The kinetics of iodide oxidation by the manganese oxide mineral birnessite     

Patricia M. Fox  James A. Davis 《Geochimica et cosmochimica acta》2009,73(10):2850-11620

The kinetics of iodide (I⁻) and molecular iodine (I₂) oxidation by the manganese oxide mineral birnessite (δ-MnO₂) was investigated over the pH range 4.5-6.25. I⁻ oxidation to iodate proceeded as a two-step reaction through an I₂ intermediate. The rate of the reaction varied with both pH and birnessite concentration, with faster oxidation occurring at lower pH and higher birnessite concentration. The disappearance of I⁻ from solution was first order with respect to I⁻ concentration, pH, and birnessite concentration, such that −d[I⁻]/dt = k[I⁻][H⁺][MnO₂], where k, the third order rate constant, is equal to 1.08 ± 0.06 × 10⁷ M⁻² h⁻¹. The data are consistent with the formation of an inner sphere I⁻ surface complex as the first step of the reaction, and the adsorption of I⁻ exhibited significant pH dependence. Both I₂, and to a lesser extent, sorbed to birnessite. The results indicate that iodine transport in mildly acidic groundwater systems may not be conservative. Because of the higher adsorption of the oxidized I species I₂ and , as well as the biophilic nature of I₂, redox transformations of iodine must be taken into account when predicting I transport in aquifers and watersheds.  相似文献   

AGB variables and the Mira period–luminosity relation     

Patricia A. Whitelock  Michael W. Feast  Floor van Leeuwen 《Monthly notices of the Royal Astronomical Society》2008,386(1):313-323

Published data for large-amplitude asymptotic giant branch variables in the Large Magellanic Cloud (LMC) are re-analysed to establish the constants for an infrared ( K ) period–luminosity relation of the form   M _K =ρ[log  P − 2.38]+δ  . A slope of  ρ=−3.51 ± 0.20  and a zero-point of  δ=−7.15 ± 0.06  are found for oxygen-rich Miras (if a distance modulus of 18.39 ± 0.05 is used for the LMC). Assuming this slope is applicable to Galactic Miras we discuss the zero-point for these stars using the revised Hipparcos parallaxes together with published very long baseline interferometry (VLBI) parallaxes for OH masers and Miras in globular clusters. These result in a mean zero-point of  δ=−7.25 ± 0.07  for O-rich Galactic Miras. The zero-point for Miras in the Galactic bulge is not significantly different from this value.
Carbon-rich stars are also discussed and provide results that are consistent with the above numbers, but with higher uncertainties. Within the uncertainties there is no evidence for a significant difference between the period–luminosity relation zero-points for systems with different metallicity.  相似文献   

The coating hypothesis for ammonia ice particles in Jupiter: Laboratory experiments and optical modeling     

Konstantinos S. Kalogerakis  Jochen Marschall  Patricia A. Engel  Rhiannon T. Meharchand  Michael H. Wong 《Icarus》2008,196(1):202-215

We report laboratory experiments and modeling calculations investigating the effect of a hydrocarbon coating on ammonia ice spectral signatures. Observational evidence and thermochemical models indicate an abundance of ammonia ice clouds in Jupiter's atmosphere. However, spectrally identifiable ammonia ice clouds are found covering less than 1% of Jupiter's atmosphere, notably in areas of strong vertical transport, indicating a short lifetime for the signature of ammonia absorption on condensed ammonia particles [Baines, K.H., Carlson, R.W., Kamp, L.W., 2002. Icarus 159, 74-94]. Current literature has suggested coating of ammonia ice particles by a hydrocarbon haze as a possible explanation for this paradox. The work presented here supports the inference of a coating effect that can alter or suppress ammonia absorption features. In the experiments, thin films of ammonia ices are deposited in a cryogenic apparatus, coated with hydrocarbons, and characterized by reflection-absorption infrared spectroscopy. We have observed the effects on the ammonia ice absorption features near 3 and 9 μm with coverage by thin layers of hydrocarbons. Modeling calculations of these multilayer thin films assist in the interpretation of the experimental results and reveal the important role of optical interference in altering the aforementioned ammonia spectral features. Mie and T-matrix scattering calculations demonstrate analogous effects for ammonia ice particles and investigate the relative effects of ammonia ice particle size, shape, and coating layer thickness on the ice particle spectral signatures.  相似文献   

Vulnerability assessment in urban areas exposed to flood risk: methodology to explore green infrastructure benefits in a simulation scenario involving the Cañaveralejo River in Cali,Colombia     

López-Valencia  Adriana Patricia 《Natural Hazards》2019,99(1):217-245

Natural Hazards - Building resilient infrastructure is one of the major challenges faced by cities due to increasing urbanization rates and climate change. Furthermore, the application of...  相似文献   

The Influence of Place on the Willingness to Pay for Ecosystem Services     

Max Nielsen-Pincus  Patricia Sussman  Drew E. Bennett  Hannah Gosnell  Robert Parker 《社会与自然资源》2017,30(12):1423-1441

Sense of place, including an individual’s attitudes toward specific geographic settings, is generally predicted to influence willingness to engage in place-protective behaviors. Relatively little research, however, has empirically examined the influence of people’s attitudes toward a place on their willingness to pay for environmental protection. Using the example of a payment for ecosystem services (PES) initiative in the McKenzie River watershed, Oregon, USA, we found that place attitudes were a significant predictor of respondents’ willingness to pay for a program designed to benefit drinking water quality. These results suggest that connecting conservation actions to landscapes that are meaningful to people may increase their financial support for PES and other conservation programs. While program managers have little or no influence over stakeholders’ political ideology, gender, or income, managers may be able to influence prospective PES buyers’ awareness and attitudes through targeted communications, thereby potentially increasing support for place-based conservation efforts.  相似文献   

Analysis of Thomsen parameters for finely layered VTI media   总被引：2，自引：0，他引：2  

James G. Berryman  Vladimir Y. Grechka  & Patricia A. Berge 《Geophysical Prospecting》1999,47(6):959-978

Since the work of Postma and Backus, much has been learned about elastic constants in vertical transversely isotropic (VTI) media when the anisotropy is due to fine layering of isotropic elastic materials. Nevertheless, there has continued to be some uncertainty about the possible range of Thomsen's anisotropy parameters ε and δ for such media. We use both Monte Carlo studies and detailed analysis of Backus' equations for both two- and three-component layered media to establish the results presented. We show that ε lies in the range ?3/8 ε ½[〈v²_p〉〈v^?2_p〉?1], for finely layered media; smaller positive and all negative values of ε occur for media with large fluctuations in the Lamé parameter λ in the component layers. We show that δ can also be either positive or negative, and that for constant density media, sign (δ) = sign (〈v^?2_p〉 ? 〈v^?2_s〉〈v²_s/v²_p〉). Monte Carlo simulations show that among all theoretically possible random media, positive and negative δ are equally likely in finely layered media. (Of course, the δs associated with real earth materials may span some smaller subset of those that are theoretically possible, but answering this important question is beyond our present scope.) Layered media having large fluctuations in λ are those most likely to have positive δ. This is somewhat surprising since ε is often negative or a small positive number for such media, and we have the general constraint that ε ? δ > 0 for layered VTI media. Since Gassmann's results for fluid-saturated porous media show that the mechanical effects of fluids influence only the Lamé parameter λ, not the shear modulus μ, these results suggest that small positive δ occurring together with small positive ε (but somewhat larger than δ) may be indicative of changing fluid content in a layered earth.  相似文献   

Reply to ‘Wolf‐triggered trophic cascades and stream channel dynamics in Olympic National Park: a comment on East et al. (2017)’ by Robert Beschta and William Ripple          下载免费PDF全文

Amy E. East  Kurt J. Jenkins  Patricia J. Happe  Jennifer A. Bountry  Timothy J. Beechie  Mark C. Mastin  Joel B. Sankey  Timothy J. Randle 《地球表面变化过程与地形》2018,43(4):936-939

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The role of antecedent groundwater heads in controlling transient aquifer storage and flood peak attenuation in karst watersheds     

Patricia Spellman  Jason Gulley  Jonathan B. Martin  Jeremy Loucks 《地球表面变化过程与地形》2019,44(1):77-87

Transient storage of floodwaters in aquifers is known to attenuate peak flows in rivers and drive subsurface dissolution. Transient aquifer storage could be enhanced in watersheds overlying karst aquifers where caves facilitate surface and groundwater exchange. Few studies, however, have examined controls on, or magnitudes of, transient aquifer storage or flood peak attenuation in karstic watersheds. Here we evaluate flood peak attenuation with multiple linear regression analyses of 10 years of river and groundwater data from the Suwannee River, which flows over the karstic upper Floridan aquifer in north-central Florida and experiences frequent flooding. Regressions show antecedent river stage exerts the dominant control on magnitudes of transient aquifer storage, with recharge and time to peak having secondary controls. Specifically, low antecedent stages result in larger magnitudes of transient aquifer storage and thus greater flood attenuation than conditions of elevated antecedent stage. These findings suggest subsurface weathering, including cave formation and enlargement, caused by transient aquifer storage could occur on a more frequent basis in aquifers where groundwater table elevation is lowered due to anthropogenic or climatic influences. Our work also shows that measures of groundwater table elevation prior to an event could be used to improve predictive flood models. © 2018 John Wiley & Sons, Ltd.  相似文献   

Benthic Community Structure and Sediment Properties in Barnegat Bay,New Jersey,Before and After Hurricane Sandy     

Gary L. Taghon  Patricia A. Ramey  Charlotte M. Fuller  Rosemarie F. Petrecca  Judith P. Grassle 《Estuaries and Coasts》2017,40(1):160-172

Hurricane Sandy was an extraordinarily large storm that affected most of the eastern coast of the USA in October 2012. To assess this storm’s impact, the benthic invertebrate community structure and sediment properties were compared in samples collected 3.5 months prior to (July 2012) and 8 months after (July 2013) the hurricane at 97 locations in Barnegat Bay, New Jersey, USA. Barnegat Bay is a shallow back-barrier estuary just north of where Sandy made landfall. For all locations taken together, sediment total nitrogen concentration was lower afterwards, while total organic carbon and total phosphorus concentrations were similar. Sediment median particle size was the same before and after, but the sediment was better sorted after the storm. There were no differences in total abundance of invertebrates, species richness, species diversity, or the abundance of polychaetes, bivalves, or gastropods. Malacostracan crustaceans were more abundant after Sandy (average 82 (0.04 m²)^?1) than they were before (average 64), due almost entirely to increased abundance of ampeliscid amphipods, which showed a shift toward smaller sizes in 2013. Annelids in the order Clitellata were on average less abundant after the hurricane (17) than before (53). The apparent minimal effect of Sandy on the benthic community in Barnegat Bay was probably because the passage of the hurricane had no detectable effects on salinity or dissolved oxygen concentrations throughout the bay.  相似文献   

Comparison of web plate numerical models for self‐centering steel plate shear walls          下载免费PDF全文

Patricia M. Clayton  Ching‐Yi Tsai  Jeffrey W. Berman  Laura N. Lowes 《地震工程与结构动力学》2015,44(12):2093-2110

Previous research has shown that self‐centering steel plate shear walls (SC‐SPSWs) are capable of achieving enhanced seismic performance at multiple hazard levels, including recentering following design‐level earthquakes. When modeling SC‐SPSWs numerically, these studies considered an idealized tension‐only steel plate shear wall (SPSW) web plate behavior. Research has shown that web plate behavior is more complex than predicted by the idealized model, and web plates can provide more strength, stiffness, and energy dissipation than predicted by the idealized model. The idealized model of web plate behavior is used widely in SPSW numerical models where the moment‐resisting boundary frame provides supplemental hysteretic damping and stiffness; however, in SC‐SPSWs, where the post‐tensioned boundary frame is designed to remain elastic during an earthquake, accounting for the more complex web plate behavior can have a significant impact on seismic performance estimates from numerical simulation. This paper presents different methods for modeling SC‐SPSWs. Responses from these models are compared with experimental results. A simple modification of the tension‐only model, referred to as the tension‐compression strip model, is shown to provide a reasonable approximation of SC‐SPSW behavior. Results from nonlinear response history analyses of SC‐SPSWs with the tension‐only and tension‐compression web plate models are compared to assess how the approximation of web plate behavior affects SC‐SPSW seismic performance. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献