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541.
This paper proposes a new approach for forecasting continuous indoor air quality time series and in particular the concentration of a common air pollutant in offices like formaldehyde. Forecasting is achieved through the combination of the spectral band decomposition using fast Fourier transform and nonlinear time series modeling. Two nonlinear models have been tested: a threshold autoregressive (TAR) model and a Chaos dynamics-based modeling. This study shows the benefit of the Fourier decomposition coupled with nonlinear modeling of each extracted component, compared to forecasting applied directly on the raw data. Both TAR and Chaos dynamics models are able to reproduce nonlinearities, with slightly better performance in the case of the second model. These hybrid models provide good performance on forecast time horizon up to 12 h ahead.  相似文献   
542.
Sediment connectivity characterizes the physical transfer of sediment through different geomorphic compartments in catchments due to sediment detachment, transport and deposition. Quantifying and modelling sediment connectivity is therefore a key prerequisite to improving our understanding of the dispersion of particle‐borne contaminants, especially in catchments exposed to highly erosive climates. The objective of this study is to provide novel insights into typhoon impacts on sediment connectivity from hillslopes to rivers. The dispersion of particle‐bound caesium‐137 (137Cs) was investigated in two coastal catchments draining the main contamination plume from the Fukushima Daiichi Nuclear Power Plant accident. Five sampling campaigns were carried out from November 2011 to November 2015, after each typhoon season. The spatial and temporal evolution of 137Cs contamination was investigated through the calculation of 137Cs enrichment ratios in sediment relative to nearby soils. Rainfall erosivity (EI30) associated with the main typhoons that occurred prior to each sampling campaign were computed, mapped, and finally used to improve a topographic‐based index of connectivity. From 2011 to 2015, mean contamination levels in Mano and Niida catchments decreased from 11.9 kBq kg?1 to 3.3 kBq kg?1 and from 34.1 kBq kg?1 to 8.0 kBq kg?1, respectively. Regional mean EI30 ranged from 262 MJ mm ha?1 h?1 for typhoon Jelawat (in 2012) to 1695 MJ mm ha?1 h?1 for typhoon Roke (in 2011). Typhoons Roke (2011) and Etau (2015) showed the highest connectivity from contaminated sources to the rivers, and induced a significant export of sediment to the ocean. In 2013 a slight increase in 137Cs levels in river sediments occurred, likely resulting from initial decontamination works and the occurrence of two consecutive typhoons. Importantly, this research provides new insights into the connectivity of the main sources of sediments contaminated with radiocaesium in Fukushima Prefecture and their temporal evolution, which will help with ongoing decontamination efforts. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
543.
544.
The recent seismicity catalogue of metropolitan France Sismicité Instrumentale de l’Hexagone (SI-Hex) covers the period 1962–2009. It is the outcome of a multipartner project conducted between 2010 and 2013. In this catalogue, moment magnitudes (M w) are mainly determined from short-period velocimetric records, the same records as those used by the Laboratoire de Détection Géophysique (LDG) for issuing local magnitudes (M L) since 1962. Two distinct procedures are used, whether M L-LDG is larger or smaller than 4. For M L-LDG >4, M w is computed by fitting the coda-wave amplitude on the raw records. Station corrections and regional properties of coda-wave attenuation are taken into account in the computations. For M L-LDG ≤4, M w is converted from M L-LDG through linear regression rules. In the smallest magnitude range M L-LDG <3.1, special attention is paid to the non-unity slope of the relation between the local magnitudes and M w. All M w determined during the SI-Hex project is calibrated according to reference M w of recent events. As for some small events, no M L-LDG has been determined; local magnitudes issued by other French networks or LDG duration magnitude (M D) are first converted into M L-LDG before applying the conversion rules. This paper shows how the different sources of information and the different magnitude ranges are combined in order to determine an unbiased set of M w for the whole 38,027 events of the catalogue.  相似文献   
545.
A set of high‐fidelity simulated asteroid materials, or simulants, was developed based on the mineralogy of carbonaceous chondrite meteorites. Three varieties of simulant were developed based on CI1 chondrites (typified by Orgueil), CM2 chondrites (typified by Murchison), and CR2/3 chondrites (multiple samples). The simulants were designed to replicate the mineralogy and physical properties of the corresponding meteorites and anticipated asteroid surface materials as closely as is reasonably possible for bulk amounts. The simulants can be made in different physical forms ranging from larger cobbles to fine‐grained regolith. We analyzed simulant prototypes using scanning electron microscopy, X‐ray fluorescence, reflectance spectroscopy at ambient conditions and in vacuum, thermal emission spectroscopy in a simulated asteroid environment chamber, and combined thermogravimetry and evolved gas analysis. Most measured properties compare favorably to the reference meteorites and therefore to predicted volatile‐rich asteroid surface materials, including boulders, cobbles, and fine‐grained soils. However, there were also discrepancies, and mistakes were made in the original mineral formulations that will be updated in the future. The asteroid simulants are available to the community from the nonprofit Exolith Lab at UCF, and the mineral recipes are freely published for other groups to reproduce and modify as they see fit.  相似文献   
546.
Benthic faunal activity and density play an important role in determining the rates of benthic nutrient fluxes, which enrich the water column and contribute to phytoplankton growth. The intensity of nutrient fluxes in the Bay of Brest depends on the density of the invasive gastropod, Crepidula fornicata. In order to study the impact of benthic fluxes on phytoplankton dynamics, realistic daily nutrient inputs simulating various densities of C. fornicata were added to six enclosures during three weeks. The increase in fertilization intensity influenced the phytoplankton biomass. A succession from Chaetoceros spp. to Pseudo-nitzschia spp. and Leptocylindrus danicus was observed in all enclosures, but the dynamics of successions were different. Pseudo-nitzschia spp. was favored in the three more fertilized enclosures, while Chaetoceros spp. persisted longer in less enriched enclosures. Despite an apparent nitrogen limitation, the quantum efficiency of PSII (Fv/Fm) was high (>0.5) and stable in all enclosures. The maximal photosynthetic capacity (PBmax) was also invariable and oscillated around an average value of 2.23 mg C (mg Chl a)−1 h−1. The stability of Fv/Fm and PBmax observed at different nutrient input intensities demonstrates that the daily inputs maintained the physiological balance of the microalgae. The maximal light utilization efficiency (α) and the light saturation parameter (Ek) were also quite stable after day 8, which reveals that photosynthetic parameters were driven by growth constraints due to nutrient availability and not by incident light or species successions. We suggest that our results correspond to an “Ek independent variation” regulation. We propose that such regulation of photosynthetic parameters appears when there are frequent nutrient additions which do not allow replete nutrient conditions to be reached but lead to physiological equilibrium.  相似文献   
547.
We report on the development and validation of a coupled two- and one-dimensional finite-element model for the Scheldt tributaries, river, estuary and region of fresh water influence (ROFI). The hydrodynamic equations are solved on a single, unstructured, multi-scale mesh stretching from the shelf break to the Scheldt tributaries. The tide is forced on the shelf break and propagates upstream in the riverine network. Upstream boundaries lie on sluices or outside of the region of tidal dominance where daily averaged discharges are imposed. Two-dimensional, depth-averaged shallow water equations are solved by means of the discontinuous Galerkin (DG) method over the marine and estuarine parts of the computational domain. In the rivers, however, one-dimensional equations are dealt with using the DG method with the addition of a technique to cope with confluence points. Model parameters are carefully calibrated, leading to the simulation of wind- and tide-forced flows that are in excellent agreement with available data. The diffusivity in the transport equation is calibrated using time series of salinity at various locations in the estuary. Finally, the Lagrangian residual transport in the estuary and the adjacent coastal zone is investigated. This work is a major step towards an integrated model for studying the dynamics of waterborne contaminants and the water renewal timescales in the Scheldt land-sea continuum.  相似文献   
548.
549.
Igneous sills and laccoliths emplaced in sedimentary basins may significantly impact petroleum systems, both positively and negatively. Igneous intrusions provide heat to maturate regionally immature organic-rich host rocks, act as fractured reservoirs hosting commercial accumulations of hydrocarbons, and form structures affecting fluid flow and trapping at different scales. Nevertheless, the petrophysical implications of igneous intrusions on their host rock are poorly known. In this study, we analyse 200 wells in the Río Grande Valley oil field, Neuquén basin, Argentina, where the main reservoirs are in fractured igneous sills. This dataset represents a globally unique possibility to characterize the igneous–host rock interaction using both wireline logs and core material. We identify a systematic Contact Low Resistivity Zone (CLRsZ) at both the upper and lower contacts of the sills emplaced in the organic-rich Vaca Muerta and Agrio Formations. We characterize the nature of these CLRsZ and their petrophysical properties by integrating resistivity and gamma ray well logs, petrographic analyses, petrophysical tests and geochemical analyses. The low resistivity signal of the CLRsZ is dominantly carried by massive-sulphide deposits, mainly pyrite, observed both in the host rock and the chilled margin of the sills. Well log images and porosity-permeability analysis on core plugs show that both the sills and their associated CLRsZ can act as carrier for fluid flow and reservoir for hydrocarbons storage. The thickness of the upper and lower CLRsZ correlates linearly with the thickness of the sill, and the volume of both the upper and lower CLRsZ represents ca. 40% with respect to the volume of their associated sill. The thickness of the CLRsZ represents ca. 13% of the thickness of contact aureole induced by the sills. In the CLRsZ, a great proportion of kerogen was transformed to hydrocarbon, so that CLRsZ were restricted to the innermost contact aureole of the sills. Our results show that the CLRsZ can have major implications on fluid flow and should be considered in reservoir models in volcanic basins hosting sills emplaced in organic-rich formations.  相似文献   
550.
Fluxes of the heavy metals chromium (Cr), cobalt (Co), nickel (Ni), copper (Cu), lead (Pb), cadmium (Cd) and zinc (Zn) delivered by rivers to the Gulf of Lion (NW Mediterranean Sea) were estimated over a three year study of the River Rhone and its smaller tributaries. Most of the particulate metal fluxes (80–90%) delivered by these rivers occurred within a very short period of time (less than 12%), a typical trend for the Mediterranean environment, where highly contrasting hydrological regimes were observed over the year. Temporal and spatial variations in the fluxes of these particulate metals were driven by the fluxes in both water discharge and suspended particulate matter load. On the shelf, these particulate metal fluxes, largely arising from the Rhone watershed, were two to ten times more important than those resulting from atmospheric deposition. Co, Cr and Ni in the rivers and on the shelf surface sediments were mainly natural and associated with the finest particles. Cd and Phosphorus appeared to be associated with the silt fraction and to be enriched in the prodelta areas. Pb, Zn and Cu were more closely associated with the organic matter content and also showed enrichment in the organic rich prodeltaic sediments. Anthropogenic influences diminished offshore, except for Pb and Zn which could be supplied from the atmosphere by man-made aerosols. Although most of the metals tended to be enriched in the prodelta areas, these did not constitute a permanent sink due to resuspension processes affecting these shallow depths. A resuspension experiment conducted on sediment cores from the Rhone prodelta demonstrated that metal deposited on the surface layer, especially those associated with the organic matter, may be resuspended; this should be taken into account for a complete understanding of the biogeochemical cycle of these metals.  相似文献   
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