A Quartz-bearing Orthopyroxene-rich Websterite Xenolith from the Pannonian Basin, Western Hungary: Evidence for Release of Quartz-saturated Melts from a Subducted Slab     

Bali  E.; Zajacz  Z.; Kovacs  I.; Szabo  CS.; Halter  W.; Vaselli  O.; Torok  K.; Bodnar  R. J. 《Journal of Petrology》2008,49(3):421-439

An unusual quartz-bearing orthopyroxene-rich websterite xenolithhas been found in an alkali basaltic tuff at Szigliget, Bakony–BalatonHighland Volcanic Field (BBHVF), western Hungary. Ortho- andclinopyroxenes are enriched in light rare earth elements (LREE),middle REE and Ni, and depleted in Nb, Ta, Sr and Ti comparedwith ortho- and clinopyroxenes occurring in either peridotiteor lower crustal granulite xenoliths from the BBHVF. Both ortho-and clinopyroxenes in the xenolith contain primary and secondarysilicate melt inclusions, and needle-shaped or rounded quartzinclusions. The melt inclusions are rich in SiO₂ and alkalisand poor in MgO, FeO and CaO. They are strongly enriched inLREE and large ion lithophile elements, and display negativeNb, Ta and Sr anomalies, and slightly positive Pb anomalies.The xenolith is interpreted to represent a fragment of an orthopyroxene-richbody that crystallized in the upper mantle from a hybrid meltthat formed by interaction of mantle peridotite with a quartz-saturatedsilicate melt that was released from a subducted oceanic slab.Although the exact composition of the slab melt cannot be determined,model calculations on major and trace elements suggest involvementof a metasedimentary component. KEY WORDS: quartz; mantle; silicate melt inclusion; SiO₂-rich melt; subduction; Carpathian-Pannonian Region  相似文献   

Mercury in itabirite-hosted soft hematite ore in the Quadrilátero Ferrífero of Minas Gerais     

Alexandre Raphael Cabral  Orlando Garcia Rocha Filho  Richard David Jones 《Journal of Geochemical Exploration》2008,96(1):69-76

Mercury contents in Precambrian banded iron formation-hosted hematite ores are virtually unknown. In an attempt to provide information on the abundance and distribution of Hg in Fe ore, we present analyses for Hg in samples of high-grade soft hematite ore from Gongo Soco, Minas Gerais, Brazil. Bulk samples contain from <  5 to 25  ppb Hg without obvious correlation with major elements. Granulometric fractions of follow-up samples have amounts of Hg from 6 to 48  ppb and display positive linear correlations with total Mn as MnO (r = 0.87), LOI (r = 0.87) and SiO₂ (r = 0.76), as well as a negative linear correlation with total Fe as Fe₂O₃ (r = −  0.87). The correlations suggest that Hg is associated with a hydrated ferruginous groundmass bearing residual Mn, Al and Si, which replaced gangue minerals in itabirite in the process of formation of the Gongo Soco soft hematite ore.  相似文献   

Active Nitrogen in Surface Ozone Depletion Events at Alert during Spring 1998     

B. A. Ridley  J. J. Orlando 《Journal of Atmospheric Chemistry》2003,44(1):1-22

Measurements of NO_x,y were made at Alert, Nunavut, Canada (82.5° N, 62.3° W) during surface layer ozone depletion events. In spring 1998, depletion events were rare and occurred under variable actinic flux, ice fog, and snowfall conditions. NO_y changed by less than 10% between normal, partially depleted, and nearly completely depleted ozone air masses. The observation of a diurnal variation in NO_x under continuous sunlight supports a source from the snowpack but with rapid conversion to nitrogen reservoirs that are primarily deposited to the surface or airborne ice crystals. It was unclear whether NO_x was reduced or enhanced in different stages of the ozone depletion chemistry because of variations in solar and ambient conditions. Because ozone was depleted from 15–20 ppbv to less than 1 ppbv in just over a day in one event it is apparent that the surface source of NO_x did not grossly inhibit the removal of ozone. In another case ozone was shown to be destroyed to less than the 0.5 ppbv detection limit of the instrument. However, simple model calculations show that the rate of depletion of ozone and its final steady-state abundance depend sensitively on the strength of the surface source of NO_x due to competition from ozone production involving NO_x and peroxy radicals. The behavior of the NO/NO₂ ratio was qualitatively consistent with enhanced BrO during the period of active ozone destruction. The model is also used to emphasize that the diurnal partitioning of BrO_x during ozone depletion events is sensitive to even sub ppbv variations in O₃.  相似文献   

The origin of thermal waters from the eastern flank of the Dead Sea Rift Valley (western Jordan)   总被引：1，自引：0，他引：1  

Bruno Capaccioni  Orlando Vaselli  Elvio Moretti  Franco Tassi  Roberto Franchi 《地学学报》2003,15(3):145-154

Thermal waters emerging along the eastern flank of the northernmost part of the Dead Sea Rift Valley close to the Yarmuk river are dilute, Ca–SO₄–(HCO₃) and Na–Cl water types with measured temperatures of 35–60 °C and estimated teperatures, according to silica solubility, of 60–110 °C. They are fed only by present‐day recharged meteoric waters (Wadi Hasa, Al Himma and North Shuna thermal baths) and by meteoric waters contaminated with saline waters (El Ma'in thermal Bath). Although they have been known for a long time, there is still dispute about their origins and the source of heat. On the basis of new chemical and isotopic analyses, the saline waters could represent residual pockets of groundwater in equilibrium with those filling the Dead Sea depression before the last retreat of Lake Lisan at 17–15 kyr bp or with the ancient seawaters of the Sedom Lagoon in the early Pleistocene, in both cases unaffected by significant evaporation processes but chemically and isotopically modified by water/rock interaction.  相似文献   

Factors affecting habitat occupancy of fish assemblage in the Gulf of Trieste (Northern Adriatic Sea)   总被引：3，自引：0，他引：3  

Martina Orlando Bonaca  & Lovrenc Lipej 《Marine Ecology》2005,26(1):42-53

Species composition, richness and abundance of the fish assemblage were studied over six different inshore macrohabitats in the southern part of the Gulf of Trieste (Northern Adriatic Sea) using the visual counts technique. Fifteen environmental variables were taken into consideration in order to determine microhabitat preferences of fish species, using canonical correspondence analysis and electivity indices. The results suggest that the structure of the fish assemblage in shallow habitats is affected by a large number of interplaying factors. Depth, type of bottom and vegetation cover – incorporating both abiotic and biotic variables – are some of the factors responsible for coastal fish distribution. Microhabitat preferences for 29 fish species are presented in the depth range from 0.5 to 3 m.  相似文献   

Time-dependent CO<Subscript>2</Subscript> variations in Lake Albano associated with seismic activity     

G.?Chiodini  F.?TassiEmail author  S.?Caliro  C.?Chiarabba  O.?Vaselli  D.?Rouwet 《Bulletin of Volcanology》2012,74(4):861-871

Lake Albano (Alban Hills volcanic complex, Central Italy) is located in a densely populated area near Rome. The deep lake waters have significant dissolved CO₂ concentrations, probably related to sub-lacustrine fluid discharges fed by a pressurized CO₂-rich reservoir. The analytical results of geochemical surveys carried out in 1989–2010 highlight the episodes of CO₂ removal from the lake. The total mass of dissolved CO₂ decreased from ∼5.8 × 10⁷ kg in 1989 to ∼0.5 × 10⁷ kg in 2010, following an exponential decreasing trend. Calculated values of both dissolved inorganic carbon and CO₂ concentrations along the vertical profile of the lake indicate that this decrease is caused by CO₂ release from the epilimnion, at depth <9 m, combined with (1) water circulation at depth <95 m and (2) CO₂ diffusion from the deeper lake layers. According to this model, Lake Albano was affected by a large CO₂ input that coincided with the last important seismic swarm at Alban Hills in 1989, suggesting an intimate relationship between the addition of deep-originated CO₂ to the lake and seismic activity. In the case of a CO₂ degassing event of an order of magnitude larger than the one that occurred in 1989, the deepest part of Lake Albano would become CO₂-saturated, resulting in conditions compatible with the occurrence of a gas outburst. These results reinforce the idea that a sudden CO₂ input into the lake may cause the release of a dense gas cloud, presently representing the major volcanic threat for this densely populated area.  相似文献   

Hard coastal-defence structures as habitats for native and exotic rocky-bottom species   总被引：1，自引：0，他引：1  

Vaselli S  Bulleri F  Benedetti-Cecchi L 《Marine environmental research》2008,66(4):395-403

The use of hard coastal-defence structures, like breakwaters and seawalls, is rapidly increasing to prevent coastal erosion. We compared low-shore assemblages between wave-protected and wave-exposed habitats on breakwaters along a sandy shore of Tuscany (North-Western Mediterranean). Assemblages were generally characterized by a low diversity of taxa, with space monopolized by Mytilus galloprovincialis and Corallina elongata on the seaward side of breakwaters and by filamentous algae on the landward side. Assemblages in wave-protected habitats were characterized by greater temporal stability than those in exposed habitats and supported non-indigenous macroalgae such as Caulerpa racemosa and Codium fragile ssp. tomentosoides. Hence, the introduction of hard coastal-defence structures in otherwise soft-bottom dominated areas, attracting native and exotic rocky-bottom species, should be of great concern for the conservation of marine biodiversity at local and regional scales and for the management of biological invasions.  相似文献   

Thresholds and relations for soil‐hydraulic and soil‐physical properties as a function of burn severity 4 years after the 2011 Las Conchas Fire,New Mexico,USA          下载免费PDF全文

Brian A. Ebel  Orlando C. Romero  Deborah A. Martin 《水文研究》2018,32(14):2263-2278

Wildfire effects on soil‐physical and ‐hydraulic properties as a function of burn severity are poorly characterized, especially several years after wildfire. A stratified random sampling approach was used in 2015 to sample seven sites representing a spectrum of remotely sensed burn severity in the area impacted by the 2011 Las Conchas Fire in New Mexico, USA. Replicate samples from each site were analysed in the laboratory. Linear and linear indicator regression were used to assess thresholds in soil‐physical and ‐hydraulic properties and functional relations with remotely sensed burn severity. Significant thresholds were present for initial soil‐water content (θ_i) at 0–6 cm depth between the change in the Normalized Burn Ratio (dNBR) equal to 618–802, for bulk density (ρ_b) at 3–6 cm between dNBR equal to 416–533, for gravel fraction at 0–1 cm between dNBR equal to 416–533, for fines (the silt + clay fraction) at 0–1 cm for dNBR equal to 416–533, and for fines at 3–6 cm for dNBR equal to 293–416. Significant linear relations with dNBR were present between ρ_b at 0–1 cm, loss on ignition (LOI) at 0–1 cm, gravel fraction at 0–1 cm, and the large organic fraction at 1–3 cm. No thresholds or effects on soil‐hydraulic properties of field‐saturated hydraulic conductivity or sorptivity were observed. These results suggest that ρ_b and LOI at 0–1 cm have residual direct impacts from the wildfire heat impulse. The θ_i threshold is most likely from delayed groundcover/vegetation recovery that increases evaporation at the highest burn severity sites. Gravel and silt + clay thresholds at 0–1 cm at the transition to high burn severity suggest surface gravel lag development from hydraulic erosion. Thresholds in ρ_b from 3 to 6 cm and in silt + clay fraction from 3 to 6 cm appear to be the result of soil variability between sites rather than wildfire impacts. This work suggests that gravel‐rich soils may have increased resilience to sustained surface runoff generation and erosion following wildfire, with implications for assessments of postwildfire hydrologic and erosion recovery potential.  相似文献   

Hydrogeochemistry of the thermal waters from the Sciacca Geothermal Field (Sicily,southern Italy)     

Bruno Capaccioni  Orlando Vaselli  Franco Tassi  Alba P. Santo  A. Delgado Huertas 《Journal of Hydrology》2011,396(3-4):292-301

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Dissolution and carbonation of a serpentinite: Inferences from acid attack and high P-T experiments performed in aqueous solutions at variable salinity     

Andrea Orlando  Daniele BorriniLuigi Marini 《Applied Geochemistry》2011,26(8):1569-1583

Dissolution experiments on a serpentinite were performed at 70 °C, 0.1 MPa, in H₂SO₄ solution, in open and closed systems, in order to evaluate the overall dissolution rate of mineral components over different times (4, 9 and 24 h). In addition, the serpentinite powder was reacted with a NaCl-bearing aqueous solution and supercritical CO₂ for 24 h at higher pressures (9-30 MPa) and temperatures (250-300 °C) either in a stirred reactor or in an externally-heated pressure vessel to assess both the dissolution rate of serpentinite minerals and the progress of the carbonation reaction. Results show that, at 0.1 MPa, MgO extraction from serpentinite ranges from 82% to 98% and dissolution rate varies from 8.5 × 10⁻¹⁰ mole m⁻² s⁻¹ to 4.2 × 10⁻⁹ mole m⁻² s⁻¹. Attempts to obtain carbonates from the Mg-rich solutions by increasing their pH failed since Mg- and NH₄- bearing sulfates promptly precipitated. On the other hand, at higher pressures, significant crystallization (5.0-10.4 wt%) of Ca- and Fe-bearing magnesite was accomplished at 30 MPa and 300 °C using 100 g L⁻¹ NaCl aqueous solutions. The corresponding amount of CO₂ sequestered by crystallization of carbonates is 9.4-15.9 mole%. Dissolution rate (from 6.3 × 10⁻¹¹ mole m⁻² s⁻¹ to 1.3 × 10⁻¹⁰ mole m⁻² s⁻¹) is lower than that obtained at 0.1 MPa and 70 °C but it is related to pH values much higher (3.3-4.4) than that (−0.65) calculated for the H₂SO₄ solution.Through a thorough review of previous experimental investigations on the dissolution kinetics of serpentine minerals the authors propose adopting: (i) the log rate [mole m⁻² s⁻¹] value of −12.08 ± 0.16 (1σ), as representative of the neutral dissolution mechanism at 25 °C and (ii) the following relationship for the acidic dissolution mechanism at 25 °C: