A procedure to identify natural arsenic sources,applied in an affected area in North Rhine-Westphalia,Germany     

Andre Banning  Wilhelm Georg Coldewey  Patricia Göbel 《Environmental Geology》2009,57(4):775-787

The aim of the study was to identify the geogenic source for elevated arsenic (As) concentrations recently discovered in soils of the Heubach plain, North Rhine-Westphalia, Germany. Therefore, a catalogue of conditions that an As source has to fulfil in order to be considered as geogenic was formulated, including the source’s linkage to the sink, its mineralogy, As total content, As mobilization potential, groundwater redox conditions and As output. Accordingly, mineralogical, geo- and hydrochemical investigations were carried out, including X-ray diffractometry, microscopy, ICP-OES and AAS analysis and a sequential extraction procedure. Paleo bog iron ores (PBIOs) of Tertiary age, occurring within unconsolidated sands (Haltern-layers, Santonian–Lower Campanian), and glauconitic marlstones (Dülmen-layers, Lower Campanian) were examined. Results indicate that output from the PBIOs is responsible for the elevated As levels. Accounting their diverse mineralogy, five types of PBIOs were defined. Type-dependent, they at least partly fulfil all of the formulated requirements. The relations and behaviour of As sources and sinks in space and time could be clarified for the area of interest. The approach presented in this paper may offer a tool for identifying natural As sources worldwide.  相似文献   

Concentrations of trace elements in blood and skin of Florida manatees (Trichechus manatus latirostris)     

Stavros HC  Bonde RK  Fair PA 《Marine pollution bulletin》2008,56(6):1221-1225

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A multispecies virtual population analysis of the eastern Bering Sea   总被引：4，自引：1，他引：3  

Livingston  Patricia A.; Jurado-Molina  Jesus 《ICES Journal of Marine Science》2000,57(2):294-299

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Apparent downwind depletion of volcanic SO<Subscript>2</Subscript> flux—lessons from Masaya Volcano,Nicaragua     

Patricia A. Nadeau  Glyn Williams-Jones 《Bulletin of Volcanology》2009,71(4):389-400

A series of 707 measurements at Masaya in 2005, 2006, and 2007 reveals that SO₂ emissions 15km downwind of the active vent appear to be ~33% to ~50% less than those measured only 5km from the vent. Measurements from this and previous studies indicate that dry deposition of sulfur from the plume and conversion of SO₂ to sulfate aerosols within the plume each may amount to a maximum of 10% loss, and are not sufficient to account for the larger apparent loss measured. However, the SO₂ measurement site 15km downwind is located on a ridge over which local trade winds, and the entrained plume, accelerate. Greater wind speeds cause localized dilution of the plume along the axis of propagation. The lower concentrations of SO₂ measured on the ridge therefore lead to calculations of lower fluxes when calculated at the same plume speed as measurements from only 5km downwind, and is responsible for the apparent loss of SO₂. Due to the importance of SO₂ emission rates with respect to hazard mitigation, petrologic studies, and sulfur budget calculations, measured fluxes of SO₂ must be as accurate as possible. Future campaigns to measure SO₂ flux at Masaya and similar volcanoes will require individual plume speed measurements to be taken at each flux measurement site to compensate for dilution and subsequent calculation of lower fluxes. This study highlights the importance of a comprehensive understanding of a volcano’s interaction with its surroundings, especially for low, boundary layer volcanoes.  相似文献   

Hydrodynamic accumulation of Karenia off the west coast of Florida     

Richard P. Stumpf  R. Wayne Litaker  Lyon Lanerolle  Patricia A. Tester 《Continental Shelf Research》2008

Blooms of the toxic dinoflagellates, Karenia spp. occur nearly annually in the eastern Gulf of Mexico with cell abundances typically >10⁵ cells L⁻¹. Thermal and ocean color satellite imagery shows sea surface temperature patterns indicative of upwelling events and the concentration of chlorophyll at fronts along the west Florida continental shelf. Daily cell counts of Karenia show greater increases in cell concentrations at fronts than can be explained by Karenia's maximum specific growth rate. This is observed in satellite images as up to a 10-fold greater increase in chlorophyll biomass over 1–2 d periods than can be explained by in situ growth. In this study, we propose a model that explains why surface blooms of Karenia may develop even when nutrients on the west Florida shelf are low. In the summer, northward winds produce a net flow east and southeast bringing water and nutrients from the Mississippi River plume onto the west Florida shelf at depths of 20–50 m. This water mass supplies utilizable inorganic and organic forms of nitrogen that promote the growth of Karenia to pre-bloom concentrations in sub-surface waters in the mid-shelf region. In the fall, a change to upwelling favorable winds produces onshore transport. This transport, coupled with the swimming behavior of Karenia, leads to physical accumulation at frontal regions near the coast, resulting in fall blooms. Strong thermal fronts during the winter provide a mechanism for re-intensification of the blooms, if Karenia cells are located north of the fronts. This conceptual model leads to testable hypotheses on bloom development throughout the Gulf of Mexico.  相似文献   

Diatom thanatocoenosis in a middle Galician Ría: Spatial patterns and their relationship to the seasonal diatom cycle in the water column and hydrographic conditions     

Patricia Bernrdez  Ricardo Prego  Manuel Varela  Guillermo Francs 《Continental Shelf Research》2008,28(17):2496-2508

Modern diatom distribution patterns in the surface sediment of the Ferrol Ría and their relationship to the hydrography and diatom patterns in the water column were studied to determine the hydrographic influence on the record of these biogenic components. Diatom abundance in the water column was assessed for different oceanographic periods and compared with the biosiliceous sedimentary record. Very low abundances were found in the water column during the winter, whereas in spring and summer, diatoms proliferated. Chaetoceros spp. formed the bulk of the water column community during spring and summer, followed by Thalassionema nitzschioides and Rhizosolenia spp. Nitzschia longissima represented a significant portion of the winter assemblage, together with Paralia sulcata and benthic taxa. Leptocylindrus danicus, N. longissima and Skeletonema costatum characterized the autumn campaign, when stratification of the waters occurs, with L. danicus being especially abundant in the outer ría.Seasonal hydrographic and associated productivity patterns govern the abundance and assemblage of the diatoms preserved in surface sediments. Samples located in the inner ría area and its margins exhibited the highest abundances of diatoms, and were primarily dominated by benthic species. The freshwater group, crysophycean cysts and phytoliths were present in the landward stations influenced by river runoff. The middle ría was characterized by P. sulcata and Thalassiosira spp., with minor occurrences of the benthic and freshwater group. Chaetoceros R.S., L. danicus R.S. and T. nitzschioides typified the outer ría, an assemblage that corresponds to nutrient-rich coastal areas of high productivity influenced by oceanic waters, demonstrating the impact of oceanic waters flowing into the embayment due to enhanced tidal mixing through the narrow channel. Therefore, sediment diatom assemblages reflect diatom production patterns in the water column of the Ría. However, we must proceed with caution when interpreting the paleorecord in the inner area due to the high contribution of allochthonous taxa, which is indicative of low water depths. This paper contributes to a better understanding of diatom thanatocoenosis in the Galician Rías, where very few studies of this kind have been done to date.  相似文献   

Sediment dynamics in the Gulf of Lions: The impact of extreme events     

Xavier Durrieu de Madron  Patricia L. Wiberg  Pere Puig 《Continental Shelf Research》2008

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Trace element concentrations in blood of free-ranging bottlenose dolphins (Tursiops truncatus): influence of age, sex and location     

Stavros HC  Bossart GD  Hulsey TC  Fair PA 《Marine pollution bulletin》2008,56(2):371-379

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Coloring and preservation state of faunal remains from the neanderthal levels of Kůlna Cave,Czech republic     

Vronique Michel  Herv Bocherens  Isabelle Thry‐Parisot  Karel Valoch  Patricia Valensi 《Geoarchaeology》2006,21(5):479-501

The preservation process of faunal remains from the Middle Paleolithic levels of Kůlna Cave was studied within a taphonomic and palaeodietary framework. A visual examination of bones and teeth showed that they display a wide variety of colors. Chemical analyses (C, N, Fe, Mn) and a combination of analytical techniques, such as Fourier transform infrared (FT‐IR), X‐ray diffraction (XRD), and electron spin resonance (ESR) spectrometry, were conducted on 13 fossil remains. The crystallinity indexes, IR‐SF, XRD‐CI, XRD‐L200, the IR area band (Amide I), and the ESR analyses showed that the bones were not burned at a temperature higher than 200°C. This implies that the bone remains were not used as fuel by Neanderthals at Kůlna Cave. Coloring in these bones is largely due to the presence of Mn and Fe. © 2006 Wiley Periodicals, Inc.  相似文献   

Building sandstone surface modification by biofilm and iron precipitation: emerging block‐scale heterogeneity and system response          下载免费PDF全文

Stephen McCabe  Daniel McAllister  Patricia A. Warke  Miguel Gomez‐Heras 《地球表面变化过程与地形》2015,40(1):112-122

Stone surfaces are sensitive to their environment. This means that they will often respond to exposure conditions by manifesting a change in surface characteristics. Such changes can be more than simply aesthetic, creating surface/subsurface heterogeneity in stone at the block scale, promoting stress gradients to be set up as surface response to, for example, temperature fluctuations, can diverge from subsurface response. This paper reports preliminary experiments investigating the potential of biofilms and iron precipitation as surface‐modifiers on stone, exploring the idea of block‐scale surface‐to‐depth heterogeneity, and investigating how physical alteration in the surface and near‐surface zone can have implications for subsurface response and potentially for long‐term decay patterns. Salt weathering simulations on fresh and surface‐modified stone suggest that even subtle surface modification can have significant implications for moisture uptake and retention, salt concentration and distribution from surface to depth, over the period of the experimental run. The accumulation of salt may increase the retention of moisture, by modifying vapour pressure differentials and the rate of evaporation. Temperature fluctuation experiments suggest that the presence of a biofilm can have an impact on energy transfer processes that occur at the stone surface (for example, buffering against temperature fluctuation), affecting surface‐to‐depth stress gradients. Ultimately, fresh and surface‐modified blocks mask different kinds of system, which respond to inputs differently because of different storage mechanisms, encouraging divergent behaviour between fresh and surface‐modified stone over time. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献