Sources and processes governing rainwater chemistry in New Delhi,India     

Pawan Kumar  Sudesh Yadav  Abhay Kumar 《Natural Hazards》2014,74(3):2147-2162

Rainwater plays an important role in scavenging of aerosols and gases from atmosphere, and its chemistry helps to understand the relative contributions of atmospheric pollution sources. The present work is aimed to understand and explain the sources, seasonal patterns and the processes thereof affecting rainwater chemistry in an urban environment of Delhi, India. Rainwater samples (n = 111) collected throughout the year in New Delhi showed alkalinity in general. Eight rainwater samples, collected in late monsoon and winter season, had pH less than 5.6 indicating that Delhi continues to face the prospects of acid rain despite the introduction of compressed natural gas as the clean fuel in city transport. Organic acids could be the possible contributors of acidity in rainwater samples having the fractional acidity (FA) value of 0.174, which is greater than the annual average FA (0.011) and the (Ca²⁺ + Mg²⁺ + NH₄ ⁺)/(SO₄ ^2? + NO₃ ^?) ration of more than one. Average acid neutralization factors of cations decrease in the order Ca²⁺ (1.01) > NH₄ ⁺ (0.77) > Mg²⁺ (0.10). However, neutralization by Ca²⁺ dominates only in summer season as cation-rich dust is transported from the Great Indian Thar Desert to this region by strong summer S–SW winds, while NH₄ ⁺ dominates in rainwater of other three sampling seasons. Identified dominant sources for soluble ions in rainwater are (1) non-silicate crustal source for carbonates and sulfates of Ca and Mg, (2) emissions from catalytic convertor-fitted vehicles and agriculture fields for NH₃ and (3) mixed anthropogenic sources for SO₄ ^2?, NO₃ ^? and Cl^?. Rainwater chemistry showed significant seasonal variations. This could be due to the changes in relative proportions of natural and anthropogenic sources of soluble ions to rainwater. Dominance of anthropogenic sources over crustal sources can result in acidic rains, which can adversely affect the environment and human health in this region.  相似文献   

Stellar contents of two young open clusters: NGC 663 and 654     

A. K. Pandey  K. Upadhyay  K. Ogura  Ram Sagar  V. Mohan  H. Mito  H. C. Bhatt  B. C. Bhatt 《Monthly notices of the Royal Astronomical Society》2005,358(4):1290-1308

UBVRI CCD photometry in a wide field around two young open clusters, NGC 663 and 654, has been carried out. Hα and polarimetric observations for the cluster NGC 654 have also been obtained. We use the photometric data to construct colour–colour and colour–magnitude diagrams, from which we can investigate the reddening, age, mass and evolutionary states of the stellar contents of the these clusters. The reddening across the cluster regions is found to be variable. There is evidence for anomalous reddening law in both clusters; however, more infrared and polarimetric data are needed to conclude about the reddening law. Both clusters are situated at about a distance of 2.4 kpc. Star formation in both clusters is found to be a continuous process. In the case of NGC 663, star formation seems to have taken place sequentially, in the sense that formation of low-mass stars precedes the formation of most massive stars. Whereas, in the case of NGC 654, formation of low-mass stars did not cease after the formation of most massive stars in the cluster.  相似文献   

An indicator-based approach to assess village-level social and biophysical vulnerability of agriculture communities in Uttarakhand,India     

Roopam Shukla  Kamna Sachdeva  Pawan Kumar Joshi 《山地科学学报》2016,13(12):2260-2271

With the growing recognition to myriad forms of current and future threats in the mountain agriculture systems,there is a pressing need to holistically understand the vulnerability of mountain agriculture communities.The study aims to assess the biophysical and social vulnerability of agriculture communities using an indicator-based approach for the state of Uttarakhand,India.A total of 14 indicators were used to capture biophysical vulnerability and 22 for social vulnerability profiles of15285 villages.Vulnerability analysis was done at village level with weights assigned to each indicator using Analytical Hierarchical Process(AHP).The results of the study highlight the presence of very high biophysical vulnerability(0.82 ± 0.10) and high social vulnerability(0.65 ± 0.15) within the state.Based on the results,it was found that incidences of high biophysical vulnerability coincide with presence of intensified agriculture land and absence of dense forest.Higher social vulnerability scores were found in villages with an absence of local institutions(like Self Helping Groups(SHGs)),negligible infrastructure facilities and higher occupational dependence on agriculture.A contrast was observed in the vulnerability scores of villages present in the three different altitudinal zones in the study area,indicating respective vulnerability generating conditions existing in these three zones.Biophysical vulnerability was recorded to be highest in the villages falling in the lower zone and lowest in the upper zone villages;whereas,social vulnerability was found to be highest in the middle zone villages and lowest in lower zone villages.Our study aids policy makers in identifying areas for intervention to expedite agriculture adaptation planning in the state.Additionally,the adaptation programmes in the region need to be more context-specific to accommodate the differential altitudinal vulnerability profiles.  相似文献   

Implications of climate change on streamflow of a snow-fed river system of the Northwest Himalaya     

Vaibhav SHARMA  Varunendra Dutta MISHRA  Pawan Kumar JOSHI 《山地科学学报》2013,10(4):574-587

Air temperature and snow cover variability are sensitive indicators of climate change. This study was undertaken to forecast and quantify the potential streamflow response to climate change in the Jhelum River basin. The implications of air temperature trends (+0.11°C/decade) reported for the entire north-west Himalaya for past century and the regional warming (+0.7°C/decade) trends of three observatories analyzed between last two decades were used for future projection of snow cover depletion and stream flow. The streamflow was simulated and validated for the year 2007-2008 using snowmelt runoff model (SRM) based on in-situ temperature and precipitation with remotely sensed snow cover area. The simulation was repeated using higher values of temperature and modified snow cover depletion curves according to the assumed future climate. Early snow cover depletion was observed in the basin in response to warmer climate. The results show that with the increase in air temperature, streamflow pattern of Jhelum will be severely affected. Significant redistribution of streamflow was observed in both the scenarios. Higher discharge was observed during spring-summer months due to early snowmelt contribution with water deficit during monsoon months. Discharge increased by 5% 40% during the months of March to May in 2030 and 2050. The magnitude of impact of air temperature is higher in the scenario-2 based on regional warming. The inferences pertaining to change in future streamflow pattern can facilitate long term decisions and planning concerning hydro-power potential, waterresource management and flood hazard mapping in the region.  相似文献   

Identification of Water Conservation Sites in a Watershed (WRJ-2) of Nagpur District, Maharashtra using Geographical Information System (GIS) Technique   总被引：1，自引：0，他引：1  

Abhay M. Varade  Y. D. Khare  N. C. Mondal  Sarang Muley  Pawan Wankawar  Priti Raut 《Journal of the Indian Society of Remote Sensing》2013,41(3):619-630

The paper deals with the application of Remote Sensing and Geographical Information System (GIS) technique for a watershed development program. For this study, the WRJ-2 watershed falling under Narkhed and Katol Tahsils of Nagpur district, Maharashtra, India is investigated. Various thematic maps (i.e. drainage, geology, soil, geomorphology and land use/ land cover) have been prepared using the remote sensing and GIS techniques. Initially, differential weightage values are assigned to all the thematic maps as per their runoff characteristics. Subsequently, the maps are integrated in GIS environment to identify potential sites for water conservation measures like gully plugs, earthen check dams, continuous contour trenches, percolation tanks, cement bandhara, afforestration and farm ponds, etc. The study depicts that the GIS technique facilitates integration of thematic maps and thereby helps in an identification of micro-zones each with unique characters in-terms of hydrogeology, thus amenable to specific water conservation techniques. It is therefore concluded that, the GIS technique is suitable for an identification of water conservation structures.  相似文献   

Neoarchean high-pressure margarite–phengitic muscovite–chlorite corona mantled corundum in quartz-free high-Mg,Al phlogopite–chlorite schists from the Bundelkhand craton,north central India     

L. Saha  N. C. Pant  J. K. Pati  D. Upadhyay  J. Berndt  A. Bhattacharya  M. Satynarayanan 《Contributions to Mineralogy and Petrology》2011,161(4):511-530

In quartz-free Fe, Na-poor and high-Mg, Al schists from the Bundelkhand craton in north central India, corundum porphyroblasts in finely interleaved phlogopite–chlorite aggregates with rare clinozoisite are mantled by fine-grained (<3 μm) intergrowths of outer collars (>200 μm wide) of phengitic-muscovite and chlorite (phlogopite + corundum + H₂O → phengitic-muscovite + chlorite), and <100 μm wide inner collars of margarite–muscovite (corundum + clinozoisite + phengitic muscovite → margarite + muscovite + H₂O). Wide-beam electron probe microanalyses indicate Mg in the bi-layered corona increases from corundum outwards, with a complementary decrease in Al and K. Si and Ca increase and then decrease to matrix values. The sharp chemical gradients across the highly structured bi-layered corona are inferred to suggest that the corona-forming reactions were promoted by local grain-boundary-controlled thermodynamic instability as opposed to element transport by advective diffusion. The P–T convergence of KMASH reactions and NCKMASH pseudosection phase relations computed using micro-domain compositions indicate the chlorite–phengitic muscovite outer collar formed at 18–20 kbar and ca. 630°C. The NCKMASH margarite–muscovite inner collar yielded lower metamorphic P–T conditions of 11 ± 3 kbar, ca. 630°C. U–Th–Pb chemical dating of metamorphic monazite and LA-ICPMS U–Pb isotope dating of re-equilibrated zircon yield ca. 2.78 Ga ages, which are interpreted to date corona formation and Neoarchean high-P metamorphism in the Bundelkhand craton, hitherto unknown in the Indian Precambrian. (220)  相似文献   

Deccan volcanism linked to the Cretaceous-Tertiary boundary mass extinction: New evidence from ONGC wells in the Krishna-Godavari Basin     

G. Keller  P. K. Bhowmick  H. Upadhyay  A. Dave  A. N. Reddy  B. C. Jaiprakash  T. Adatte 《Journal of the Geological Society of India》2011,78(5):399-428

A scientific challenge is to assess the role of Deccan volcanism in the Cretaceous-Tertiary boundary (KTB) mass extinction. Here we report on the stratigraphy and biologic effects of Deccan volcanism in eleven deep wells from the Krishna-Godavari (K-G) Basin, Andhra Pradesh, India. In these wells, two phases of Deccan volcanism record the world’s largest and longest lava mega-flows interbedded in marine sediments in the K-G Basin about 1500 km from the main Deccan volcanic province. The main phase-2 eruptions (∼80% of total Deccan Traps) began in C29r and ended at or near the KTB, an interval that spans planktic foraminiferal zones CF1–CF2 and most of the nannofossil Micula prinsii zone, and is correlative with the rapid global warming and subsequent cooling near the end of the Maastrichtian. The mass extinction began in phase-2 preceding the first of four mega-flows. Planktic foraminifera suffered a 50% drop in species richness. Survivors suffered another 50% drop after the first mega-flow, leaving just 7 to 8 survivor species. No recovery occurred between the next three mega-flows and the mass extinction was complete with the last phase-2 mega-flow at the KTB. The mass extinction was likely the consequence of rapid and massive volcanic CO₂ and SO₂ gas emissions, leading to high continental weathering rates, global warming, cooling, acid rains, ocean acidification and a carbon crisis in the marine environment.  相似文献   

New insights on petrography and geochemistry of impactites from the Lonar crater,India          下载免费PDF全文

Dwijesh Ray  Dewashish Upadhyay  Saumitra Misra  Horton E. Newsom  Sambhunath Ghosh 《Meteoritics & planetary science》2017,52(8):1577-1599

The Lonar impact crater, India, is one of the few known terrestrial impact craters excavated in continental basaltic target rocks (Deccan Traps, ~65 Ma). The impactites reported from the crater to date mainly include centimeter‐ to decimeter‐sized impact‐melt bombs, and aerodynamically shaped millimeter‐ and submillimeter‐sized impact spherules. They occur in situ within the ejecta around the crater rim and show schlieren structure. In contrast, non–in situ glassy objects, loosely strewn around the crater lake and in the ejecta around the crater rim do not show any schlieren structure. These non–in situ fragments appear to be similar to ancient bricks from the Daityasudan temple in the Lonar village. Synthesis of existing and new major and trace element data on the Lonar impact spherules show that (1) the target Lonar basalts incorporated into the spherules had undergone minimal preimpact alteration. Also, the paleosol layer as preserved between the top‐most target basalt flow and the ejecta blanket, even after the impact, was not a source component for the Lonar impactites, (2) the Archean basement below the Deccan traps were unlikely to have contributed material to the impactite parental melts, and (3) the impactor asteroid components (Cr, Co, Ni) were concentrated only within the submillimeter‐sized spherules. Two component mixing calculations using major oxides and Cr, Co, and Ni suggest that the Lonar impactor was a EH‐type chondrite with the submillimeter‐sized spherules containing ~6 wt% impactor components.  相似文献   

Sorption model for dissolved and particulate aluminium in the Conway estuary, UK   总被引：1，自引：0，他引：1  

S. Upadhyay   《Estuarine, Coastal and Shelf Science》2008,76(4):914-919

Dissolved Al carried in river water apparently undergoes a fractional removal at the early stages of mixing in the Conway estuary. On the other hand, dissolved Al behaves almost conservatively in high salinity (>13) estuarine waters. In order to understand the geochemistry of Al in these estuarine waters, simple empirical sorption models have been used. Partitioning of Al occurs between solid and solution phases with a distribution coefficient, K_d, which varies from 0.67 × 10⁵ to 3.38 × 10⁶ ml g⁻¹ for suspended particle concentrations of 2–64 mg l⁻¹. The K_d values in general decrease with increasing suspended particulate matter and this tendency termed the “particle concentration effect” is quite pronounced in these waters. The sorption model derived by previous workers for predicting concentrations of dissolved Al with changing suspended sediment loads has been applied to these data. Reasonable fits are obtained for K_d values of 10⁵, 10⁶ and 10⁷ ml g⁻¹ with various values of α. Further, a sorption model is proposed for particulate Al concentrations in these waters that fits the data extremely well defined by a zone with K_d value 10⁷ ml g⁻¹ and C₀ values 16 × 10⁻⁶ mg ml⁻¹ and 92 × 10⁻⁶ mg ml⁻¹. These observations provide strong evidence of sorption processes as key mechanisms influencing the distribution of dissolved and particulate Al in the Conway estuary and present new insight into Al geochemistry in estuaries.  相似文献   

Modeling urban floods and drainage using SWMM and MIKE URBAN: a case study     

Deepak Singh Bisht  Chandranath Chatterjee  Shivani Kalakoti  Pawan Upadhyay  Manaswinee Sahoo  Ambarnil Panda 《Natural Hazards》2016,84(2):749-776

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