Sites occupancy of Fe3+ in Garfield Nontronite: A spectroscopic study     

Dominique Bonnin  Georges Calas  Hélène Suquet  Henri Pezerat 《Physics and Chemistry of Minerals》1985,12(1):55-64

New data on the structure of Garfield nontronite have been produced by the use of different spectroscopic techniques: Mössbauer spectroscopy, optical spectroscopy, X-ray absorption edges and EXAFS and NMR. The tetrahedral iron content is found to be no higher than 1 percent. All iron atoms belong to the octahedral sheet excluding the possibility of the presence of non crystallized phases. Some ambiguities remain about the coherence of the octahedral sheet because of the presence of two doublets in the Mössbauer spectrum and at least two lineshapes in NMR spectra of OH which correspond to different environments.  相似文献   

The lead isotope systematics of ophiolite complexes     

Bruno Hamelin  Bernard Dupré  Claude J. Allègre 《Earth and Planetary Science Letters》1984,67(3):351-366

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Statistical analysis of isotopic ratios in MORB: the mantle blob cluster model and the convective regime of the mantle     

Claude J. Allègre  Bruno Hamelin  Bernard Dupré 《Earth and Planetary Science Letters》1984,71(1):71-84

A statistical examination of isotopic distributions for MORB from various ocean ridges leads to the “blob cluster model”, in which the oceanic crust accreting at ridges results from the mixing of two components within the ascending mantle. These are (1) upper mantle material and (2) discrete rising blobs of more radiogenic material. The blobs are fractionated to a variable degree and are distributed in the upper mantle circulation in a manner that is related to the spreading rate.(1) Themean values of the isotopic distributions allow us to calculate the probabilities of the two types of material within the mantle. The results show that theproportion of asthenospheric material in the mixtureincreases with the spreading rate, in agreement with the hypothesis of blob dilution within the upper mantle convection.Mass fluxes can be estimated for the rising blobs from these probabilities, which depend on the respective concentrations in the sources of the two types of material. If the blobs originate in the lower mantle, this flux estimation would suggest that a significant part of the lower mantle has been injected into the upper mantle during earth history.(2) Thestandard deviations of the distributions depend on the “efficiency” of the mixing process:the more imbricated are the asthenospheric and blob materials in the mixture,the smaller is theisotopic spread. This efficiency parameter is shown to increase with the spreading rate, as already suggested by previous comparisons between the East Pacific Rise and the Mid-Atlantic Ridge. Moreover, this feature may also be correlated with other data such as ridge bathymetric variations.  相似文献   

Finite strains from non-coaxial strain paths. I. Computational techniques     

Patrick J. Shore  Ian J. Duncan 《Tectonophysics》1984,110(1-2)

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Importance of the oxidation/maturation pair in the evolution of humic coals     

Landais Patrick  Marc Monthioux  Jean-Dominique Meunier 《Organic Geochemistry》1984,7(3-4)

The natural thermal evolution of type III coals (Humic origin) is expressed during diagenesis by a loss of oxygen as CO₂ and H₂O. Other phenomena such as oxidation can cause extensive geochemical modifications and may complicate the effects of simple maturation.Humic coals from the Jurassic in southeastern Utah were studied by elemental analysis, Rock-Eval pyrolysis and infrared spectroscopy. In a van Krevelen diagram (atomic H/C vs atomic O/C), the samples fall within the envelope defined by 860 reference humic coals covering the entire range of diagenesis. Nevertheless, various criteria (geochemical, petrographic, geological and microscopic) cast doubt upon the interpretation that such a distribution of coal composition results from thermal maturation.The same criteria indicate the intervention of redox phenomena. Comparison of our results with those from artificial and natural oxidation shows that these coals were subjected to an oxidation process different from ordinary late alteration. This process was probably due to circulation of highly oxidizing saline water causing oxygen fixation and the transformation of carboxyls into carboxylate anions. The cations that were fixed are oxygenated and certainly contain calcium, but also uranium and perhaps several other cations (V, Mo, Fe...). Emphasis is placed on possible mechanisms that cause such phenomena.  相似文献   

Policy and implementation in rural planning     

Paul Cloke  Patrick Hanrahan 《Geoforum》1984,15(2):261-269

Although often critical of the results achieved by rural planners, research by geographers and others has for some time been constrained by an inability to isolate the precise impacts of planning procedures on rural areas. The notions of a technically solvable ‘implementation problem’ and a politically complex ‘policy problem’ are confronted here, and acknowledgement of the latter directs research into the realms of decision-making and policy-implementation iteration in rural areas. Key themes in the understanding of these matters are those of central-local state relations, inter-agency relations and public-private sector relations, all of which should figure prominently in any conceptualisation of policymaking and implementation in rural areas. One final factor which invites conceptual clarification is that of the specificity of rurality as a policy-moulding phenomenon. The idea is introduced of a ‘rural dimension’ which presents a spatial facade to aspatial structures and processes.  相似文献   

A modified parameterization of flux-profile relationships in the surface layer using different roughness length values for heat and momentum   总被引：1，自引：0，他引：1  

Patrick Mascart  Joel Noilhan  Hervé Giordani 《Boundary-Layer Meteorology》1995,72(4):331-344

The surface-layer flux-profile formulae of Louis (1979), used in many atmospheric models, are modified in a simple way to allow for different values of the roughness lengths for heat and momentum. The modified set of formulae simplifies the calculation of surface-layer fluxes over most natural land surfaces, where the roughness length for momentum can be almost an order of magnitude greater than that for heat.  相似文献   

The two-step shape and timing of the last deglaciation in Antarctica   总被引：5，自引：0，他引：5  

J Jouzel  R Vaikmae  J R Petit  M Martin  Y Duclos  M Stievenard  C Lorius  M Toots  M A Mélières  L H Burckle  N I Barkov  V M Kotlyakov 《Climate Dynamics》1995,11(3):151-161

The two-step character of the last deglaciation is well recognized in Western Europe, in Greenland and in the North Atlantic. For example, in Greenland, a gradual temperature decrease started at the Bölling (B) around 14.5 ky BP, spanned through the Alleröd (A) and was followed by the cold Younger Dryas (YD) event which terminated abruptly around 11.5 ky BP. Recent results suggest that this BA/YD sequence may have extended throughout all the Northern Hemisphere but the evidence of a late transition cooling is still poor for the Southern Hemisphere. Here we present a detailed isotopic record analyzed in a new ice core drilled at Dome B in East Antarctica that fully demonstrates the existence of an Antarctic cold reversal (ACR). These results suggest that the two-step shape of the last deglaciation has a worldwide character but they also point to noticeable interhemispheric differences. Thus, the coldest part of the ACR, which shows a temperature drop about three times weaker than that recorded during the YD in Greenland, may have preceded the YD. Antarctica did not experienced abrupt changes and the two warming periods started there before they started in Greenland. The links between Southern and Northern Hemisphere climates throughout this period are discussed in the light of additional information derived from the Antarctic dust record.  相似文献   

Turbulent heat fluxes by profile and inertial dissipation methods: analysis of the atmospheric surface layer from shipboard measurements during the SOFIA/ASTEX and SEMAPHORE experiments     

Hélène Dupuis  Alain Weill  Kristina Katsaros  Peter K. Taylor 《Annales Geophysicae》1995,13(10):1065-1074

Heat flux estimates obtained using the inertial dissipation method, and the profile method applied to radiosonde soundings, are assessed with emphasis on the parameterization of the roughness lengths for temperature and specific humidity. Results from the inertial dissipation method show a decrease of the temperature and humidity roughness lengths for increasing neutral wind speed, in agreement with previous studies. The sensible heat flux estimates were obtained using the temperature estimated from the speed of sound determined by a sonic anemometer. This method seems very attractive for estimating heat fluxes over the ocean. However allowance must be made in the inertial dissipation method for non-neutral stratification. The SOFIA/ASTEX and SEMAPHORE results show that, in unstable stratification, a term due to the transport terms in the turbulent kinetic energy budget, has to be included in order to determine the friction velocity with better accuracy. Using the profile method with radiosonde data, the roughness length values showed large scatter. A reliable estimate of the temperature roughness length could not be obtained. The humidity roughness length values were compatible with those found using the inertial dissipation method.  相似文献   

Some Biases in Sampling Multilevel Piezometers for Volatile Organics     

J. F. Barker  G. C Patrick  L. Lemon  G. M. Travis 《Ground Water Monitoring & Remediation》1987,7(2):48-54

Multilevel piezometers are cost-effective monitoring devices for determining the three-dimensional distribution of solutes in ground water. Construction includes flexible tubing (plastic or Teflon®). Their sampling is subject to a number of'potential biases, particularly: (1) losses of volatile organic solutes via volatilization, (2) sorption onto the flexible tubing of the piezometers, (3) leaching of organics from this tubing, and (4) collection of unrepresentative samples due to inadequate piezometer flushing. It is shown that these biases are minimal or are easily controlled in most situations.
Another source of bias has been recognized. Organic solutes present in ground water above the screened level can penetrate the flexible plastic or Teflon tubing and contaminate the sampled water being drawn through this tubing. Laboratory tests and field results indicate this transmission causes low organic contaminant concentrations to be erroneously attributed to ground water which is free of such contaminants. The transmitted organics apparently desorb from the plastic tubing during flushing of even 40 piezometer volumes.
Recognition of this transmission problem provides for a better interpretation of existing organic contaminant distribution data. Caution is advised when considering the use of these monitoring devices in organic solute contaminant studies.  相似文献