Latitudinal variations in Titan’s methane and haze from Cassini VIMS observations     

Paulo F. Penteado  Caitlin A. Griffith  Steffi Engel  Lyn Doose  Robert H. Brown  Roger Clark  Christophe Sotin 《Icarus》2010,206(1):352-365

We analyze observations taken with Cassini’s Visual and Infrared Mapping Spectrometer (VIMS), to determine the current methane and haze latitudinal distribution between 60°S and 40°N. The methane variation was measured primarily from its absorption band at 0.61 μm, which is optically thin enough to be sensitive to the methane abundance at 20-50 km altitude. Haze characteristics were determined from Titan’s 0.4-1.6 μm spectra, which sample Titan’s atmosphere from the surface to 200 km altitude. Radiative transfer models based on the haze properties and methane absorption profiles at the Huygens site reproduced the observed VIMS spectra and allowed us to retrieve latitude variations in the methane abundance and haze. We find the haze variations can be reproduced by varying only the density and single scattering albedo above 80 km altitude. There is an ambiguity between methane abundance and haze optical depth, because higher haze optical depth causes shallower methane bands; thus a family of solutions is allowed by the data. We find that haze variations alone, with a constant methane abundance, can reproduce the spatial variation in the methane bands if the haze density increases by 60% between 20°S and 10°S (roughly the sub-solar latitude) and single scattering absorption increases by 20% between 60°S and 40°N. On the other hand, a higher abundance of methane between 20 and 50 km in the summer hemisphere, as much as two times that of the winter hemisphere, is also possible, if the haze variations are minimized. The range of possible methane variations between 27°S and 19°N is consistent with condensation as a result of temperature variations of 0-1.5 K at 20-30 km. Our analysis indicates that the latitudinal variations in Titan’s visible to near-IR albedo, the north/south asymmetry (NSA), result primarily from variations in the thickness of the darker haze layer, detected by Huygens DISR, above 80 km altitude. If we assume little to no latitudinal methane variations we can reproduce the NSA wavelength signatures with the derived haze characteristics. We calculate the solar heating rate as a function of latitude and derive variations of ∼10-15% near the sub-solar latitude resulting from the NSA. Most of the latitudinal variations in the heating rate stem from changes in solar zenith angle rather than compositional variations.  相似文献   

Archaeofacies analysis: Using depositional attributes to identify anthropic processes of deposition in a monumental shell mound of Santa Catarina State,southern Brazil     

Ximena S. Villagran  Paulo C.F. Giannini  Paulo DeBlasis 《Geoarchaeology》2009,24(3):311-335

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Evidences of Holocene transgression on Domingos Petrolini Swamp, southern coastal plain, Rio Grande do Sul, Brazil     

Soraia G. Bauermann  Paulo C. P. Neves  Marleni Marques-Toigo  Abdul R. Ashraf 《世界地质(英文版)》2005,8(1)

The Domingos Petrolini Swamp, located on the Southern Coastal Plain of Rio Grande do Sul, near the town of Rio Grande, constitutes an ample holocene lagoonal deposit. Events related to the holocene transgression and their diverse phases of glacial-eustatic ocillations were found through palynological analysis. Bases on these palynological data, four distinct phases to the paleoenvironmental evolution of the ecosystem were identified. It has also shown a transgressive restricted marine sequence on the base, which suggests the existence of a coastal brackish lagoon or a marisme type of environment. Later, there was a gradation for continentality conditions along with a scarce pollinical record. The third phase is characterized by the presence of marine components and halophyte vegetation, showing another transgressive event in that place. Lastly, the end of direct marine influence over the swamp was recorded and also the vegetation development as it appears these days.  相似文献   

Metal distribution in sediment cores from São Paulo State Coast, Brazil     

Silva PS  Damatto SR  Maldonado C  Fávaro DI  Mazzilli BP 《Marine pollution bulletin》2011,62(5):1130-1139

Ten sediment core samples with lengths ranging from 35 to 100 cm were collected in the Baixada Santista region and analyzed to determine As, Br, Co, Cr, Cs, Fe, Rb, Sb, Ta, Th, U, Zn and rare earths (Sc, Ce, Eu, La, Lu, Nd, Sm, Tb and Yb) level concentrations using instrumental neutron activation analysis (INAA). The studied region is located in the southeastern coast of São Paulo State and is comprised of a densely urbanized area, the largest industrial complex of the country, with a predominance of petrochemical and fertilizer plants. It is also home to Brazil’s most important and busiest port. The conclusions found that the As, La, Sm, Ne, Ce, Eu, Hf, Ta, Th, and U elements have a high background level in the region and that Fe and Zn were the main indicators of anthropogenic contribution in the sediments.  相似文献   

Local and remote responses to opposite Ross Sea ice anomalies: a numerical experiment with the CPTEC/INPE AGCM     

Christopher A. Cunningham  Jos�� Paulo Bonatti 《Theoretical and Applied Climatology》2011,106(1-2):23-44

This work examines the near-surface responses, in the Southern Hemisphere atmosphere, to a reduction and an excess of sea ice cover in the Ross Sea. Large ensembles (60 members) of the Atmospheric General Circulation Model of the Center for Weather Forecast and Climate Studies (AGCM-CPTEC) are used for this purpose. Locally, when the sea ice cover decreases (increases), heat fluxes, temperature, and pressure increase (decreases). A principal component analysis of temperature and geopotential height identifies the potential remote connections. We have found three main results: first, an association between the sea ice cover in the Ross Sea and a wave train that resembles the Pacific South American (PSA) pattern; second, a relationship between temperatures in the Ross Sea and in the southern South America; and third, an apparent correspondence between reduced sea ice cover in the Ross Sea and the subtropical jet over Australia.  相似文献   

Field observations of SPM using ADV, ADP, and OBS in a shallow estuarine system with low SPM concentration—Vitória Bay, SE Brazil     

Marcel G. Moura  Valeria S. Quaresma  Alex C. Bastos  Paulo Veronez Jr 《Ocean Dynamics》2011,61(2-3):273-283

The present study investigated direct and indirect methods using optical and acoustic instruments for the acquisition of information required to estimate the concentration of suspended particulate matter (SPM) in Vitória Bay, a shallow estuarine system in SE Brazil. The aim was to calibrate and compare the use of different instruments (OBS, ADP, and ADV) to estimate SPM concentration in the water column and near the bed. Concentration was determined by correlating filtered water samples with the optical and acoustic measurements. In general, the methodology proved tenable for the chosen shallow estuarine environment with low SPM concentration (<60?mg/L). Pearson’s coefficient ranged from 0.75 to 0.85, when correlating measurements taken at three sampled depths. Differences in the correlation coefficient values showed that calibration at three depths (near the bed, mid-water column, and near the surface) was more effective than for surface samples alone, even in shallow (???m deep) water. When calibration was attempted for concentration in the entire water column with samples at just one elevation, the correlation value was very low, thus increasing the error in estimating the SPM concentration.  相似文献   

P–T-Fluid evolution and graphite deposition during retrograde metamorphism in Ribeira Fold Belt,SE Brazil: Oxygen fugacity,fluid inclusions and C–O–H isotopic evidence     

Telmo M. Bento dos Santos  José M.U. Munhá  Colombo C.G. Tassinari  Fernando M. Noronha  Alexandra Guedes  Paulo E. Fonseca  Coriolano Dias Neto  Armanda Dória 《Journal of South American Earth Sciences》2011,31(1):93-109

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Selective chemical extraction of heavy metals in tailings and soils contaminated by mining activity: Environmental implications   总被引：1，自引：0，他引：1  

Paulo J.C. Favas  João Pratas  M. Elisa P. Gomes  V. Cala 《Journal of Geochemical Exploration》2011,111(3):160-171

Total concentrations of chemical elements in soils may not be enough to understand the mobility and bioavailability of the elements. It is important to characterise the degree of association of chemical elements in different physical and chemical phases of soil. Another geochemical characterisation methodology is to apply sequential selective chemical extraction techniques. A seven-step sequential extraction procedure was used to investigate the mobility and retention behaviour of Al, Fe, Mn, Cu, Zn, Pb, Cr, Co, Ni, Mo, Cd, Bi, Sn, W, Ag, As and U in specific physical–chemical and mineral phases in mine tailings and soils in the surroundings of the abandoned Ervedosa mine. The soil geochemical data show anomalies associated with mineralised veins or influenced by mining. Beyond the tailings, the highest recorded concentrations for most elements are in soils situated in mineralised areas or under the influence of tailings. The application of principal components analysis allowed recognition of (a) element associations according to their geochemical behaviour and (b) distinction between samples representing local geochemical background and samples representing contamination. Some metal cations (Mn, Cd, Cu, Zn, Co, Cr, Ni) showed important enrichment in the most mobilisable and bioavailable (i.e., water-soluble and exchangeable) fractions due likely to the acidic conditions in the area. In contrast, oxy-anions such as Mo and As showed lower mobility because of adsorption to Fe oxy-hydroxides. The residual fraction comprised largest proportions of Sn and Al and to a lesser extent Zn, Pb, Ni, Cr, Bi, W, and Ag, which are also present at low concentrations in the bioavailable fractions. The elements in secondary mineral phases (mainly Fe, Mn, Cu, Zn, Cd, Pb, W, Bi, Mo, Cr, Ni, Co, As and U) as well as in organic matter and sulphides are temporarily withheld, suggesting that they may be released to the environment by changes in physico-chemical conditions.  相似文献   

Defining the dynamics of groundwater in Serra da Estrela Mountain area, central Portugal: an isotopic and hydrogeochemical approach     

Paula M. Carreira  Jos�� M. Marques  Jorge Espinha Marques  Helder I. Chamin��  Paulo E. Fonseca  Fernando Monteiro Santos  Rui M. Moura  Jos�� M. Carvalho 《Hydrogeology Journal》2011,19(1):117-131

In a multidisciplinary approach, geological, geomorphologic, structural, hydrogeochemical and isotopic surveys were conducted on the Serra da Estrela groundwater system (central Portugal) in order to establish/develop a conceptual circulation model of the Caldas de Manteigas thermomineral system. A detailed study of the isotopic and geochemical composition of surface waters (e.g. Zêzere River), shallow groundwaters (cold dilute springs), and thermomineral waters was carried out to characterize the distribution of isotopes in waters of this mountainous region, and to determine the origin and possible recharge locations of the thermomineral system. Special attention was dedicated to isotopic tracers and their role in the definition of the thermomineral waters??conceptual model, considering: (1) the δ¹⁸O fractionation gradient; (2) the mean isotopic composition of the thermomineral waters in the region; and (3) the estimation of snowmelt contribution as a source of groundwater recharge at Serra da Estrela. The recharge of the thermomineral aquifer takes place on the more permeable zones of the granitic massif, associated with the main tectonic structures, whereas the recharge of the shallow aquifers seems to take place mostly in the plateaus, although another part of the recharge may occur in the slopes of the Zêzere River valley.  相似文献   

Groundwater salinization in the Azores archipelago (Portugal)   总被引：1，自引：1，他引：0  

J. Virgílio Cruz  Rui Coutinho  Dina Pacheco  Raquel Cymbron  Paulo Antunes  Pedro Freire  Sandra Mendes 《Environmental Earth Sciences》2011,62(6):1273-1285

Groundwater salinization in coastal regions causes severe constraints to water supply and economic losses to society worldwide. In the Azores archipelago, groundwater abstraction in wells drilled in coastal aquifers is very important for water supply, and quality problems have been reported. Therefore, a groundwater chemistry dataset from wells was compiled to study groundwater salinization in these aquifers. Waters are mainly of the Na–Cl type, presenting a slightly acidic to slightly alkaline character, with a pH between 5.63 and 8.50 (median 7.40). Electrical conductivity measurements range from 127 to 9,670 μS/cm (median 862), suggesting highly variable mineralization, with higher values observed on Santa Maria, São Miguel, Pico, Graciosa, and São Jorge islands. The major-ion composition reflects the contribution of seawater to the groundwater compositional evolution, which is essentially explained by seawater intrusion into wells. In many samples, exchange reactions of Na⁺ + K⁺ for Ca²⁺ + Mg²⁺ are associated with salinization. The seawater fraction in groundwater composition reaches a maximum of 22.5%. These results are extremely challenging to water managers in the Azores because failure to comply with national water quality regulations and with European Union groundwater directive requirements often occurs.  相似文献