Effect of iron and carbonation on the diffusion of iodine and rhenium in waste encasement concrete and soil fill material under hydraulically unsaturated conditions     

Dawn M. Wellman  Kent E. Parker  Laura Powers  Greg A. Whyatt  Libby N. Clayton  Shas V. Mattigod  Marcus I. Wood 《Applied Geochemistry》2008,23(8):2256-2271

Assessing long-term performance of Category 3 cement wasteforms and accurate prediction for radionuclide encasement requires knowledge of the radionuclide–cement interactions and mechanisms of retention (i.e. sorption or precipitation). A set of sediment-concrete half-cell diffusion experiments was conducted under unsaturated conditions (4% and 7% by weight moisture content) using carbonated and non-carbonated concrete–soil half cells. Results indicate the behavior of Re and I release was comparable within a given half-cell test. Diffusivity in soil is a function of moisture content; a 3% increase in moisture content affords a one to two order of magnitude increase in diffusivity. Release of I and Re was 1–3 orders of magnitude less from non-carbonated, relative to carbonated, concrete monoliths. Inclusion of Fe in non-carbonate monoliths resulted in the lowest concrete diffusivity values for both I and Re. This suggests that in the presence of Fe, I and Re are converted to reduced species, which are less soluble and better retained within the concrete monolith. The release of I and Re was greatest from Fe-bearing, carbonated concrete monoliths, suggesting carbonation negates the effect of Fe on the retention of I and Re within concrete monoliths. This is likely due to enhanced formation of microcracks in the presence of Fe, which provide preferential paths for contaminant migration. Although the release of I and Re were greatest from carbonated concrete monoliths containing Fe, the migration of I and Re within a given half cell is dependent on the moisture content, soil diffusivity, and diffusing species.  相似文献   

World's Largest In Situ Thermal Desorption Project: Challenges and Solutions          下载免费PDF全文

G. Heron  K. Parker  S. Fournier  P. Wood  G. Angyal  J. Levesque  R. Villecca 《Ground Water Monitoring & Remediation》2015,35(3):89-100

This paper presents the largest In Situ Thermal Desorption (ISTD) project completed to date. The redevelopment of a former aerospace manufacturing facility adjacent to a commercial airport was the main driver, requiring relatively rapid reduction of several chlorinated volatile organic compounds (CVOC) in a 3.2‐acre source zone. The source zone was divided into four quadrants with differing treatment depths, heated simultaneously using a total of 907 thermal conduction heater wells. Five different depths were selected across the area, according to the depth of contaminant impact. Prior to implementation, a risk and optimization study led to placement of a vertical sheet‐pile wall around the treatment zone to minimize groundwater flow, and a pilot test of a novel direct‐drive method for installation of the heater casings. Because of a shallow water table, a layer of clean fill was placed over the treatment zone, and partial dewatering was necessary prior to heating. A network of vertical multiphase extraction wells and horizontal vapor extraction wells was used to establish hydraulic and pneumatic control and to capture the contaminants. The site was split into four decision units, each with a rigorous soil sampling program which included collecting a total of 270 confirmatory soil samples from locations with the highest pretreatment CVOC concentrations requiring reduction to below 1 mg/kg for each contaminant. Temperature monitoring and mass removal trends were used to trigger the sampling events. Eventually, a small area near the center of the site required the installation of four additional heaters before the soil goals were reached after 238 days of heating. The total energy usage for heating and treating the source area was 23 million kWh—slightly lower than the estimated 26.5 million kWh. Actual energy losses and the energy removal associated with the extracted steam were lower than anticipated. An estimated 13,400 kg (29,800 lbs) of CVOC mass was removed, and all soil goals were met. This paper presents the challenges associated with a project of this scale and describes the solutions to successfully complete the ISTD remedy.  相似文献   

Preface     

Parker MacCready  David A. Jay 《Continental Shelf Research》2009

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Virus occurrence in private and public wells in a fractured dolostone aquifer in Canada     

Amy S. Allen  Mark A. Borchardt  Burney A. KiekeJr  Kari E. Dunfield  Beth L. Parker 《Hydrogeology Journal》2017,25(4):1117-1136

Groundwater samples from 22 wells completed in a regional fractured dolostone aquifer in the Guelph region of southern Ontario, Canada, were collected over an 8-month period and analyzed for viruses and Campylobacter jejuni. Only 8% of the 118 samples exhibited viruses at extremely low concentrations, but of the 22 wells sampled, 10 (45%) were positive for human enteric viruses (polyomavirus, adenovirus A, and GII norovirus) including 5 of the 8 public supply wells (62.5%) and 5 of the 11 private wells (45%). Each virus-positive well had only one virus occurrence with six sampling events during the 8-month sampling campaign and only one virus type was detected in each well. The probability of virus detection was positively associated with well open-interval length. Virus concentration (in the wells that were virus-positive) was negatively associated with well depth and open-interval length and positively associated with overburden thickness (i.e., the thickness of unconsolidated materials overlying bedrock facies) and the amount of precipitation 8–14 and 15–21 days prior to the sampling date. The ephemeral nature of the virus detections and the low detection rate on a per sample basis were consistent with previous studies. The percentage of virus-positive wells, however, was much higher than previous studies, but consistent with the fact that the hydrogeologic conditions of fractured bedrock aquifers create wide capture zones and short groundwater travel times to wells making them more vulnerable to contamination occurrence but at very low concentrations.  相似文献   

When plenty is not enough: an assessment of the white stumpnose (Rhabdosargus globiceps) fishery of Saldanha Bay,South Africa     

D Parker  SE Kerwath  TF Næsje  CJ Arendse  FJ Keulder-Stenevik  K Hutchings 《African Journal of Marine Science》2017,39(2):153-166

White stumpnose Rhabdosargus globiceps is the main target of the linefishery in Saldanha Bay. Increased fishing pressure over the last three decades, particularly by the recreational sector, has led to concerns regarding sustainability of the local white stumpnose stock. The fishery was exceptionally productive between 2006 and 2008, with an estimated annual catch of 141.2 tonnes (t). Only 3% of boat outings surveyed were commercial boats targeting white stumpnose, yet this sector accounted for 39.3 t (31%) of the average annual catch. The recreational boat sector accounted for most of the catch (70.0 t), and the recreational shore sector the least (31.9 t). Commercial boat catch per unit effort (CPUE; 3.7 fish angler^–1 h^–1) was more than 10 times that of recreational boats (0.3 fish angler^–1 h^–1). White stumpnose catch length-frequency differed significantly (p < 0.01) between the fishing sectors, with the commercial sector retaining larger fish (34.7 cm [SD 5.9]) than the recreational boat (33.9 cm [SD 5.9]) and shore (30.4 cm [SD 5.8]) sectors. A decline in commercial CPUE (2000–2015) of approximately 40% and a concomitant severe decline (>95%) in survey data for juvenile white stumpnose CPUE (2007–2016) indicate that the current rate of exploitation is not sustainable. Recovery of the white stumpnose stock will require a decrease in fishing mortality. Possible management regulations include sector-specific effort limitations, extending the ‘no take’ marine protected area, reducing the recreational-sector bag limit to 5 fish person^–1 day^–1, implementing a commercial-sector bag limit, and increasing the minimum size limit to 30 cm TL.  相似文献   

The effects of variability in bank material properties on riverbank stability: Goodwin Creek, Mississippi   总被引：1，自引：1，他引：0  

Chris Parker  Andrew Simon  Colin R. Thorne 《Geomorphology》2008,101(4):533-543

Bank retreat is an important area of research within fluvial geomorphology and is a land management problem of global significance. The Yazoo River Basin in Mississippi is one example of a system which is experiencing excessive erosion and bank instability. The properties of bank materials are important in controlling the stability of stream banks and past studies have found that these properties are often variable spatially. Through an investigation of bank material properties on a stretch of Goodwin Creek in the Yazoo Basin, Mississippi, this study focuses on: i) how and why effective bank material properties vary through different scales; ii) how this variation impacts on the outputs from a bank stability model; and iii) how best to appropriately represent this variability within a bank stability model.The study demonstrates the importance that the variability of effective bank material properties has on bank stability: at both the micro-scale within a site, and at the meso-scale between sites in a reach. This variability was shown to have important implications for the usage of the Bank Stability and Toe Erosion Model (BSTEM), a deterministic bank stability model that currently uses a single value to describe each bank material property. As a result, a probabilistic representation of effective bank material strength parameters is recommended as a potential solution for any bank stability model that wishes to account for the important influence of the inherent variability of soil properties.  相似文献   

The influence of correlated crustal signals in modelling the main geomagnetic field   总被引：2，自引：0，他引：2  

C. Rygaard-Hjalsted  C. G. Constable  R. L. Parker 《Geophysical Journal International》1997,130(3):717-726

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Reflections on Macrophysics and the Sun (Special Historical Review)     

Parker  E. N. 《Solar physics》1997,176(2):219-247

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S. Chandrasekhar and magnetohydrodynamics     

E. N. Parker 《Journal of Astrophysics and Astronomy》1996,17(3-4):147-166

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Book review     

Harry M. Parker 《Mathematical Geology》1988,20(7):899-903

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