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Composition of the water accommodated fractions as a function of exposure times and temperatures 总被引:1,自引:0,他引:1
The water accommodated fractions (WAFs) of nine oils in seawater have been studied. The oils range from light condensate to heavy crude, and include one highly biodegraded oil and one very wax rich oil. This study has identified large variations in the chemical composition of WAFs, depending on oil type, temperature, and mixing time. Experiments at different temperatures (2-13 °C) showed that it takes longer time to reach equilibrium at the lowest temperatures, and that this varies for the different oil types. Oils with higher pour point (wax rich oils) need a longer time to establish WAF in equilibrium than oils with lower pour points (naphthenic oils). At 13 °C a mixing time of 48 h, as recommended in standard procedures, seems to be sufficient for asphalthenic and paraffinic oils. The results demonstrated that for WAF prepared from an unknown oil, or at lower temperatures, different mixing times should be tested. Since the WAF often is used in toxicity testing, the toxicity might be underestimated if the mixing time is too short. 相似文献
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A field investigation of unsaturated flow through a lithophysal unit of fractured welded tuff containing lithophysal cavities has been initiated. To characterize flow in this spatially heterogeneous medium, a systematic approach has been developed to perform tests in boreholes drilled at regular intervals in an underground tunnel (drift). The purpose of the testing is to quantify the amounts of water seeping into the drift versus the amount of water moving around the drift when released into boreholes at many equidistant locations along the drift. In this paper, we describe the test equipment system that has been built for this purpose. Because the field-scale measurements--of liquid flow in the unsaturated, fractured rocks--require continuous testing for periods of days to weeks, the control of test equipment has been fully automated, allowing operation with no human presence at the field site. Preliminary results from the first set of tests indicate that, while the effects of evaporation on characterization of hydrological properties of the rock can be significant, these effects can be controlled and quantified. These tests give insight into the role of the cavities as potential storage during the initial transient flow prior to the breakthrough of water at the drift crown, as well as the role of connected fractures that provide the subsequent quasi-steady flow. In addition to the stated purpose of realizing the flow partitioning, the results yield values for the effective porosity in the pathways for liquid flow in the regions tested thus far. 相似文献
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Peebles PJ 《The Astrophysical journal》2000,534(2):L127-L129
Dark matter modeled as a classical scalar field that interacts only with gravity and with itself by a potential that is close to quartic at large field values and approaches a quadratic form when the field is small would be gravitationally produced by inflation and, at the present epoch, could act like an ideal fluid with pressure that is a function only of the mass density. This could have observationally interesting effects on the core radii and solid-body rotation of dark matter halos and on the low-mass end of the primeval mass fluctuation power spectrum. 相似文献
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