Identification of magnetic minerals related to hydrocarbon authigenesis in venezuelan oil fields using an alternative decomposition of isothermal remanence curves     

Milagrosa Aldana  Vincenzo Costanzo-Álvarez  Luis Gómez  Carlos González  Marisel Díaz  Pedro Silva  Myriam Rada 《Studia Geophysica et Geodaetica》2011,55(2):343-358

In this work we try to better characterise the shallow magnetic signature of hydrocarbon microseepage in oil fields from eastern and western Venezuela. To get a better insight of the processes involved, we attempt to find out the main magnetic phases responsible for the observed oil-related shallow magnetic anomalies. In this way, a new and alternative numerical approach to decompose Isothermal Remagnetization (IRM) curves is introduced. The method is based on a Direct Signal Analysis (DSA) of the IRM curve in order to identify the number and type of magnetic components. Representative wells from western (La Victoria) and eastern (San Joaquín) Venezuelan fields are studied. The DSA approach, together with rock magnetic experimental results, indicates that in the well from western Venezuela the main magnetic mineralogy associated to hydrocarbon microseepage is magnetite. Conversely, in the well from eastern Venezuela, these MS anomalies are mainly caused by the presence of Fe-sulphides (i.e. greigite). These results support the hypothesis of two different authigenic processes. For the well at the western field, we propose that a net electron transfer from the organic matter, degraded by hydrocarbon gas leakage, should occur precipitating Fe(II) magnetic minerals (e.g. magnetite). On the other hand, in the well of the eastern field, high concentrations of H2S at shallow levels, might allow the formation of secondary Fe-sulphides.  相似文献   

Triterpenols in mangrove sediments as a proxy for organic matter derived from the red mangrove (Rhizophora mangle)     

Boris P. Koch  Pedro W.M. Souza FilhoHermann Behling  Marcelo C.L. CohenGerhard Kattner  Jürgen RullkötterBarbara Scholz-Böttcher  Rubén J. Lara 《Organic Geochemistry》2011,42(1):62-73

Mangroves are the dominant type of vegetation along many tropical coasts. Organic matter (OM) derived from mangrove leaf litter and root material is stored in sediments and is a major contributor to the amount and chemical composition of sedimentary OM. A set of organic biomarkers in sediments was applied as a palaeo-indicator for the Holocene dynamics of a mangrove Estuary (Rio Caeté, Pará, Brazil). Six sediment cores were collected perpendicular to the present coast line and analysed for triterpenols and sitosterol. The influence of microbial biomarker degradation was implemented from a previous study. Biomarker profiles were validated with pollen data and multivariate statistics to test whether these compounds were suitable indicators for the palaeo-vegetation. Sediments deposited up to 2 Ma BP showed biomarker assemblages similar to those of recent surface sediment. In two cores, the biomarker composition revealed a transition from marsh to mangrove vegetation. Taraxerol, germanicol and β-amyrin provided the most significant chemotaxonomical information and, especially in combination, served as reliable proxies for OM from Rhizophora mangle in northern Brazil. The maximum age of the mangrove system ranged between 1000 and 5100 yr depending on the topographic elevation of the drilling location.  相似文献   

Discrimination of coastal wetland environments in the Amazon region based on multi-polarized L-band airborne Synthetic Aperture Radar imagery     

Pedro Walfir M. Souza-Filho  Waldir R. Paradella  Suzan W.P. Rodrigues  Francisco R. Costa  José C. Mura  Fabrício D. Gonçalves 《Estuarine, Coastal and Shelf Science》2011

This study assessed the use of multi-polarized L-band images for the identification of coastal wetland environments in the Amazon coast region of northern Brazil. Data were acquired with a SAR R99B sensor from the Amazon Surveillance System (SIVAM) on board a Brazilian Air Force jet. Flights took place in the framework of the 2005 MAPSAR simulation campaign, a German-Brazilian feasibility study focusing on a L-band SAR satellite. Information retrieval was based on the recognition of the interaction between a radar signal and shallow-water morphology in intertidal areas, coastal dunes, mangroves, marshes and the coastal plateau. Regarding the performance of polarizations, VV was superior for recognizing intertidal area morphology under low spring tide conditions; HH for mapping coastal environments covered with forest and scrub vegetation such as mangrove and vegetated dunes, and HV was suitable for distinguishing transition zones between mangroves and coastal plateau. The statistical results for the classification maps expressed by kappa index and general accuracy were 83.3% and 0.734 for the multi-polarized color composition (R-HH, G-HV, B-VV), 80.7% and 0.694% for HH, 79.7% and 0.673% for VV, and 77.9% and 0.645% for HV amplitude image. The results indicate that use of multi-polarized L-band SAR is a valuable source of information aiming at the identification and discrimination of distinct geomorphic targets in tropical wetlands.  相似文献   

Can salt marsh plants influence levels and distribution of DDTs in estuarine areas?     

Pedro N. Carvalho  Pedro Nuno R. RodriguesRafael Evangelista  M. Clara P. BastoM. Teresa S.D. Vasconcelos 《Estuarine, Coastal and Shelf Science》2011

Sediments are depositories of toxic substances such as organochlorine pesticides and there is a global need for their removal in contaminated environments. Studies that combine contaminated sediments and phytoremediation are relatively recent and their number has been increasing. This work aimed to investigate whether salt marsh plants (sea club-rush Scirpus maritimus, sea rush Juncus maritimus and sea purslane Halimione portulacoides) can favor DDT and metabolites remediation in estuarine environment. For this purpose the levels of DDT, DDE and DDD were compared in vegetated and non-vegetated sediments from an estuary in the North of Portugal (in-situ study) and from another in the South of Portugal (ex-situ study). Results obtained both in the in-situ study, involving S. maritimus and J. maritimus, and in the ex-situ study, involving H. portulacoides, indicated that these plants did not have a significant role in DDTs removal and/or degradation. Therefore, it seems that the tested plants cannot influence levels and distribution of DDTs in estuarine areas.  相似文献   

Recent structures in the Alboran Ridge and Yusuf fault zones based on swath bathymetry and sub-bottom profiling: evidence of active tectonics   总被引：2，自引：2，他引：0  

Pedro Mart��nez-Garc��a  Juan I. Soto  Menchu Comas 《Geo-Marine Letters》2011,31(1):19-36

The seafloor of the Alboran Sea in the western Mediterranean is disrupted by deformations resulting from convergence between the African and Eurasian plates. Based on a compilation of existing and new multibeam bathymetry data and high-resolution seismic profiles, our main objective was to characterize the most recent structures in the central sector, which depicts an abrupt morphology and was chosen to investigate how active tectonic processes are shaping the seafloor. The Alboran Ridge is the most prominent feature in the Alboran Sea (>130 km in length), and a key element in the Gibraltar Arc System. Recent uplift and deformation in this ridge have been caused by sub-vertical, strike-slip and reverse faults with associated folding in the most recent sediments, their trend shifting progressively from SW–NE to WNW–ESE towards the Yusuf Lineament. Present-day transtensive deformation induces faulting and subsidence in the Yusuf pull-apart basin. The Alboran Ridge and Yusuf fault zones are connected, and both constitute a wide zone of deformation reaching tens of kilometres in width and showing a complex geometry, including different active fault segments and in-relay folds. These findings demonstrate that Recent deformation is more heterogeneously distributed than commonly considered. A narrow SSW–NNE zone with folding and reverse faulting cuts across the western end of the Alboran Ridge and concentrates most of the upper crustal seismicity in the region. This zone of deformation defines a seismogenic, left-lateral fault zone connected to the south with the Al Hoceima seismic swarm, and representing a potential seismic hazard. Newly detected buried and active submarine slides along the Alboran Ridge and the Yusuf Lineament are clear signs of submarine slope instability in this seismically active region.  相似文献   

On the detectability of lightcurves of Kuiper belt objects     

Pedro Lacerda  Jane Luu 《Icarus》2003,161(1):174-180

We present a statistical study of the detectability of lightcurves of Kuiper belt objects (KBOs). Some Kuiper belt objects display lightcurves that appear “flat”; i.e., there are no significant brightness variations within the photometric uncertainties. Under the assumption that KBO lightcurves are mainly due to shape, the lack of brightness variations may be due to (1) the objects having very nearly spherical shapes or (2) their rotation axes coinciding with the line of sight. We investigate the relative importance of these two effects and relate it to the observed fraction of “flat” lightcurves. This study suggests that the fraction of KBOs with detectable brightness variations may provide clues about the shape distribution of these objects. Although the current database of rotational properties of KBOs is still insufficient to draw any statistically meaningful conclusions, we expect that, with a larger dataset, this method will provide a useful test for candidate KBO shape distributions.  相似文献   

Groundwater vulnerability assessment in coastal plain of Rio Grande do Sul State,Brazil, using drastic and adsorption capacity of soils   总被引：1，自引：0，他引：1  

Ronaldo HerlingerJr  Antonio Pedro Viero 《Environmental Geology》2007,52(5):819-829

Groundwater vulnerability assessment to delineate areas that are more susceptible to contamination has become an important element for resource management and land use planning. The objective of this work was to integrate hydrogeologic data in a geographic information system (GIS) for phreatic groundwater vulnerability assessment of a pilot area from the Coastal Plain of the Rio Grande do Sul State, Brazil, using the DRASTIC method and adsorption capacity of soils. The studied ions were copper, lead, sulfate and phosphate. Using the original DRASTIC method, the vulnerability presented high values, mainly due to the texture of the sediments and the low depths of waters, which favor the accessibility of the contaminants to the groundwaters. DRASTIC with adsorption capacity of soils showed specifics results for each studied ion. Groundwater vulnerability to metals in relationship to anions was lower. These results show that the original DRASTIC method represents better contaminants with high mobility. An erratum to this article can be found at  相似文献   

National-scale data-driven rainfall induced landslide susceptibility mapping for China by accounting for incomplete landslide data     

Qigen Lin  Pedro Lima  Stefan Steger  Thomas Glade  Tong Jiang  Jiahui Zhang  Tianxue Liu  Ying Wang 《地学前缘(英文版)》2021,12(6):262-276

China is one of the countries where landslides caused the most fatalities in the last decades.The threat that landslide disasters pose to people might even be greater in the future,due to climate change and the increasing urbanization of mountainous areas.A reliable national-scale rainfall induced landslide suscep-tibility model is therefore of great relevance in order to identify regions more and less prone to landslid-ing as well as to develop suitable risk mitigating strategies.However,relying on imperfect landslide data is inevitable when modelling landslide susceptibility for such a large research area.The purpose of this study is to investigate the influence of incomplete landslide data on national scale statistical landslide susceptibility modeling for China.In this context,it is aimed to explore the benefit of mixed effects mod-elling to counterbalance associated bias propagations.Six influencing factors including lithology,slope,soil moisture index,mean annual precipitation,land use and geological environment regions were selected based on an initial exploratory data analysis.Three sets of influencing variables were designed to represent different solutions to deal with spatially incomplete landslide information:Set 1(disregards the presence of incomplete landslide information),Set 2(excludes factors related to the incompleteness of landslide data),Set 3(accounts for factors related to the incompleteness via random effects).The vari-able sets were then introduced in a generalized additive model(GAM:Set 1 and Set 2)and a generalized additive mixed effect model(GAMM:Set 3)to establish three national-scale statistical landslide suscep-tibility models:models 1,2 and 3.The models were evaluated using the area under the receiver operating characteristics curve(AUROC)given by spatially explicit and non-spatial cross-validation.The spatial pre-diction pattern produced by the models were also investigated.The results show that the landslide inven-tory incompleteness had a substantial impact on the outcomes of the statistical landslide susceptibility models.The cross-validation results provided evidence that the three established models performed well to predict model-independent landslide information with median AUROCs ranging from 0.8 to 0.9.However,although Model 1 reached the highest AUROCs within non-spatial cross-validation(median of 0.9),it was not associated with the most plausible representation of landslide susceptibility.The Model 1 modelling results were inconsistent with geomorphological process knowledge and reflected a large extent the underlying data bias.The Model 2 susceptibility maps provided a less biased picture of landslide susceptibility.However,a lower predicted likelihood of landslide occurrence still existed in areas known to be underrepresented in terms of landslide data(e.g.,the Kuenlun Mountains in the northern Tibetan Plateau).The non-linear mixed-effects model(Model 3)reduced the impact of these biases best by introducing bias-describing variables as random effects.Among the three models,Model 3 was selected as the best national-scale susceptibility model for China as it produced the most plausible portray of rainfall induced landslide susceptibility and the highest spatially explicit predictive perfor-mance(median AUROC of spatial cross validation 0.84)compared to the other two models(median AUROCs of 0.81 and 0.79,respectively).We conclude that ignoring landslide inventory-based incomplete-ness can entail misleading modelling results and that the application of non-linear mixed-effect models can reduce the propagation of such biases into the final results for very large areas.  相似文献   

Petrology,phase equilibria modelling,noble gas chronology and thermal constraints of the El Pozo L5 meteorite     

Pedro Corona-Chávez  María del Sol Hernández-Bernal  Pietro Vignola  Rufino Lozano-Santacruz  Juan Julio Morales-Contreras  Margarita Reyes-Salas  Jesús Solé-Viñas  José F. Molina 《Chemie der Erde / Geochemistry》2018,78(2):248-253

We present the results of physical properties, petrography, bulk chemistry, mineral compositions, phase relations modelling and Noble gases study of the meteorite El Pozo. The petrography and mineral compositions indicate that the meteorite is an L5 chondrite with a low shock stage of S2-S3. Heterogenous weathering was preferentially along shock structures. Thermobarometric calculations indicate thermal equilibrium conditions between 768?°C and 925?°C at ～4 to 6?kb, which are substantially consistent with the petrological metamorphism type 5. A pseudosection phase diagram is relatively consistent with the mineral assemblage observed and PT conditions calculated. Temperature vs. fO₂ diagram shows that plagioclase compositional stability is very sensitive to Tschermack substitution in orthopyroxene, clinopyroxene and X_An plagioclase during the high temperature metamorphic process. Based on noble gases He, Ne, Ar and K contents a cosmogenic exposure age CRE of 1.9?Myr was calculated. The ²¹Ne would be totally cosmogenic, with no primordial Ne. The ²¹Ne/²²Ne value (0.97) is higher than solar value. According to the cosmogenic Ne content, we argue that El Pozo chondrite originally had a pre-atmospheric mass of 9–10?kg, which would have been produced by a later collision after the recognized collision of the L-chondrite parent body ～470?Ma ago.  相似文献   

New rurality and the experience of place: the small rural locality of La Niña,Buenos Aires,Argentina     

Pedro S. Urquijo  Gerardo Bocco  Andrew F. Boni-Noguez 《GeoJournal》2018,83(6):1301-1315

This paper presents a cultural geographic approach for understanding local social processes of territorial re-appropriation taking place in response to non-local forces and interests. This approach is applied to the small rural locality of La Niña, in Buenos Aires Province, Argentina. The small village of La Niña is currently in a locally-led process of recovering from a recent depopulation trend caused mainly by the irruption of transnational agribusiness. As economic opportunities have dwindled in the last decades, more recently local inhabitants and new settlers have set forth diverse strategies aimed at mitigating the effects of depopulation on the social structure. We focus our attention on the way the living experience of place is involved in all these strategies. We contend that despite economic and cultural homogenization caused by globalization, the experience of place is a permanent though ever-changing aspect of social life. Our research was based on archival and hemerographic surveys and ethnographic field techniques, encompassing participatory observation, semistructured and in-depth interviews with social and government leaders and local producers as well as field landscape appraisals.  相似文献