A New Method to Quantify Carbonate Rock Weathering     

Caroline Dubois  John Deceuster  Olivier Kaufmann  Matt D. Rowberry 《Mathematical Geosciences》2015,47(8):889-935

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The use of a Multilayer Perceptron for detecting new human settlements from a time series of MODIS images     

B.P. Salmon  J.C. Olivier  W. Kleynhans  K.J. Wessels  F. van den Bergh  K.C. Steenkamp 《International Journal of Applied Earth Observation and Geoinformation》2011

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Volcanic and solar activity, and atmospheric circulation influences on cosmogenic Be fallout at Vostok and Concordia (Antarctica) over the last 60 years     

Mélanie Baroni  Edouard Bard  Olivier Magand 《Geochimica et cosmochimica acta》2011,75(22):7132-7145

The cosmogenic nuclide beryllium-10 (¹⁰Be), recovered from ice cores, is often used to study solar activity on long timescales. However, the ¹⁰Be signal is also influenced by factors other than the Sun. To identify and quantify various contributions to the ¹⁰Be signal, two Antarctic snow records from the Vostok and Concordia sites spanning the last 60 years were studied at a sub-annual resolution. Three factors that contribute to the ¹⁰Be signal were identified. First, a significant period of approximately 11 yr that can be associated with the modulation of ¹⁰Be production by solar activity was detected in both records. The solar imprint constitutes 20-35% of the variance within the total signal. The 11-yr ¹⁰Be snow component was attenuated by a factor of ∼0.5 and was delayed by ∼1.4 yr compared to the ¹⁰Be production expected within the polar atmosphere. The result could be interpreted as the composite response of a stratospheric ¹⁰Be reservoir with an 11-yr modulation that was attenuated and delayed (with respect to ¹⁰Be polar production) and to a tropospheric ¹⁰Be reservoir with an 11-yr modulation that was not attenuated or delayed. Then, peaks in ¹⁰Be concentrations that were ∼66% and ∼35% higher than the average concentration were observed during the stratospheric volcanic eruptions of Agung (in 1963) and Pinatubo (in 1991), respectively. In light of these new results, published ¹⁰Be ice core records could be reinterpreted because spikes in ¹⁰Be concentration appear at the time of several stratospheric events. The data indicate that stratospheric volcanic eruptions can impact ¹⁰Be transport and deposition as a result of the roles played by the sedimentation of sulfate aerosols and the formation and rapid settling of polar stratospheric clouds (PSC). Also, an interannual variability of ∼4 yr was determined in both ¹⁰Be records, corresponding to ∼26% of the variance within the signal at Vostok. As with species of marine origin (sodium), this 4-yr variability is interpreted as a tropospheric modulation. The 4-yr variability could be associated with atmospheric circulation associated with the coupled Southern Ocean ocean-atmosphere system. The results presented here, from sites within the high Antarctic plateau, open new possibilities for ice core dating over the last few centuries and for the reconstruction of past solar activity in relation to climate.  相似文献   

Age of river basins in Guadeloupe impacting chemical weathering rates and land use     

Sétareh Rad  Olivier Cerdan  Karine Rivé  Gilles Grandjean 《Applied Geochemistry》2011

The Lesser Antilles have very high chemical weathering rates, with values that can reach 1290 t/km²/a. The tropical environment induces high precipitation rates, high temperature, dense vegetation, with sharp relief and thick soils. Because of volcanic activity, frequent pyroclastic flows produce very erodible and porous materials. In addition, agriculture induces important land use changes which replace existing native forest cover with banana and sugar cane plantations. Their surface can cover as much as 40% of the total area of a river basin. The aim of this study is to identify key parameters, either natural or anthropogenic, that control chemical weathering rates. Among the combined impact of all parameters (climate, runoff, slopes, vegetation etc.), basin age seems to be the control parameter: the younger the basin, the higher the weathering rate. A correlation between the chemical weathering rate and the basin age suggests that young volcanic rocks are more easily weathered than old ones: young fresh material is easily mobilized by erosion, while for older rocks with thick soil covers, chemical rates are much lower. A combined effect between the higher erodibility and a higher climate erosivity of the younger relief could be observed. Moreover, a correlation between banana plantations and the chemical weathering rates that can be explained by an increase of infiltration, due to stem flow processes is shown here. Banana plantations also have a correlation with the basin age, older basins being more favorable terrains for cultivation.  相似文献   

Pyrite tracks assimilation of crustal sulfur in Pyrenean peridotites     

Jean-Pierre Lorand  Olivier Alard 《Mineralogy and Petrology》2011,101(1-2):115-128

Cobalt-bearing pyrite (0.5?C2.0?wt.% Co) is abnormally abundant (up to 35?vol.% of the total volume of the sulfide phase) in some eastern Pyrenean peridotite massifs, compared to pieces of subcontinental mantle studied so far for sulfides. Pyrite occurs as vermicular intergrowths inside pentlandite and/or chalcopyrite or as coarser, blocky grains in the intergranular pores of host peridotites. Those different pyrites are characterized by different platinum-group element systematics (measured by laser ablation microprobe and ICP-MS). Vermicular pyrite intergrown with pentlandite displays Os-, Ir-, Ru- and Rh-enriched chondrite normalized PGE patterns of Monosulfide solid solution (Mss). In contrast, coarse-grained intergranular (??blocky??) pyrites, are PGE-poor. Chalcophile trace elements (i.e. Zn, Pb, Ag, Au) that are not usually concentrated in mantle-derived sulfides were commonly detected. By contrast, selenium contents are generally low, yielding thus pyrite with high S/Se ratio (>10⁵), consistent with a sedimentary sulfur source. Pyrite microtextures and chalcophile trace element contents support a process of assimilation of crustal sulfur from the metamorphosed sedimentary country rocks. These latter generated highly reactive CO₂-S fluids, which were injected into structural discontinuities of the lherzolitic bodies. Sulfur has reacted at T?=?300?C550°C with pre-existing, mantle-derived, metal-rich sulfide assemblages (pentlandite-chalcopyrite). Addition of crustal sulfur did produce Mss which, on cooling, exsolved the Os-rich pyrite in addition to pentlandite. The coarse-grained pyrite types have crystallized directly from S-rich fluids.  相似文献   

Oscarella balibaloi,a new sponge species (Homoscleromorpha: Plakinidae) from the Western Mediterranean Sea: cytological description,reproductive cycle and ecology     

Thierry Pérez  Julijana Ivanisevic  Maude Dubois  Laura Pedel  Olivier P. Thomas  Daria Tokina  Alexander V. Ereskovsky 《Marine Ecology》2011,32(2):174-187

A new homoscleromorph sponge species was observed for the first time in 2002 along the coast of Provence (France) and since then, several investigations have been implemented. The new homoscleromorph species is devoid of skeleton and it is thus related to the Oscarella genus. Oscarella balibaloi sp. nov. has been found in several littoral submarine caves of the Western Mediterranean Sea (France and Spain). After several years of monitoring, we show that this sponge is becoming abundant in several locations. The species has a peculiar habit, often overgrowing massive sponges, gorgonians or some erected bryozoans. Oscarella balibaloi sp. nov. is thinly encrusting, with an irregular morphology, lobate surface, and soft and very slimy consistency. Its color is white to orange. At the cytological level, this new species is characterized by three distinct types of cells with inclusions in its mesohyl: one with vacuoles and the others with paracrystalline inclusions. The reproduction pattern is very similar to other Oscarella species. We also present a specific metabolic fingerprint and compare it to that of other Mediterranean Oscarella species.  相似文献   

CO2 geological storage: The environmental mineralogy perspective     

François Guyot  Damien Daval  Sébastien Dupraz  Isabelle Martinez  Bénédicte Ménez  Olivier Sissmann 《Comptes Rendus Geoscience》2011,343(2-3):246-259

Geological storage of carbon dioxide (CO₂) is one of the options envisaged for mitigating the environmental consequences of anthropogenic CO₂ increases in the atmosphere. The general principle is to capture carbon dioxide at the exhaust of power plants and then to inject the compressed fluid into deep geological formations. Before implementation over large scales, it is necessary to assess the efficiency of the process and its environmental consequences. The goal of this paper is to discuss some environmental mineralogy research perspectives raised by CO₂ geological storage.  相似文献   

Origin of high Zn contents in Jurassic limestone of the Jura mountain range and the Burgundy: evidence from Zn speciation and distribution     

Olivier Jacquat  Claire Rambeau  Andreas Voegelin  Natalia Efimenko  André Villard  Karl B. Föllmi  Ruben Kretzschmar 《Swiss Journal of Geoscience》2011,104(3):409-424

In order to better understand the origin and enrichment mechanisms leading to elevated Zn concentrations in Jurassic limestone of the Jura mountain range (JMR) and the Burgundy (B), we investigated four locations of Bajocian age (JMR: Lausen–Schleifenberg, Gurnigel; B: Vergisson–Davayé, Lucy-le-Bois) and two locations of Oxfordian age (JMR: Dornach, Pichoux) for their Zn distribution and speciation. Measurements of the acid-extractable and bulk Zn contents showed that Zn is stratigraphically and spatially heterogeneously distributed, in association with permeable carbonate levels. Up to 3,580 and 207 mg/kg Zn was detected in Bajocian and Oxfordian limestone, respectively, with numerous limestone samples having Zn contents above 50 mg/kg. Using X-ray absorption near edge structure spectroscopy and micro-X-ray fluorescence spectrometry, the speciation and micro-scale distribution of Zn was investigated for selected limestone samples. In Bajocian limestone sphalerite and/or Zn-substituted goethite and a minor fraction of Zn-bearing carbonates were identified. In contrast, Zn-bearing carbonates (Zn-substituted calcite and hydrozincite) were accounting for most of the total Zn in Oxfordian limestone. The micro-scale distribution of Zn for Bajocian and Oxfordian limestone was however similar with localized Zn-rich zones in the limestone cement and at the rim of oolites. The stratigraphic sporadicity and microscale heterogeneity of the Zn distribution together with the Zn speciation results point to a hydrothermal origin of Zn. Occurence of Zn-goethite is probably linked to the oxidative transformation of framboidal pyrite and hydrothermal sphalerite in contact with meteoritic waters. Difference in speciation between Bajocian limestone and Oxfordian limestone may be related to differences in rock permeability and/or to various hydrothermal events. Isotopic dating of the different mineralizations will be needed to decipher differences in Zn speciation and the precise chronology of hydrothermal episodes.  相似文献   

Physical constraints on impact melt properties from Lunar Reconnaissance Orbiter Camera images     

Brett W. Denevi  Steven D. Koeber  Mark S. Robinson  W. Brent Garry  B. Ray Hawke  Thanh N. Tran  Samuel J. Lawrence  Laszlo P. Keszthelyi  Olivier S. Barnouin  Carolyn M. Ernst  Livio L. Tornabene 《Icarus》2012,219(2):665-675

Impact melt flows exterior to Copernican-age craters are observed in high spatial resolution (0.5 m/pixel) images acquired by the Lunar Reconnaissance Orbiter Camera (LROC) Narrow Angle Camera (NAC). Impact melt is mapped in detail around 15 craters ranging in diameter from 2.4 to 32.5 km. This survey supports previous observations suggesting melt flows often occur at craters whose shape is influenced by topographic variation at the pre-impact site. Impact melt flows are observed around craters as small as 2.4 km in diameter, and preliminary estimates of melt volume suggest melt production at small craters can significantly exceed model predictions. Digital terrain models produced from targeted NAC stereo images are used to examine the three-dimensional properties of flow features and emplacement setting, enabling physical modeling of flow parameters. Qualitative and quantitative observations are consistent with low-viscosity melts heated above their liquidii (superheated) with limited amounts of entrained solids.  相似文献   

Trojans’ Odyssey: Unveiling the early history of the Solar System     

Philippe Lamy  Pierre Vernazza  Joel Poncy  Vincent Martinot  Emmanuel Hinglais  Elisabet Canalias  Jim Bell  Dale Cruikshank  Olivier Groussin  Joern Helbert  Francesco Marzari  Alessandro Morbidelli  Pascal Rosenblatt  Holger Sierks 《Experimental Astronomy》2012,33(2-3):685-721

In our present understanding of the Solar System, small bodies (asteroids, Jupiter Trojans, comets and TNOs) are the most direct remnants of the original building blocks that formed the planets. Jupiter Trojan and Hilda asteroids are small primitive bodies located beyond the ‘snow line’, around respectively the L₄ and L₅ Lagrange points of Jupiter at ～5.2?AU (Trojans) and in the 2:3 mean-motion resonance with Jupiter near 3.9?AU (Hildas). They are at the crux of several outstanding and still conflicting issues regarding the formation and evolution of the Solar System. They hold the potential to unlock the answers to fundamental questions about planetary migration, the late heavy bombardment, the formation of the Jovian system, the origin and evolution of trans-neptunian objects, and the delivery of water and organics to the inner planets. The proposed Trojans’ Odyssey mission is envisioned as a reconnaissance, multiple flyby mission aimed at visiting several objects, typically five Trojans and one Hilda. It will attempt exploring both large and small objects and sampling those with any known differences in photometric properties. The orbital strategy consists in a direct trajectory to one of the Trojan swarms. By carefully choosing the aphelion of the orbit (typically 5.3?AU), the trajectory will offer a long arc in the swarm thus maximizing the number of flybys. Initial gravity assists from Venus and Earth will help reducing the cruise time as well as the ΔV needed for injection thus offering enough capacity to navigate among Trojans. This solution further opens the unique possibility to flyby a Hilda asteroid when leaving the Trojan swarm. During the cruise phase, a Main Belt Asteroid could be targeted if requiring a modest ΔV. The specific science objectives of the mission will be best achieved with a payload that will perform high-resolution panchromatic and multispectral imaging, thermal-infrared imaging/ radiometry, near- and mid-infrared spectroscopy, and radio science/mass determination. The total mass of the payload amounts to 50?kg (including margins). The spacecraft is in the class of Mars-Express or a down-scaled version of Jupiter Ganymede Orbiter. It will have a dry mass of 1200?kg, a total mass at launch of 3070?kg and a ΔV capability of 700?m/s (after having reached the first Trojan) and can be launched by a Soyuz rocket. The mission operations concept (ground segment) and science operations are typical of a planetary mission as successfully implemented by ESA during, for instance, the recent flybys of Main Belt asteroids Steins and Lutetia.  相似文献