depends on the level of confinement applied. The microstructural investigations show that swelling is accompanied by significant microfabric changes.  相似文献   
589.
New stratigraphic data, lithostratigraphic correlations, and fault kinematic analysis are used to discuss the basin geometry and sedimentation patterns of the northeastern Tunisia during Cretaceous times. Significant facies and thickness variations are deduced along the northeastern Atlas of Tunisia. The NW-SE 80-km-long regional correlation suggests a high sedimentation rate associated with irregular sea floor. The fault kinematic analysis highlights N-S to NE-SW tectonic extension during Early Cretaceous. During Aptian–Albian times, an extensional regime is recognized with NE-SW tectonic extension. The Cenomanian–Turonian fault populations highlight a WNW-ESE to NW-SE extension, and Campanian–Maastrichtian faults illustrate an NW-SE extension. The normal faulting is associated to repetitive local depocenters with a high rate of sedimentation as well as abundant syntectonic conglomeratic horizons, slump folds, and halokinetic structures. The sequence correlation shows repetitive local depocenters characterizing the basin during Early Cretaceous times. All the above arguments are in favor of basin configuration with tilted blocks geometry. This geometry is shaped by major synsedimentary intra-basin listric normal faults, themselves related to the extensional setting of the southern Tethyan paleomargin, which persisted into the Campanian–Maastrichtian times. The results support a predominant relationship between tilted blocks geometry and sedimentation rather than E-W “Tunisian trough” as it was previously accepted.  相似文献   
590.
The end of the Triassic and the Early Jurassic are intervals characterised by profound biotic and environmental changes, accompanied by dramatic decreases in marine fauna diversity. Corals were strongly affected and assemblages underwent a severe reduction; compared with those of the Upper Triassic, the Early Jurassic is traditionally defined as holding a “reef gap”. A Sinemurian coral-microbialites patch reef, located in southern France in the Hérault department (Le Perthus locality), is here described. This bioconstruction developed in a shallow mixed siliciclastic-carbonate inner ramp setting. The reef volume is composed of up to 70% of an intercoral facies mostly microbialites, with subordinated sediments (approximately 20–30% of the intercoral facies). Therefore, the patch reef can be defined as a coral-microbialite bioconstruction, in which microbialites were the main framebuilders. The coral assemblage has low diversity and is dominated by massive to branching colonies of Chondrocoenia clavellata. This highlights the reef diversity after the T/J boundary crisis. The Le Perthus patch reef could have acted as an edge for the dominant currents and probably induced reductions in hydrodynamic energy and sedimentation on one of its sides. Consequently, it could have triggered the growth of small lateral bioconstructions, composed of oysters and microbialites, uniquely on one of its sides. The evolution of the facies shows that the Le Perthus patch reef grew in a shallowing-upward setting accompanied by an increase in siliciclastic inputs. The rate of bioerosion and the faunal assemblage suggest that the bioconstructions could have been developed in a mesotrophic environment.  相似文献   
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