Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

The behavior of trace elements during schwertmannite precipitation and subsequent transformation into goethite and jarosite   总被引：5，自引：0，他引：5  

Patricia Acero  Carlos Ayora  José-Miguel Nieto 《Geochimica et cosmochimica acta》2006,70(16):4130-4139

Schwertmannite is a ubiquitous mineral formed from acid rock drainage (ARD), and plays a major role in controlling the water chemistry of many acid streams. The formation of schwertmannite was investigated in the acid discharge of the Monte Romero abandoned mine (Iberian Pyrite Belt, SW, Spain). Schwertmannite precipitated from supersaturated solutions mainly owing to the oxidation of Fe(II) to Fe(III) and transformed with time into goethite and jarosite. In a few hours, schwertmannite precipitation removed more than half of the arsenic load from solution, whereas the concentration of divalent trace metals (Zn, Cu, Pb, Cd, Ni, and Co) remained almost unchanged. In the laboratory, natural schwertmannite was kept in contact with its coexisting acid water in a flask with a solid-liquid mass ratio of 1:5 for 353 days. During this time, the pH of the solution dropped from 3.07 to 1.74 and the concentrations of sulfate and Fe increased. During the first 164 days, schwertmannite transformed into goethite plus H₃O-jarosite but, subsequently, goethite was the only mineral to form. Some of the trace elements, such as Al, Cu, Pb, and As were depleted in solution during the first stage as schwertmannite transformed into goethite plus H₃O-jarosite. On the contrary, the transformation of schwertmannite to goethite (with no jarosite) during the second stage released Al, Cu, and As to the solution. Despite the variation in their concentrations in solution, approximately 80% of the total Al and Cu inventories and more than 99% As and Pb remained in the solid phase throughout the entire aging process.  相似文献   

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo R?islien  Henning Omre 《Mathematical Geology》2006,38(7):821-849

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.  相似文献   

Late Early Miocene lake deposits near Mauensee, central Switzerland: Fish fauna (otoliths, teeth), accompanying biota and palaeoecology     

Jürg Jost  Daniel K?lin  Tanja Schulz-Mirbach  Bettina Reichenbacher 《Eclogae Geologicae Helvetiae》2006,99(3):309-326

  相似文献   

韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例   总被引：6，自引：0，他引：6  

戚学祥李海兵  吴才来陈松永 《地质通报》2005,24(3):252-257

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。  相似文献   

Direct observations of aluminosilicate weathering in the hyporheic zone of an Antarctic Dry Valley stream   总被引：1，自引：0，他引：1  

Patricia A. Maurice  Diane M. McKnightLaura Leff  Julia E. FulghumMichael Gooseff 《Geochimica et cosmochimica acta》2002,66(8):1335-1347

This study focused on chemical weathering and bacterial ecology in the hyporheic zone of Green Creek, a McMurdo Dry Valley (Antarctica) stream. An in situ microcosm approach was used to observe dissolution features on the basal-plane surface of muscovite mica. Four mica chips were buried in December 1999 and dug up 39 d later. Atomic force microscopy (AFM) of the basal-plane surfaces revealed small, anhedral ∼10-Å-deep etch pits covering ∼4% of the surfaces, from which an approximate basal-plane dissolution rate of 8.3 × 10⁻¹⁸ mol muscovite cm⁻² s⁻¹ was calculated (on the basis of the geometric surface area) for the study period. This is an integrated initial dissolution rate on a fresh surface exposed for a relatively brief period over the austral summer and should not be compared directly to other long-term field rates. The observation of weathering features on mica agrees with previous stream- and watershed-scale studies in the Dry Valleys, which have demonstrated that weathering occurs where liquid water is present, despite the cold temperatures.AFM imaging of mica surfaces revealed biofilms including numerous small (<1 μm long), rounded, oblong bacteria. The AFM observations agreed well with X-ray photoelectron microscopy results showing increased organic C and N. Bacteriologic analysis of the hyporheic zone sediments also revealed <1-μm-long bacteria. α-Proteobacteria were observed, consistent with the oligotrophic conditions of the hyporheic zone. Nitrate-reducing bacteria were found, in agreement with a previous tracer test at Green Creek that suggested nitrate reduction occurs in the hyporheic zone. The results of this study thus provide direct evidence of dynamic geochemical and microbial processes in the hyporheic zone of a Dry Valley stream despite the extreme conditions; such processes were inferred previously from stream-scale hydrogeochemical studies.  相似文献   

新时期我国区域经济地理学发展问题初探   总被引：4，自引：0，他引：4  

刘曙光 《地域研究与开发》2002,21(2):1-4

我国新时期的区域经济地理学在取得全面发展的同时，在理论体系，研究方法和实践领域等方面还需要进一步的发展，文章根据学习和实践区域经济地理学的体会，初步提出基础理论和应用理论，思维方法和技术方法等方面发展见解，并指出区域创新系统和国际经济技术合作等学科应注意拓展的重要实践领域，最后提出我国区域经济地理学科发展的建议。  相似文献   

华南地区凉果加工业与凉果资源的匹配关系分析——以广东省新兴县为例     

刘一明  胡新艳  牛宝俊 《地域研究与开发》2002,21(2):60-63

文章以广东省新兴县为例，从凉果资源分布与加工能力的匹配关系角度对华南地区凉果资源的分布，凉果加工业的分布与布局，凉果市场分布与竞争力，凉果加工业与资源的匹配关系等进行了分析，并针对华南地区凉果加工业面临的主要问题提供了一些建议。  相似文献   

成都市民消费结构与休闲活动关系研究   总被引：6，自引：0，他引：6  

杨国良 《地域研究与开发》2002,21(2):77-80

城市居民消费水平，消费结构会影响其休闲消费能力，消费意愿，消费方式，消费态度和休闲时空结构，文章以成都市7个城区歌舞，茶棋牌，电影及城市公园休闲活动调查为基础，探讨了城市居民消费结构及其变化与休闲活动特征的关系。研究结果表明，城市居民消费结构的改变对歌舞，茶棋牌娱乐活动影响最大。  相似文献   

南水北调中线工程建设与河南水资源可持续利用   总被引：2，自引：0，他引：2  

赵永江  刘荷芬  贾虎 《地域研究与开发》2002,21(2):85-88

文章通过对河南省水资源开发利用现状，存在的主要问题，水资源供需平衡以及南水北调工程对河南省水资源利用的影响论述，提出了在拟定南水北调工程供水方案中，应通过强化节水，加强水资源保护，严格控制地下水开采，将水资源作为商品等措施，促进河南省水资源的可持续开发利用。  相似文献